Experimental Investigation of the Thermal Emission Cross Section of Nanoresonators Using Hierarchical Poisson-Disk Distributions.

Effective cross sections of nano-objects are fundamental properties that determine their ability to interact with light. However, measuring them for individual resonators directly and quantitatively remains challenging, particularly because of the very low signals involved. Here, we experimentally measure the thermal emission cross section of metal-insulator-metal nanoresonators using a stealthy hyperuniform distribution based on a hierarchical Poisson-disk algorithm. In such distributions, there are no long-range interactions between antennas, and we show that the light emitted by such metasurfaces behaves as the sum of cross sections of independent nanoantennas, enabling direct retrieval of the single resonator contribution. The emission cross section at resonance is found to be on the order of λ_{0}^{2}/3, a value that is nearly 3 times larger than the theoretical maximal absorption cross section of a single particle, but remains smaller than the maximal extinction cross section. This measurement technique can be generalized to any single resonator cross section, and we also apply it to a lossy dielectric layer.

Over-coupled resonator for broadband surface enhanced infrared absorption (SEIRA).

Detection of molecules is a key issue for many applications. Surface enhanced infrared absorption (SEIRA) uses arrays of resonant nanoantennas with good quality factors which can be used to locally enhance the illumination of molecules. The technique has proved to be an effective tool to detect small amount of material. However, nanoresonators can detect molecules on a narrow bandwidth so that a set of resonators is necessary to identify a molecule fingerprint. Here, we introduce an alternative paradigm and use low quality factor resonators with large radiative losses (over-coupled resonators). The bandwidth enables to detect all absorption lines between 5 and 10 µm, reproducing the molecular absorption spectrum. Counterintuitively, despite a lower quality factor, the system sensitivity is improved and we report a reflectivity variation as large as one percent per nanometer of molecular layer of PMMA. This paves the way to specific identification of molecules. We illustrate the potential of the technique with the detection of the explosive precursor 2,4-dinitrotoluene (DNT). There is a fair agreement with electromagnetic simulations and we also introduce an analytic model of the SEIRA signal obtained in the over-coupling regime.

Helmholtz Resonator Applied to Nanocrystal-Based Infrared Sensing.

While the integration of nanocrystals as an active medium for optoelectronic devices progresses, light management strategies are becoming required. Over recent years, several photonic structures (plasmons, cavities, mirrors, etc.) have been coupled to nanocrystal films to shape the absorption spectrum, tune the directionality, and so on. Here, we explore a photonic equivalent of the acoustic Helmholtz resonator and propose a design that can easily be fabricated. This geometry combines a strong electromagnetic field magnification and a narrow channel width compatible with efficient charge conduction despite hopping conduction. At 80 K, the device reaches a responsivity above 1 A·W-1 and a detectivity above 1011 Jones (3 µm cutoff) while offering a significantly faster time-response than vertical geometry diodes.

High-efficiency second-harmonic generation in coupled nano Fabry-Perot thin resonators.

In this paper we experimentally demonstrate second-harmonic generation (SHG) enhancement in thin 1D periodic plasmonic nanostructures on GaAs in the infrared spectral range. Due to the properly designed coupling of horizontal Fabry-Perot nanoresonators that occurs inside these structures, the obtained conversion efficiencies go up to the 10-7 W-1 range. Moreover, we demonstrate that the engineering of the plasmonic nanoantenna dimensions on the same GaAs layer can lead to SHG enhancement for pump wavelengths ranging from 2.8 µm to 3.3 µm.

Rapid prototyping of a bispectral terahertz-to-infrared converter.

Conversion of terahertz radiation into thermal radiation is a promising approach for the development of low cost terahertz instruments. Here, we experimentally demonstrate bispectral terahertz-to-infrared conversion using metamaterials fabricated using a rapid prototyping technique. The converter unit cell is composed of two metal-insulator-metal (MIM) antennas absorbing independently the terahertz radiation at 96 and 130 GHz and a thin carbon nanotubes (CNT) layer used as a thermal emitter. The converter unit cell has a typical λ/100 thickness and sub-wavelength lateral dimensions. The terahertz absorption of the converter was observed by monitoring its thermal emission using an infrared camera. Within the first hundred milliseconds of the terahertz pulse, thermal radiation from the CNTs only increases at the location of the MIM antennas, thus allowing to record the terahertz response of each MIM antenna independently. Beyond 100 ms, thermal diffusion causes significant cross-talk between the pixels, so the spectral information is more difficult to extract. In a steady state regime, the minimum terahertz power that can be detected is 5.8 µW at 130 GHz. We conclude that the converter provides a suitable low-cost solution for fast multi-spectral terahertz imaging with resolution near the diffraction limit, using an infrared camera in combination with a tunable source.

Towards perfect metallic behavior in optical resonant nanostructures.

