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1.
Nature ; 614(7949): 682-687, 2023 02.
Artigo em Inglês | MEDLINE | ID: mdl-36813895

RESUMO

The invention of scanning probe microscopy revolutionized the way electronic phenomena are visualized1. Whereas present-day probes can access a variety of electronic properties at a single location in space2, a scanning microscope that can directly probe the quantum mechanical existence of an electron at several locations would provide direct access to key quantum properties of electronic systems, so far unreachable. Here, we demonstrate a conceptually new type of scanning probe microscope-the quantum twisting microscope (QTM)-capable of performing local interference experiments at its tip. The QTM is based on a unique van der Waals tip, allowing the creation of pristine two-dimensional junctions, which provide a multitude of coherently interfering paths for an electron to tunnel into a sample. With the addition of a continuously scanned twist angle between the tip and sample, this microscope probes electrons along a line in momentum space similar to how a scanning tunnelling microscope probes electrons along a line in real space. Through a series of experiments, we demonstrate room-temperature quantum coherence at the tip, study the twist angle evolution of twisted bilayer graphene, directly image the energy bands of monolayer and twisted bilayer graphene and, finally, apply large local pressures while visualizing the gradual flattening of the low-energy band of twisted bilayer graphene. The QTM opens the way for new classes of experiments on quantum materials.

2.
Nature ; 609(7926): 276-281, 2022 09.
Artigo em Inglês | MEDLINE | ID: mdl-36071191

RESUMO

Electrical resistance usually originates from lattice imperfections. However, even a perfect lattice has a fundamental resistance limit, given by the Landauer1 conductance caused by a finite number of propagating electron modes. This resistance, shown by Sharvin2 to appear at the contacts of electronic devices, sets the ultimate conduction limit of non-interacting electrons. Recent years have seen growing evidence of hydrodynamic electronic phenomena3-18, prompting recent theories19,20 to ask whether an electronic fluid can radically break the fundamental Landauer-Sharvin limit. Here, we use single-electron-transistor imaging of electronic flow in high-mobility graphene Corbino disk devices to answer this question. First, by imaging ballistic flows at liquid-helium temperatures, we observe a Landauer-Sharvin resistance that does not appear at the contacts but is instead distributed throughout the bulk. This underpins the phase-space origin of this resistance-as emerging from spatial gradients in the number of conduction modes. At elevated temperatures, by identifying and accounting for electron-phonon scattering, we show the details of the purely hydrodynamic flow. Strikingly, we find that electron hydrodynamics eliminates the bulk Landauer-Sharvin resistance. Finally, by imaging spiralling magneto-hydrodynamic Corbino flows, we show the key emergent length scale predicted by hydrodynamic theories-the Gurzhi length. These observations demonstrate that electronic fluids can dramatically transcend the fundamental limitations of ballistic electrons, with important implications for fundamental science and future technologies.

3.
Nature ; 576(7786): E6, 2019 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-31772389

RESUMO

An Amendment to this paper has been published and can be accessed via a link at the top of the paper.

4.
Nature ; 575(7784): 628-633, 2019 11.
Artigo em Inglês | MEDLINE | ID: mdl-31634903

RESUMO

Topology is a powerful recent concept asserting that quantum states could be globally protected against local perturbations1,2. Dissipationless topologically protected states are therefore of major fundamental interest as well as of practical importance in metrology and quantum information technology. Although topological protection can be robust theoretically, in realistic devices it is often susceptible to various dissipative mechanisms, which are difficult to study directly because of their microscopic origins. Here we use scanning nanothermometry3 to visualize and investigate the microscopic mechanisms that undermine dissipationless transport in the quantum Hall state in graphene. Simultaneous nanoscale thermal and scanning gate microscopy shows that the dissipation is governed by crosstalk between counterpropagating pairs of downstream and upstream channels that appear at graphene boundaries as a result of edge reconstruction. Instead of local Joule heating, however, the dissipation mechanism comprises two distinct and spatially separated processes. The work-generating process that we image directly, which involves elastic tunnelling of charge carriers between the quantum channels, determines the transport properties but does not generate local heat. By contrast, the heat and entropy generation process-which we visualize independently-occurs nonlocally upon resonant inelastic scattering from single atomic defects at graphene edges, and does not affect transport. Our findings provide an insight into the mechanisms that conceal the true topological protection, and suggest routes towards engineering more robust quantum states for device applications.

5.
Nat Commun ; 10(1): 3334, 2019 Jul 26.
Artigo em Inglês | MEDLINE | ID: mdl-31350410

RESUMO

Van der Waals materials and their heterostructures offer a versatile platform for studying a variety of quantum transport phenomena due to their unique crystalline properties and the exceptional ability in tuning their electronic spectrum. However, most experiments are limited to devices that have lateral dimensions of only a few micrometres. Here, we perform magnetotransport measurements on graphene/hexagonal boron-nitride Hall bars and show that wider devices reveal additional quantum effects. In devices wider than ten micrometres we observe distinct magnetoresistance oscillations that are caused by resonant scattering of Landau-quantised Dirac electrons by acoustic phonons in graphene. The study allows us to accurately determine graphene's low energy phonon dispersion curves and shows that transverse acoustic modes cause most of phonon scattering. Our work highlights the crucial importance of device width when probing quantum effects and also demonstrates a precise, spectroscopic method for studying electron-phonon interactions in van der Waals heterostructures.

