A dual responsive bis-thiophene affixed thiosemicarbazide based chemosensor for colorimetrically Hg2+ and fluorometrically Cu2+ ions and their applications in live cell imaging.

In this work, we developed a fast and straightforward colorimetric and photoluminescent chemosensor probe (P1), featuring bis-thiophene-thiosemicarbazide moieties as its signaling and binding unit. This probe exhibited rapid sensitivity to Hg2+ and Cu2+ ions in a semi-aqueous medium, resulting in distinct colorimetric and photoluminescent changes. In the presence of Cu2+, P1 displayed an impressive 50-fold increase in photoluminescence (PL) at 450 nm (with excitation at 365 nm). The probe P1 formed a 1:1 complex with Hg2+ and Cu2+ ions, featuring association constant values of 4.04 × 104 M-1 and 1.25 × 103 M-1, respectively. P1 has demonstrated its efficacy in the analysis of real samples, yielding promising results. Additionally, the probe successfully visualized copper ions on a mouse fibroblast cell line (NIH3T3), highlighting its potential as an intracellular probe for copper ion detection.

Noble metal-free CZTS electrocatalysis: synergetic characteristics and emerging applications towards water splitting reactions.

This review provides a comprehensive overview of the production and modification of CZTS nanoparticles (NPs) and their application in electrocatalysis for water splitting. Various aspects, including surface modification, heterostructure design with carbon nanostructured materials, and tunable electrocatalytic studies, are discussed. A key focus is the synthesis of small CZTS nanoparticles with tunable reactivity, emphasizing the sonochemical method's role in their formation. Despite CZTS's affordability, it often exhibits poor hydrogen evolution reaction (HER) behavior. Carbon materials like graphene, carbon nanotubes, and C60 are highlighted for their ability to enhance electrocatalytic activity due to their unique properties. The review also discusses the amine functionalization of graphene oxide/CZTS composites, which enhances overall water splitting performance. Doping with non-noble metals such as Fe, Co., and Ni is presented as an effective strategy to improve catalytic activity. Additionally, the synthesis of heterostructures consisting of CZTS nanoparticles attached to MoS2-reduced graphene oxide (rGO) hybrids is explored, showing enhanced HER activity compared to pure CZTS and MoS2. The growing demand for energy and the need for efficient renewable energy sources, particularly hydrogen generation, are driving research in this field. The review aims to demonstrate the potential of CZTS-based electrocatalysts for high-performance and cost-effective hydrogen generation with low environmental impact. Vacuum-based and non-vacuum-based methods for fabricating CZTS are discussed, with a focus on simplicity and efficiency. Future developments in CZTS-based electrocatalysts include enhancing activity and stability, improving charge transfer mechanisms, ensuring cost-effectiveness and scalability, increasing durability, integrating with renewable energy sources, and gaining deeper insight into reaction processes. Overall, CZTS-based electrocatalysts show great promise for sustainable hydrogen generation, with ongoing research focused on improving performance and advancing their practical applications.

CTAB-Assisted Synthesis of FeNi Alloy Nanoparticles: Effective and Stable Electrocatalysts for Urea Oxidation Reactions.

Development of highly efficient electrocatalysts for treating urea-rich wastewater is an important problem in environmental management and energy production. In this work, an iron-nickel alloy (Fe-Ni alloy) was synthesized via soft-template cetyltrimethylammonium bromide (CTAB)-assisted precipitation using low-temperature calcination. The as-synthesized nanoalloy was characterized by X-ray diffraction (XRD), which revealed the formation of a face-centered cubic (FCC) structure of the Fe-Ni alloy; field emission-scanning electron microscopic (FE-SEM) analysis revealed the spherical shape of the Fe-Ni alloy; high-resolution transmission electron microscopy (HR-TEM) revealed the average size to be ∼33.09 nm; and X-ray photoelectron spectroscopy (XPS) showed the presence of Fe, Ni, C, and O components and their chemical composition and valence states in the Fe-Ni alloy. The electrochemical urea oxidation reaction (UOR) was investigated by conducting linear sweep voltammetry (LSV) tests on the synthesized electrocatalysts with different Ni/Fe ratios in alkaline electrolytes with urea. The potential required to reach a current density of 10 mA cm-2 is 1.27 V vs RHE, which demonstrates the higher electrochemical activity of the Fe-Ni alloy compared to other individual compounds. This could be due to CTAB which improved the structural stability and synergetic and electronic effects in the nanoscale. This study will further contribute to renewable energy generation technology with long-term energy sustainability and also opens up great potential for reducing water pollution.

