2D Lateral Heterojunction Arrays with Tailored Interface Band Bending.

Two-dimensional (2D) lateral heterojunction arrays, characterized by well-defined electronic interfaces, hold significant promise for advancing next-generation electronic devices. Despite this potential, the efficient synthesis of high-density lateral heterojunctions with tunable interfacial band alignment remains a challenging. Here, a novel strategy is reported for the fabrication of lateral heterojunction arrays between monolayer Si2Te2 grown on Sb2Te3 (ML-Si2Te2@Sb2Te3) and one-quintuple-layer Sb2Te3 grown on monolayer Si2Te2 (1QL-Sb2Te3@ML-Si2Te2) on a p-doped Sb2Te3 substrate. The site-specific formation of numerous periodically arranged 2D ML-Si2Te2@Sb2Te3/1QL-Sb2Te3@ML-Si2Te2 lateral heterojunctions is realized solely through three epitaxial growth steps of thick-Sb2Te3, ML-Si2Te2, and 1QL-Sb2Te3 films, sequentially. More importantly, the precisely engineering of the interfacial band alignment is realized, by manipulating the substrate's p-doping effect with lateral spatial dependency, on each ML-Si2Te2@Sb2Te3/1QL-Sb2Te3@ML-Si2Te2 junction. Atomically sharp interfaces of the junctions with continuous lattices are observed by scanning tunneling microscopy. Scanning tunneling spectroscopy measurements directly reveal the tailored type-II band bending at the interface. This reported strategy opens avenues for advancing lateral epitaxy technology, facilitating practical applications of 2D in-plane heterojunctions.

Probing the topologically trivial nature of end states in antiferromagnetic atomic chains on superconductors.

Spin chains proximitized by s-wave superconductors are predicted to enter a mini-gapped phase with topologically protected Majorana modes (MMs) localized at their ends. However, the presence of non-topological end states mimicking MM properties can hinder their unambiguous observation. Here, we report on a direct method to exclude the non-local nature of end states via scanning tunneling spectroscopy by introducing a locally perturbing defect on one of the chain's ends. We apply this method to particular end states observed in antiferromagnetic spin chains within a large minigap, thereby proving their topologically trivial character. A minimal model shows that, while wide trivial minigaps hosting end states are easily achieved in antiferromagnetic spin chains, unrealistically large spin-orbit coupling is required to drive the system into a topologically gapped phase with MMs. The methodology of perturbing candidate topological edge modes in future experiments is a powerful tool to probe their stability against local disorder.

Precursors of Majorana modes and their length-dependent energy oscillations probed at both ends of atomic Shiba chains.

Isolated Majorana modes (MMs) are highly non-local quantum states with non-Abelian exchange statistics, which localize at the two ends of finite-size 1D topological superconductors of sufficient length. Experimental evidence for MMs is so far based on the detection of several key signatures: for example, a conductance peak pinned to the Fermi energy or an oscillatory peak splitting in short 1D systems when the MMs overlap. However, most of these key signatures were probed only on one of the ends of the 1D system, and firm evidence for an MM requires the simultaneous detection of all the key signatures on both ends. Here we construct short atomic spin chains on a superconductor-also known as Shiba chains-up to a chain length of 45 atoms using tip-assisted atom manipulation in scanning tunnelling microscopy experiments. We observe zero-energy conductance peaks localized at both ends of the chain that simultaneously split off from the Fermi energy in an oscillatory fashion after altering the chain length. By fitting the parameters of a low-energy model to the data, we find that the peaks are consistent with precursors of MMs that evolve into isolated MMs protected by an estimated topological gap of 50 µeV in chains of at least 35 nm length, corresponding to 70 atoms.

Spin-orbit coupling induced splitting of Yu-Shiba-Rusinov states in antiferromagnetic dimers.