6.
Sci Adv ; 5(12): eaay8897, 2019 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-32064323

RESUMO

When two-dimensional (2D) atomic crystals are brought into close proximity to form a van der Waals heterostructure, neighbouring crystals may influence each other's properties. Of particular interest is when the two crystals closely match and a moiré pattern forms, resulting in modified electronic and excitonic spectra, crystal reconstruction, and more. Thus, moiré patterns are a viable tool for controlling the properties of 2D materials. However, the difference in periodicity of the two crystals limits the reconstruction and, thus, is a barrier to the low-energy regime. Here, we present a route to spectrum reconstruction at all energies. By using graphene which is aligned to two hexagonal boron nitride layers, one can make electrons scatter in the differential moiré pattern which results in spectral changes at arbitrarily low energies. Further, we demonstrate that the strength of this potential relies crucially on the atomic reconstruction of graphene within the differential moiré super cell.

7.
Nano Lett ; 18(4): 2623-2629, 2018 04 11.
Artigo em Inglês | MEDLINE | ID: mdl-29529377

RESUMO

It is well-known that superconductivity in thin films is generally suppressed with decreasing thickness. This suppression is normally governed by either disorder-induced localization of Cooper pairs, weakening of Coulomb screening, or generation and unbinding of vortex-antivortex pairs as described by the Berezinskii-Kosterlitz-Thouless (BKT) theory. Defying general expectations, few-layer NbSe2, an archetypal example of ultrathin superconductors, has been found to remain superconducting down to monolayer thickness. Here, we report measurements of both the superconducting energy gap Δ and critical temperature TC in high-quality monocrystals of few-layer NbSe2, using planar-junction tunneling spectroscopy and lateral transport. We observe a fully developed gap that rapidly reduces for devices with the number of layers N ≤ 5, as does their TC. We show that the observed reduction cannot be explained by disorder, and the BKT mechanism is also excluded by measuring its transition temperature that for all N remains very close to TC. We attribute the observed behavior to changes in the electronic band structure predicted for mono- and bi- layer NbSe2 combined with inevitable suppression of the Cooper pair density at the superconductor-vacuum interface. Our experimental results for N > 2 are in good agreement with the dependences of Δ and TC expected in the latter case while the effect of band-structure reconstruction is evidenced by a stronger suppression of Δ and the disappearance of its anisotropy for N = 2. The spatial scale involved in the surface suppression of the density of states is only a few angstroms but cannot be ignored for atomically thin superconductors.

8.
Nat Commun ; 8: 14552, 2017 02 17.
Artigo em Inglês | MEDLINE | ID: mdl-28211517

RESUMO

An energy gap can be opened in the spectrum of graphene reaching values as large as 0.2 eV in the case of bilayers. However, such gaps rarely lead to the highly insulating state expected at low temperatures. This long-standing puzzle is usually explained by charge inhomogeneity. Here we revisit the issue by investigating proximity-induced superconductivity in gapped graphene and comparing normal-state measurements in the Hall bar and Corbino geometries. We find that the supercurrent at the charge neutrality point in gapped graphene propagates along narrow channels near the edges. This observation is corroborated by using the edgeless Corbino geometry in which case resistivity at the neutrality point increases exponentially with increasing the gap, as expected for an ordinary semiconductor. In contrast, resistivity in the Hall bar geometry saturates to values of about a few resistance quanta. We attribute the metallic-like edge conductance to a nontrivial topology of gapped Dirac spectra.

9.
Biospectroscopy ; 4(4): 257-66, 1998.
Artigo em Inglês | MEDLINE | ID: mdl-9706384

RESUMO

X-ray photoelectron spectroscopy (XPS) is a surface sensitive analytical technique that measures the binding energy of electrons in atoms and molecules on the surface of a material. XPS was used to determine the distribution of the oligosaccharide side chains in the glycoprotein, MUC1 mucin. Low-resolution XPS spectra provided elemental composition of MUC1 mucin (fully glycosylated), mucin polypeptide (nonglycosylated), and carbohydrates found in mucin. The nitrogen content of MUC1 mucin was determined to be intermediate between the mucin polypeptide and the carbohydrates. Assuming a uniform distribution of carbohydrate on MUC1 mucin, the average thickness of the carbohydrate layer was calculated to be 4.9 nm using the low-resolution N 1s signals. High-resolution XPS spectra give detailed information about the chemical bonding of the surface molecules. Calculations based on the high-resolution O 1s spectra showed a carbohydrate thickness of 6.6 nm. These experimentally determined values agree reasonably well with an estimated 5 nm of carbohydrate thickness from a simple model which assume that the core protein is a rodlike molecule approximately 5 nm in diameter. Although the carbohydrate coating on the MUC1 mucin appears to be thick enough to cover the core protein entirely, fully glycosylated breast milk MUC1 mucin is susceptible to proteolytic digestion without removal of any oligosaccharide side chain, suggesting areas of exposed core protein. A possible explanation is that the oligosaccharide side chains may form patches of carbohydrate along the core protein with regions of exposed core protein.