A Porphyrin-based NIR Fluorescent Probe for Bi3+ and Potential Applications.

Herein, we have prepared a 5,10,15,20-Tetrakis(4-hydroxyphenyl) porphyrin (P) which acts as a probe for selective and sensitive detection of Bi3+ ions. Probe P was obtained by reacting pyrrole with 4-hydroxyl benzaldehyde and characterized by NMR, IR, and ESI-MS. All photo-physical studies of P were tested in DMSO:H2O (8:2, v/v) media by spectrophotometry and spectrofluorometry respectively. The selectivity of P was tested with different metal ions in solution as well as in the solid phase, only Bi3+ showed red fluorescence quenching while with other metal ions, no such effect was observed. The Job's plot unveiled the 1:1 stoichiometric binding ratio of the probe with Bi3+ and anticipated association constant of 3.4 ×105 M-1, whereas the Stern-Volmer quenching constant was noticed to be 5.6 ×105 M-1. Probe P could detect Bi3+ down to 27 nM by spectrofluorometric. The binding mechanism of P with Bi3+ was well supported with NMR, mass, and DFT studies. Further, the P was applied for the quantitative determination of Bi3+ in various water samples and the biocompatibility of P was examined using neuro 2A (N2a) cells. Overall, probe P proves promising for the detection of Bi3+ in the semi-aqueous phase and it is the first report as a colorimetric and fluorogenic probe.

Spherical Ni/NiO nanoparticles decorated on nanoporous carbon (NNC) as an active electrode material for urea and water oxidation reactions.

Herein, we report a chemical method for scalable synthesis of spherical Ni/NiO nanoparticle-decorated nanoporous carbon (NNC) based electrocatalytic system using a simple and easy chemical method with ultra-high activity towards urea electrooxidation. Morphological analysis by scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HR-TEM) confirms the formation of Ni/NiO NPs on highly nanoporous carbon with an average size of ∼50 nm. X-ray diffraction (XRD) confirms NNC with a face-centred cubic (FCC) crystal structure. Ni/NiO NPs intercalated with nanoporous carbon exhibited the best electrocatalytic performance towards urea oxidation with an ultra-low onset potential of ∼0.33 V vs. SCE, and faster electrokinetic mechanism confirmed from Tafel slope (∼45 mV dec-1), EIS Rct (∼6.98 Ω), and long term durability for 7 h at 10 mA cm-2 with high CO poisoning tolerance. This work affords noble metal-free electrocatalysts for novel appliances and remarkable potential for urea determination, hydrogen generation, real-time water remediation, and energy conversion.

Recent Progress on Carbon Quantum Dots Based Photocatalysis.

As a novel carbon allotrope, carbon quantum dots (CQDs) have been investigated in various fields, including photocatalysis, bioimaging, optoelectronics, energy and photovoltaic devices, biosensing, and drug delivery owing to their unique optical and electronic properties. In particular, CQDs' excellent sunlight harvesting ability, tunable photoluminescence (PL), up-conversion photoluminescence (UCPL), and efficient photo-excited electron transfer have enabled their applications in photocatalysis. This work focuses on the recent progress on CQDs-related materials' synthesis, properties, and applications in photocatalysis.

Design and Synthesis of Lead(II)-Based Electrocatalysts for Oxygen Evolution Reaction.