Magnetic atoms coupled to the Cooper pairs of a superconductor induce Yu-Shiba-Rusinov states (in short Shiba states). In the presence of sufficiently strong spin-orbit coupling, the bands formed by hybridization of the Shiba states in ensembles of such atoms can support low-dimensional topological superconductivity with Majorana bound states localized on the ensembles' edges. Yet, the role of spin-orbit coupling for the hybridization of Shiba states in dimers of magnetic atoms, the building blocks for such systems, is largely unexplored. Here, we reveal the evolution of hybridized multi-orbital Shiba states from a single Mn adatom to artificially constructed ferromagnetically and antiferromagnetically coupled Mn dimers placed on a Nb(110) surface. Upon dimer formation, the atomic Shiba orbitals split for both types of magnetic alignment. Our theoretical calculations attribute the unexpected splitting in antiferromagnetic dimers to spin-orbit coupling and broken inversion symmetry at the surface. Our observations point out the relevance of previously unconsidered factors on the formation of Shiba bands and their topological classification.

Atomic-scale spin-polarization maps using functionalized superconducting probes.

A scanning tunneling microscope (STM) with a magnetic tip that has a sufficiently strong spin polarization can be used to map the sample's spin structure down to the atomic scale but usually lacks the possibility to absolutely determine the value of the sample's spin polarization. Magnetic impurities in superconducting materials give rise to pairs of perfectly, i.e., 100%, spin-polarized subgap resonances. In this work, we functionalize the apex of a superconducting Nb STM tip with such impurity states by attaching Fe atoms to probe the spin polarization of atom-manipulated Mn nanomagnets on a Nb(110) surface. By comparison with spin-polarized STM measurements of the same nanomagnets using Cr bulk tips, we demonstrate an extraordinary spin sensitivity and the possibility to measure the sample's spin-polarization values close to the Fermi level quantitatively with our new functionalized probes.

Anisotropic circular photogalvanic effect in colloidal tin sulfide nanosheets.

Tin sulfide promises very interesting properties such as a high optical absorption coefficient and a small band gap, while being less toxic compared to other metal chalcogenides. However, the limitations in growing atomically thin structures of tin sulfide hinder the experimental exploration of these properties. Due to the flexibility of the colloidal synthesis, it is possible to synthesize very thin and at the same time large nanosheets. Electrical transport measurements show that these nanosheets can function as field-effect transistors with an on/off ratio of more than 105 at low temperatures and p-type behavior. The temperature dependency of the charge transport reveals that defects in the crystal are responsible for the formation of holes as majority carriers. During illumination with circularly polarized light, these crystals generate a helicity dependent photocurrent at zero-volt bias, since their symmetry is broken by asymmetric interfaces (substrate and vacuum). Further, the observed circular photogalvanic effect shows a pronounced in-plane anisotropy, with a higher photocurrent along the armchair direction, originating from the higher absorption coefficient in this direction. Our new insights show the potential of tin sulfide for new functionalities in electronics and optoelectronics, for instance as polarization sensors.

Canadian psychiatrists' current attitudes, practices, and knowledge regarding fitness to drive in individuals with mental illness: a cross-Canada survey.

OBJECTIVES: To assess current attitudes, practices, and knowledge of Canadian psychiatrists regarding fitness to drive in individuals with mental illness and to explore variations according to provincial legislation. METHOD: We carried out a national cross-sectional survey, using a random sample of psychiatrists. We used a mail survey to collect data. RESULTS: In total, 248 psychiatrists participated; the response rate was 54.2% on traced subjects. The majority (64.1%) reported that they strongly agreed or agreed that addressing patients' fitness to drive is an important issue. However, only 18.0% of respondents were always aware of whether their patients were active drivers. One-fourth strongly agreed or agreed that they were confident in their ability to evaluate fitness to drive. In discretionary provinces, 29.3% of psychiatrists reported not knowing their provincial legislation, as did 14.6% of psychiatrists in mandatory provinces; of those responding, 54.0% from discretionary provinces and 2.8% from mandatory provinces gave incorrect answers. DISCUSSION: Psychiatrists' responses demonstrate a broad range of attitudes, practices, and knowledge. There appears to be a large gap between what is expected of psychiatrists and their readiness and self-perceived ability to make informed clinical decisions related to driving safety. CONCLUSION: There is a clear need for education and guidelines to assist psychiatrists in decision making about driving fitness.