Assuntos
Mucina-1/química , Sequência de Aminoácidos , Configuração de Carboidratos , Sequência de Carboidratos , Microanálise por Sonda Eletrônica/métodos , Epitopos/química , Humanos , Modelos Moleculares , Dados de Sequência Molecular , Conformação Proteica , Propriedades de Superfície
10.
Int J Obes Relat Metab Disord ; 21(10): 891-6, 1997 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-9347407

RESUMO

OBJECTIVE: To estimate the costs of health care that are attributable to obesity in New Zealand. METHODS: The 1991 health care costs of non-insulin dependent diabetes, coronary heart disease, hypertension, gallstone disease, post-menopausal breast cancer and colon cancer were estimated and multiplied by the population attributable factor for obesity for each condition. The relative risk estimates were taken from the literature, the obesity prevalence from a 1990 New Zealand survey, and the costs and volumes of services were taken from a variety of sources and covered hospital (inpatient and outpatient) services, general practitioner consultations, pharmaceuticals, laboratory tests and ambulance services. Calculations were conservative and net of goods and services tax. RESULTS: A conservative estimate of the health care costs attributable to obesity for the six conditions was NZ$135 million. This represents about 2.5% of total health care costs which is similar to analyses from other countries. CONCLUSIONS: The health care costs of obesity as estimated are considerable. However, the total cost of overfatness to the New Zealand population is far greater than this because lesser degrees of overfatness, the health care costs of other obesity-related conditions such as arthritis, the costs to individuals of weight-loss programs and the indirect and intangible costs were not included in the analysis. A substantial and wide-ranging public health effort is needed to turn around the increasing prevalence and costs of obesity.


Assuntos
Custos de Cuidados de Saúde , Obesidade/economia , Adulto , Neoplasias da Mama/economia , Colelitíase/economia , Neoplasias do Colo/economia , Doença das Coronárias/economia , Efeitos Psicossociais da Doença , Diabetes Mellitus Tipo 2/economia , Feminino , Humanos , Hipertensão/economia , Masculino , Pessoa de Meia-Idade , Nova Zelândia , Obesidade/complicações
12.
N Z Med J ; 105(935): 221-4, 1992 Jun 10.
Artigo em Inglês | MEDLINE | ID: mdl-1598146

RESUMO

1. Weaning is the process by which the milk fed infant is gradually accustomed to a varied diet. 2. The time at which weaning should commence should be signalled by the infant's being dissatisfied with a milk diet. While this tends to occur around five to six months of age, it may be later. 3. Appropriate foods to start weaning should be almost liquid in consistency, provide useful nutrients, and be of low allergenicity. 4. The aim is to achieve a diet based on family foods. These should conform to the criteria for a healthful diet, but should not be especially low in fat or rich in fibre. 5. In the earlier stages breast milk or formula remains the principal source of nutrition. Weaning foods should not be used in a way which discourages consumption of milks. 6. Water or diluted fruit juice may be used to assuage thirst, but should not supplant milk even in the later stages of weaning, since they contain no calcium or most other essential micronutrients. Tea and coffee are not suitable drinks for young children.


Assuntos
Desmame , Fatores Etários , Hipersensibilidade Alimentar/etiologia , Hipersensibilidade Alimentar/prevenção & controle , Humanos , Lactente , Alimentos Infantis , Fenômenos Fisiológicos da Nutrição do Lactente
13.
Lancet ; 338(8772): 949-50, 1991 Oct 12.
Artigo em Inglês | MEDLINE | ID: mdl-1681295
14.
N Z Med J ; 102(860): 24, 1989 Jan 25.
Artigo em Inglês | MEDLINE | ID: mdl-2521529
15.
N Z Med J ; 101(851): 521, 1988 Aug 10.
Artigo em Inglês | MEDLINE | ID: mdl-3405537
16.
N Z Med J ; 101(849): 465, 1988 Jul 13.
Artigo em Inglês | MEDLINE | ID: mdl-3399196
18.
N Z Med J ; 101(841): 122, 1988 Mar 09.
Artigo em Inglês | MEDLINE | ID: mdl-3380452
20.
N Z Med J ; 101(838): 27-8, 1988 Jan 27.
Artigo em Inglês | MEDLINE | ID: mdl-3380414
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