A well-organized worldwide effort in providing remedies to sustainable clean energy generation and storage has focused on the strategic design and development of stable and efficient earth-abundant metal (Fe, Co, Ni, Pb, etc.)-based electrocatalysts for the oxygen evolution reaction (OER). Unfortunately, examples of Pb-based catalysts for such a process are rare. In this work, based on the dual-linker strategy, we have designed and synthesized two new two-dimensional (2D) coordination polymers of Pb with the hcb topology, [Pb2(tpbn)(adc)2]·4H2O·0.5CH3OH}n (CP1) and {[Pb2(tpbn)(fum)2]·7H2O}n (CP2), in excellent yields by the room-temperature self-assembly of Pb(OAc)2, tpbn, and H2adc or H2fum (where tpbn = N,N',N‴,N‴'-tetrakis-(2-pyridylmethyl)-1,4-diaminobutane, H2adc = acetylene dicarboxylic acid, and H2fum = fumaric acid). In addition to determining their X-ray single crystal structures, the phase purity and thermal stability were established by powder X-ray diffraction and thermogravimetric analysis, respectively. Furthermore, these were also characterized by the microscopic techniques (SEM/EDX and TEM/HRTEM). For their conductive and highly stable nature in alkaline medium, both CP1 and CP2 were tested for their suitability in the OER process. Interestingly, with a subtle change from adc in CP1 to fumarate in CP2 as the dicarboxylate linker, the latter performed much better than the former and displayed an excellent electrochemical stability in basic medium. Remarkably, CP2 has one of the lowest Tafel values (35 mV dec-1) and a low overpotential value (140 mV vs RHE) in 0.5 M KOH compared to those reported for any materials. Such a comparative study with CP1 and CP2, which are the simplest CPs and made with green-chemistry protocols for an easy making in large quantities, provides an outlook to developing the next-generation Pb-based electrocatalysts.

A simple pyridine based fluorescent chemosensor for selective detection of copper ion.

A feasibly constructed novel pyridine based receptor (S) has been reported for the selective detection of copper ion over other metal ions. The metal sensing ability of receptor with diverse metal ions were studied by colorimetry, absorption and emission spectroscopic systems in CH3CN/H2O (7:3, v/v). This receptor reveals a drastic color converts from vapid to yellow and cyan under normal light and UV light with copper ion. Further, S-Cu2+ complex exhibits new UV-Visible band at 419 nm and intense fluorescence band at 494 nm upon the excitation at 388 nm. The stoichiometric binding ratio of receptor with metal ion was confirmed with Job's method and ESI-Mass also further supported the complexation. Besides, limits of detection of Cu2+ were calculated to be 0.25 µM. The limiting capacity of receptor with Cu2+ ion was additionally explored by quantum chemical calculation. Moreover, this receptor was effectively utilized for the measurement of Cu2+ ion in various water tests.

Rapid detection strategies for the ultra-level chemosensing of uranyl ions.

A simple and reliable colorimetric probe N,N'-bis-(4-diethylamino-2-hydroxybenzylidene)-1,10-phenanthroline-2,9-carbohydrazide (L) has been synthesised by reacting 4-(diethylamino)salicylaldehyde with 1,10-phenanthroline-2,9-dicarbohydrazide. The sensing ability of L was studied by its interactions with various f-block metal ions and other selected metal ions from s- and d-block by colorimetry, UV-visible spectrophotometry, and smartphone integrated red-green-blue (RGB) model in DMSO : H2O (7 : 3, v/v). The pale-yellow colour of L turns to wine-red upon interaction with uranyl ions (UO22+) and yellow-orange in the presence of Th4+, Zr4+, Fe3+, and Lu3+ ions. Other tested metal ions did not show any colour change of L. This color change offered a simple, quick, and consistent method for the selective and sensitive visual detection of trace levels of UO22+ ions without any need for sophisticated instruments. Sensor L exhibits two absorption bands at 358 and 389 nm due to ligand-to-ligand charge transfer (LLCT). Upon interaction of L with UO22+ and Th4+ ions, absorption bands are exhibited at 480 nm and 422 nm, respectively, due to ligand-to-metal charge transfer (LMCT). The UV-vis spectral studies indicated the formation of a 1 : 2 ligand-to-metal complex between L and UO22+ with an estimated association constant of 1.0 × 104 M-2. Using L, the concentration of UO22+ can be detected as low as 73 nM and 150 nM by spectrophotometry and RGB methods, respectively, without any interference from other tested ions with an RSD < 5% (n = 3). The binding mechanism was studied by 1H NMR titration, ESI mass, and FT-IR spectral analysis and was well supported by theoretical results. Overall, sensor L demonstrates promising analytical applicability for the detection of UO22+ ions in a semi-aqueous medium.

Liver Parenchymal Transection Through Radiofrequency Ablation Using a Radial Probe: Technical Report of a New Modality.

Various techniques have been reported to reduce blood loss during a parenchymal transection, and the radiofrequency ablation (RFA) technique is one of them. Owing to the charring of the adjacent liver tissue and the inability to use the conventional RFA techniques near major vessels, this study used a radial fiber of RFA. This technical report thus describes a technique to perform parenchymal transection using a radial fiber as well as its advantages and disadvantages. A radial fiber dissipates the energy radially and it has the added advantage of placing along the same and perpendicular axis of the liver parenchyma; it has been used in three patients in this study. The total intraoperative blood loss was 30-50 ml during parenchymal transection, and the intraoperative duration was 120-170 min. Bile leak was noted in one patient, which was then managed using the conventional treatment. Through the present technique, the fiber can be used in the vicinity of major blood vessels and necrosis and charring can be prevented. Although radial fiber has some advantages, it remains in the preliminary stage and requires further validation.

