On Roth's "human fossil" from Baradero, Buenos Aires Province, Argentina: morphological and genetic analysis.

The "human fossil" from Baradero, Buenos Aires Province, Argentina, is a collection of skeleton parts first recovered by the paleontologist Santiago Roth and further studied by the anthropologist Rudolf Martin. By the end of the nineteenth century and beginning of the twentieth century it was considered one of the oldest human skeletons from South America's southern cone. Here, we present the results of an interdisciplinary approach to study and contextualize the ancient individual remains. We discuss the context of the finding by first compiling the available evidence associated with the historical information and any previous scientific publications on this individual. Then, we conducted an osteobiographical assessment, by which we evaluated the sex, age, and overall preservation of the skeleton based on morphological features. To obtain a 3D virtual reconstruction of the skull, we performed high resolution CT-scans on selected skull fragments and the mandible. This was followed by the extraction of bone tissue and tooth samples for radiocarbon and genetic analyses, which brought only limited results due to poor preservation and possible contamination. We estimate that the individual from Baradero is a middle-aged adult male. We conclude that the revision of foundational collections with current methodological tools brings new insights and clarifies long held assumptions on the significance of samples that were recovered when archaeology was not yet professionalized.

Assessment of cation exchange as conditioning processes of water chemistry in freshwater lenses.

Freshwater lenses are groundwater sources of limited dimensions that can be usually found in a variety of climates worldwide. These aquifers' quality is important for socioeconomic development, being cation exchange one of the most important geochemical processes that can change the water geochemistry. This study aims to assess the cation exchange processes that determine the chemistry of freshwater lenses in a multilayer aquifer type, considering the center-east of the Pampean Region (Argentina) as a case study. Water samples were taken from the freshwater lenses at different depths to analyze major ions in the laboratory. In addition, geological profiles were made along with the extraction of sediment samples for X-ray diffractometry (XRD) and laboratory tests to analyze the cation exchange capacity. The results show that water stored in the lenses has a vertical facies variation from Ca-HCO3 to Na-HCO3 . According to the laboratory results, the change of water facies mainly occurs in the clayey sediments that divide the carbonate bioclastic material above and the loessic sediment below, being cation exchange the most important process. PRACTITIONER POINTS: Cation exchange is the main geochemical process regulating groundwater chemistry. Hydrochemical changes determine the quality of freshwater lenses. Na/Ca exchange is mainly regulated by the groundwater flow into the bioturbated clay. Batch exchange tests were also carried out to quantify the Na/Ca exchange processes.

Role of rock glaciers and other high-altitude depositional units in the hydrology of the mountain watersheds of the Northern Patagonian Andes.

Mountain depositional landforms are important units for freshwater supply in regions with water deficits and significant droughts during the summer season. In the Northern Patagonian Andes, the cold climatic events during the Pleistocene period left a large number of glacial and periglacial depositional landforms, among which a glacial cirque called La Hoya stands out. An analysis of geomorphological landforms, climatic data, soil temperature, flows in springs and streams, electrical conductivity measurements, and stable isotope determination of water, were made to study the hydrological role of these depositional mountain landforms. In this region, precipitations are concentrate during the winter season when an important snow cover accumulates and persists until spring. During winter and spring seasons, part of the snowmelt infiltrates, being kept in solid states inside the depositional landforms, and part of it contributes to the runoff between winter and summer. At the ends of spring and early summer, the snowmelt is the main water contribution to the La Hoya watershed. During late summer and autumn, the most important water contribution is from groundwater discharge. Where glacial ice is absent and the presence of permafrost is limited or non-existent, morphosedimentary units are important landforms for water storage and streams sustenance. This is the case of the city of Esquel, which depends exclusively on the "Los Bandidos" stream for water supply, which is sustained throughout the year by these landforms. The increase in temperature and the decrease in precipitation in this region highlights the importance of the high-altitude depositional landforms for the capture, storage, and distribution of water resources in the Northern Patagonian Andes.

Flood hazard assessment in large plain basins with a scarce slope in the Pampean Plain, Argentina.

Floods are one of the most common natural phenomena and represent a serious hazard when they affect human activities. Structural measures are commonly used to mitigate them; however, these do not always give good results, mainly in plain areas with scarce slope. In this sense, the generation of a flood hazard map contributes to adequate hazard management and disaster prevention. The aim of this work is to evaluate the flood hazard areas in hydrological plain basins with scarce slope, taking as a case study the Samborombón river basin located in the Pampean Plain, Argentina. For this, a flood hazard map was made based on the analytical hierarchy process and using a GIS, taking into account physical aspects of the terrain, observations, and field measurements. Likewise, the map was validated using satellite images and the inhabitants in danger in the basin were quantified. The results show that the flood hazard areas correspond mainly to the floodplain of rivers and tributaries, while the main and secondary divide zones have low flood hazard sectors. On the other hand, numerous urban settlements were identified within flood hazard areas, these being urban settlements in the vicinity of old urban centers and new gated communities with high value homes, quantifying 1961 inhabitants at flood hazard and showing poor territorial planning. The methodology proposed gives to the management agencies the possibility of generating land use maps, as well as designing mitigation and contingency plans after a large rainfall event.

Hydrodynamic and hydrochemistry of wet meadows and shallow lakes in areas of the Patagonian basaltic plateaus, Argentina.