Application of Statistical Tooling Techniques for Designing of Carvedilol Nanolipid Transferosomes and its Dermatopharmacokinetic and Pharmacodynamic Studies.

BACKGROUND: The hypothesis is to augment the bioavailability and therapeutic potential of low bioavailable Carvedilol (25-35%) through Nanostructured Lipid Carrier (NLC) loaded Transdermal patch (Nanolipid Transferosomes). METHODS: Box-Behnken design was designed to formulate NLC through a hot homogenization technique. About 17 formulations (C1-C17) were formulated by varying the critical material attribute and critical process parameter. Optimization was done based on its critical quality attributes like particle size, zeta potential and entrapment efficiency. Selected NLC (C16) has been fabricated into a transdermal patch through solvent evaporation technique and estimated for thickness, weight variation, moisture content, folding endurance, drug content, in vitro drug release, ex vivo skin permeation studies 48 hrs, in vitro drug release kinetic studies and skin irritation studies. In vivo pharmacokinetics and pharmacodynamic study parameters were compared between carvedilol loaded NLC transdermal patch and a conventional formulation (Coreg CR). RESULTS: NLC (C16) was selected as the best formulation based on desirable, less particle size (201.1 ± 2.02 nm), more zeta potential (-37.2 ± 1.84mV) and maximum entrapment efficiency (87.54 ± 1.84%). Experimental investigations of in vivo dermatopharmacokinetic data shown statistically significant changes (p<0.05) in the parameter (increased AUC0-α, MRT with decreased Cmax, Tmax) when administered through the transdermal patch and on compared to the conventional dosage form. It was observed that there was a significant change with p<0.05 among the pharmacokinetic factors of conventional Carvedilol formulation, Carvedilol NLC and Carvedilol NLC loaded Transdermal patch with a maximum time of peak plasma concentration (Tmax) of 4 hrs, 8 hrs and 8 hrs; maximum peak plasma concentration (Cmax) of 0.258 µg/ml, 0.208 µg/ml and 0.108 µg/ml. Area Under Curve (AUC0-α) was established to be 125.127 µg/ml/h, 132.576 µg/ml.h and 841.032 µg/ml.h. Mean Residence Time (MRT0- α) of the drug was established to be 17 hrs, 19 hrs and 82 hrs, respectively. This data reveals the impact of NLC on the enhancement of bioavailability through a transdermal patch. In vivo pharmacodynamic studies confirm that NLC loaded transdermal patch (Nanolipid Transferosomes) shows a significant control in blood pressure for 48 hrs when compared to the conventional dosage form. CONCLUSION: This research data concludes that NLC loaded transdermal patch (Nanolipid Transferosomes) was a suitable candidate to enhance the bioavailability of low bioavailable drug-like Carvedilol. Lay Summary: It was inferred from the literature that NLC filled transdermal patches were a novel strategy to increase the solubility and permeability of Carvedilol, which has less bioavailability. It reveals that there was no reproducible preparation for the NLC. It also reveals that the option of formulation and process parameters for the formation of NLC is not clearly justified. On account of this, an uniquely validated and optimized formulation technique was developed for NLC with low soluble and poorly bioavailable carvedilol, tested in Albino wistar rats for enhancement of bioavailability, the same study has been performed and proved.

Bismuth-Oxide-Decorated Graphene Oxide Hybrids for Catalytic and Electrocatalytic Reduction of CO2.

Global warming challenges are fueling the demand to develop an efficient catalytic system for the reduction of CO2 , which would contribute significantly to the control of climate change. Herein, as-synthesized bismuthoxide-decorated graphene oxide (Bi2 O3 @GO) was used as an electro/thermal catalyst for CO2 reduction. Bi2 O3 @GO is found to be distributed uniformly, as confirmed by scanning electron and transmission electron microscopic analysis. The X-ray diffraction (XRD) pattern shows that the Bi2 O3 has a ß-phase with 23.4 m2 g-1 BET surface area. Significantly, the D and G bands from Raman spectroscopic analysis and their intensity ratio (ID /IG ) reveal the increment in defective sites on GO after surface decoration. X-ray photoelectron spectroscopic (XPS) analysis shows clear signals for Bi, C, and O, along with their oxidation states. An ultra-low onset potential (-0.534 V vs. RHE) for the reduction of CO2 on Bi2 O3 @GO is achieved. Furthermore, potential-dependent (-0.534, -0.734, and -0.934 vs. RHE) bulk electrolysis of CO2 to formate provides Faradaic efficiencies (FE) of approximately 39.72, 61.48, and 83.00 %, respectively. Additionally, in time-dependent electrolysis at a potential of -0.934 versus RHE for 3 and 5 h, the observed FEs are around 84.20 % and 87.17 % respectively. This catalyst is also used for the thermal reduction of CO2 to formate. It is shown that the thermal reduction provides a path for industrial applications, as this catalyst converts a large amount of CO2 to formate (10 mm).

Bi2O3 Nanoparticles Decorated Carbon Nanotube: An Effective Nanoelectrode for Enhanced Electrocatalytic 4-Nitrophenol Reduction.

4-Nitrophenol (4-NP) is present in most industrial waste water resources as an organic pollutant, and is a highly toxic and environmentally hazardous pollutant. Herein, we report that bismuth oxide (Bi2O3) decorated multi-walled carbon nanotubes (Bi2O3@MWCNTs) are the most prominent electrocatalyst for 4-NP electroreduction in acidic conditions. The electrocatalyst is synthesized by a simple chemical reduction method using ethylene glycol as a capping agent. The synthesized Bi2O3@MWCNTs electrocatalyst has been well-characterized by Fourier-transform infrared (FT-IR) spectroscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD), and Raman spectroscopy. Bi2O3@MWCNTs have a cubic structure which is confirmed by XRD. TEM imaging reveals Bi2O3 NPs are ~2 nm in size, are grown on MWCNTs and that these nanoparticles are active toward 4-NP electroreduction. The electrochemical studies by cyclic voltammetry measurements show that the Bi2O3@MWCNTs electrocatalyst can sense 4-NP at a very low potential i.e., -0.17 vs. saturated calomel electrode (SCE). Furthermore, electroanalytical parameters like scan rate and concentration dependence were studied with electrochemcial impedance spectroscopy (EIS) and the effect of pH on cathodic current was examined under experimental conditions. The lower limit of detection (LOD) was found to be 0.1 µM for the Bi2O3@MWCNTs nanomaterial and is excellent toward 4-NP. The present study has applications for reducing water pollution and for sorting out related issues.

What does carbon tolerant really mean? Operando vibrational studies of carbon accumulation on novel solid oxide fuel cell anodes prepared by infiltration.

Operando Raman spectroscopy and electrochemical techniques were used to examine carbon deposition on niobium doped SrTiO3 (STN) based SOFC anodes infiltrated with Ni, Co, Ce0.9Gd0.1O2 (CGO) and combinations of these materials. Cells were operated with CH4/CO2 mixtures at 750 °C. Raman data shows that carbon forms on all cells under operating conditions when Ni is present as an infiltrate. Additional experiments performed during cell cool down, and on separate material pellets (not subject to an applied potential), show that chemically labile oxygen available in the CGO infiltrate will preferentially oxidize all deposited surface carbon as temperatures drop below 700 °C. These observations highlight the benefit of CGO as a material in SOFC anodes but more importantly, the value of operando spectroscopic techniques as a tool when evaluating a material's susceptibility to carbon accumulation. Solely relying on ex situ measurements will potentially lead to false conclusions about the studied materials' ability to resist carbon and improperly inform efforts to develop mechanisms describing electrochemical oxidation and material degradation mechanisms in these high temperature energy conversion devices.

Rationally designed imidazole derivative as colorimetric and fluorometric sensor for selective, qualitative and quantitative cyanide ion detection in real time samples.

A new imidazole derivative of 1,2-diaminoanthraquinone and fluorene-2-carboxaldehyde was designed as a sensor B2 to selectively detect the cyanide (CN-) ion through colorimetric and/or fluorometric methods. The photochemical characterizations of sensor B2 were tested using absorption and emission spectral studies in CH3CN-H2O (8:2) semi-aqueous medium. An excited state proton transfer process (ESIPT) was proved by theoretical and spectral studies. The colorimetric and fluorescence detection limit of CN- ion was found to be 5.3 × 10-6 M and 4.11 × 10-8 M, respectively. 1H NMR titration, electrochemical and DFT studies were supported the removal of -NH proton from B2. In order to utilize this sensor in real-time applications, we developed a test cassette which is coated with sensor B2 detected the presence of CN- ion in the food sample with endogenous cyanide ion.