Extra-Andean Patagonia, located in the south end of South America, is a wide arid region where the basaltic plateau landscape dominates. Associated with the basaltic plateaus, wet meadows and shallow lakes make up environments of relevance due to the ecosystemic services they provide. The aim of this work was to define the processes and factors that condition the hydrodynamics and hydrogeochemistry of wet meadows and shallow lakes in a sector of the Patagonian plateau basalts. For this, detailed geological and geomorphological studies were carried out and water was sampled at 29 points for the analysis of major ions and, in some samples, stable isotopes of the water molecule. Values of δ18O and δ2H similar to the local meteoric line in the water of wet meadows indicate that rainwater quickly infiltrates through the fractures of the basaltic plateaus and stores in the underlying sediments. Groundwater discharge occurs in the scarp zone due to changes in sediment permeability. The weathering of silicates in basalts, ion exchange in the sediment clays, and the dissolution of soluble salts provided by the dust control water chemistry of this wetland. Water from wet meadows drains into saline endorheic basins of sodium chloride composition where the isotopic signal is indicative of evaporation percentages close to 95%. The high evaporation rates cause the precipitation of evaporitic salts at the edges of shallow lakes with carbonate, sulfate, and chloride species controlled by the dominance of sodium in the water.

Geogenic arsenic contamination of wet-meadows associated with a geothermal system in an arid region and its relevance for drinking water.

Arsenic (As) is an important component in thermal springs, which can reach water sources constituting an important hazard for both the environment and people. For this reason, the aim of this paper is to analyze the geologic and geochemical processes that determine the presence and concentration of As in wet-meadows associated to a geothermal field in Patagonia (Argentina) which is used as water supply. To achieve this, during field surveys temperature, pH and electrical conductivity were measured and water and rock samples were taken. Major ions and stable isotopes were determined in water samples while As content was analyzed in both water and rock samples. Due to geological control and chemical analyses, three areas were recognized with respect to major streams in the geothermal field: wet-meadows at headwaters, thermal springs at mid basin and wet-meadows at down basin. Even though, water in wet-meadows have the same origin the obtained results evidence how thermal springs at mid-basin influence the chemistry of these wetlands, particularly those at down basin. In the latter, As raises over two orders of magnitude than the ones at headwaters which surpasses the reference limit, proving that thermal springs are also responsible for the increase of the As content in water changing its quality as a source of potable water. The concentration of this metalloid could be higher but it is retained in travertine and sinter deposits formed near the geothermal discharge area. Understanding processes controlling water quality and the chemistry of As in this type of wetlands is of vital importance, mainly in an arid region where water supply sources are scarce.

Geochemical mechanisms controlling the isotopic and chemical composition of groundwater and surface water in a sector of the Pampean plain (Argentina).

The Samborombón River basin, which has eminently rural characteristics, develops within the Pampean plain along with other basins with serious contamination problems due to the growth of the industrial activities and the absence of a proper groundwater management. Considering that the knowledge of the natural baseline quality is important to measure an imposed environmental change, the aim of this work was to study the mechanisms that control the natural composition of groundwater and superficial water in the Samborombón River basin. In order to achieve this, detailed analysis of the minerals forming the aquifer matrix along with the data obtained from isotopes, major and trace elements were performed. Geochemical processes that define the chemical characteristics and contribute to the evolution of both surface and groundwater are associated with rainwater infiltration, carbonate dissolution, cation exchange and evaporation. Additionally, the low concentration of heavy metals may respond to natural background levels. Comprehending the hydrochemical processes governing groundwater and superficial water quality, particularly in a rural area where water supply is vital for the development of human activities, is essential to prevent environmental deterioration and thus, enhance socio-economic growth.

Assessment of factors enabling halite formation in a marsh in a humid temperate climate (Ajó Marsh, Argentina).

The formation of evaporites associated with the final stages of the precipitation sequence, such as the case of halite, is frequent in marshes in arid areas, but it is not to be expected in those humid climates. This work, by means of the study of the hydrological, climatic and land use conditions, identifies the factors that allow the formation of saline precipitations in a marsh located in a humid climate area. The results obtained show that the exclusion of the marsh as a result of the embankment is the main reason for the presence of halite. It is to be expected that in the future the growth of the embanked marsh areas, together with the climatic and tidal condition tendencies recorded, will favour a higher rate of formation of evaporite salts. The identification of these factors makes it possible to set basic sustainable management guidelines to avoid soil salinisation.

Geochemical processes regulating F-, as and NO3- content in the groundwater of a sector of the Pampean Region, Argentina.

The presence of F(-) and As in groundwater is common in volcanic aquifers. Excessive concentrations of these ions affect the quality of drinking water and can be harmful to health. When there is an anthropogenic source in phreatic aquifers, NO3(-) is incorporated to the groundwater components, deteriorating its quality. The objective of this work is to assess the geochemical processes that regulate the contents of F(-), As and NO3(-) of the groundwater in a sector of the Pampean Region in Argentina. This area is supplied with water by exploiting a multilayer aquifer, composed of a phreatic aquifer occurring in loess sediments and a fluvial semi-confined aquifer, separated by an aquitard. The results obtained show that the phreatic aquifer has a higher concentration of F(-), As and NO3(-) than the semi-confined aquifer. Fluoride derives from the dissolution of volcanic glass at a slightly alkaline pH and from anion exchange; however, it may also be absorbed by the reprecipitating carbonates. The As is released by desorption, with the main source being the glass and lithic fragments of the loess. The NO3(-) originates from the decomposition of organic matter, mainly in the septic tanks of the peri-urban areas. Meanwhile, the As and F(-) content in the semi-confined aquifer is lower and its origin is the result of water inflow by vertical downward infiltration from the phreatic aquifer through the aquitard. The Pampean Region is one of the areas with the largest volume of agricultural exports in the world and at present it is undergoing a strong social and economic growth. Understanding the geochemical processes that regulate the quality of drinking water is of vital importance to generate water management guidelines aiming at minimizing the deterioration of drinking water sources.