Heterostructural CuO-ZnO Nanocomposites: A Highly Selective Chemical and Electrochemical NO2 Sensor.

A simple one-step chemical method is employed for the successful synthesis of CuO(50%)-ZnO(50%) nanocomposites (NCs) and investigation of their gas sensing properties. The X-ray diffraction studies revealed that these CuO-ZnO NCs display a hexagonal wurtzite-type crystal structure. The average width of 50-100 nm and length of 200-600 nm of the NCs were confirmed by transmission electron microscopic images, and the 1:1 proportion of Cu and Zn composition was confirmed by energy-dispersive spectra, i.e., CuO(50%)-ZnO(50%) NC studies. The CuO(50%)-ZnO(50%) NCs exhibit superior gas sensing performance with outstanding selectivity toward NO2 gas at a working temperature of 200 °C. Moreover, these NCs were used for the indirect evaluation of NO2 via electrochemical detection of NO2 - (as NO2 converts into NO2 - once it reacts with moisture, resulting into acid rain, i.e., indirect evaluation of NO2). As compared with other known modified electrodes, CuO(50%)-ZnO(50%) NCs show an apparent oxidation of NO2 - with a larger peak current for a wider linear range of nitrite concentration from 20 to 100 mM. We thus demonstrate that the as-synthesized CuO(50%)-ZnO(50%) NCs act as a promising low-cost NO2 sensor and further confirm their potential toward tunable gas sensors (electrochemical and solid state) (Scheme 1).

Enhanced Overall Water-Splitting Performance: Oleylamine-Functionalized GO/Cu2ZnSnS4 Composite as a Nobel Metal-Free and NonPrecious Electrocatalyst.

Using emergent highly proficient and inexpensive non-noble metal-based bifunctional electrocatalysts to overall water splitting reaction is a pleasingly optional approach to resolve greenhouse gases and energy anxiety. In this work, oleylamine-functionalized graphene oxide/Cu2ZnSnS4 composite (OAm-GO/CZTS) is prepared and investigated as a higher bifunctional electrocatalyst for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). The OAm-GO/CZTS shows brilliant electrocatalytic performance and durability toward H2 and O2 in both acidic and basic media, with overpotentials of 47 mV for HER and 1.36 V for OER at a current density of 10 mA cm-2 and Tafel slopes of 64 and 91 mV dec-1, respectively, which are extremely higher to those of transition metal chalcogenide and as good as of commercial precious-metal catalysts.

CZTS Decorated on Graphene Oxide as an Efficient Electrocatalyst for High-Performance Hydrogen Evolution Reaction.

Cu2ZnSnS4 (CZTS) was synthesized by the sonochemical method using 2-methoxyethanol as the solvent and subsequently decorated onto graphene oxide (GO synthesized by the modified Hummers' method) using two different approaches such as in situ growth and ex situ synthesis followed by deposition. Preliminary characterizations indicated that the synthesized CZTS belongs to the kesterite structure with a sphere-like morphology. The in situ-synthesized CZTS/GO (I-CZTS/GO) composite is used as an efficient electrocatalyst for hydrogen evolution reaction (HER) which revealed superior electrocatalytic activity with a reduced overpotential (39.3 mV at 2 mA cm-2), Tafel slope (70 mV dec-1), a larger exchange current density of 908 mA cm-2, and charge transfer resistance (5 Ω), significantly different from pure CZTS. Besides, the I-CZTS/GO composite exhibits highest HER performance with high current stability of which shows no noticeable degradation after i-t amperometry. The catalytic activity demonstrates that the I-CZTS/GO composite could be a promising electrocatalyst in hydrogen production from their cooperative interactions.

Facile synthesis of highly porous CuO nanoplates (NPs) for ultrasensitive and highly selective nitrogen dioxide/nitrite sensing.

Copper oxide (CuO) nanoplates (NPs of ∼100 nm width) were successfully synthesized via a chemical method (emulsion method). Superior catalytic activities towards both chemical and electrochemical sensing of nitrite were achieved.