Looking for a perfect metallic behavior is a crucial research line for metamaterials scientists. This paper outlines a versatile strategy based on a contrast of dielectric index to control dissipative losses in metal within waveguides and resonant nanostructures. This permits us to tune the quality factor of the guided mode and of the resonance over a large range, up to eight orders of magnitude, and over a broad spectral band, from visible to millimeter waves. An interpretation involving a low-loss equivalent model for the metal is developed. The latter is based on a Drude model, in which the dissipative parameter can reach very low values, which amounts to a nearly perfect metallic behavior. Finally, this concept is applied to a practical design that permits us to finely control the localization of dissipation in an absorbing photonic structure.

Experimental demonstration of second-harmonic generation in high χ2 metasurfaces.

Metasurfaces able to concentrate light at various wavelengths are promising for enhancing nonlinear interactions. In this Letter, we experimentally demonstrate infrared second-harmonic generation (SHG) by a multi-resonant nanostructure. A 100 GaAs layer embedded in a metal-insulator-metal waveguide is shown to support various localized resonances. One resonance enhances the nonlinear polarization due to the transverse magnetic (TM)-polarized pump wavelength near 3.2µm, while another is set near the TE-polarized generated wavelength (1.6µm). The measured SHG efficiency is higher than 10-9W-1 for pump wavelengths ranging from 2.9 to 3.3µm, which agrees with theoretical computations. This is typically 4 orders of magnitude higher than the equivalent GaAs membrane.

Hybrid modes in a single thermally excited asymmetric dimer antenna.

The study of hybrid modes in a single dimer of neighboring antennas is an essential step to optimize the far-field electromagnetic (EM) response of large-scale metasurfaces or any complex antenna structure made up of subwavelength building blocks. Here we present far-field infrared spatial modulation spectroscopy (IR-SMS) measurements of a single thermally excited asymmetric dimer of square metal-insulator-metal (MIM) antennas separated by a nanometric gap. Through thermal fluctuations, all the EM modes of the antennas are excited, and hybrid bonding and anti-bonding modes can be observed simultaneously. We study the latter within a plasmon hybridization model, and analyze their effect on the far-field response.

Spectrally exclusive phase masks for wavefront coding.

The use of phase masks is necessary for wavefront coding, and these are often based on optical path differences. However, the optical dispersion constrains the resulting device to operate within a restricted spectral bandwidth. Here we propose to remove this constraint due to sub-wavelength structuration of the surface. The use of spatial and spectral co-localization properties of these structures allows the production of various spectrally exclusive phase masks on the same area.

Dispersion-based intertwined SEIRA and SPR effect detection of 2,4-dinitrotoluene using a plasmonic metasurface.

Surface enhanced infrared absorption (SEIRA) spectroscopy and surface plasmon resonance (SPR) make possible, thanks to plasmonics nanoantennas, the detection of low quantities of biological and chemical materials. Here, we investigate the infrared response of 2,4-dinitrotoluene deposited on various arrays of closely arranged metal-insulator-metal (MIM) resonators and experimentally show how the natural dispersion of the complex refractive index leads to an intertwined combination of SEIRA and SPR effect that can be leveraged to identify molecules. They are shown to be efficient for SEIRA spectroscopy and allows detecting of the dispersive explosive material, 2,4-dinitrotoluene. By changing the in-plane parameters, a whole spectral range of absorptions of 2,4-DNT is scanned. These results open the way to the design of sensors based on SEIRA and SPR combined effects, without including a spectrometer.

4000-enhancement of difference frequency generation in a mode-matching metamaterial.

In the wake of the control of light at the sub-wavelength scale by nanoresonators, metasurfaces allowing strong field exaltations are an attractive platform to enhance nonlinear processes. Recently, high efficiency second harmonic and difference frequency generations were demonstrated in metasurfaces that generate a nonlinear polarization normal to the surface. Here, we introduce a mode matched resonator that is able to produce this particular nonlinear polarization in a layer of gallium arsenide associated with a gold metasurface. The nonlinear conversion mechanism is described as a two-step process in which efficiency is shown to yield a good colocalization and a strong enhancement of the pump fields, as well as a high extraction efficiency of the generated field. This mode-matched metasurface is able to reach a difference frequency generation (DFG) efficiency of 10-2W/W2. This opens a new paradigm where alternative nonlinear materials could be reintroduced in metasurfaces and yields even higher efficiency than high effective χ(2) structures.

Three multispectral configurations of a snapshot kaleidoscope-based camera in long wavelength infrared spectral band.

In the field of spectral imaging, numerous instruments use scanning-based technologies. However, the temporal dimension of these systems, whether to scan the spectrum or scan the scene, can be an issue for some applications. This is particularly the case when trying to observe and identify rapid temporal variations in a fixed scene or detecting objects of interest when moving. In this case, it is suitable to observe the desired spectral information of the scene simultaneously, and so-called snapshot systems have been thus investigated. In this paper, we study the ability of a kaleidoscope-based multiview camera to acquire multispectral information in the long wavelength infrared. Several strategies and technologies will be compared to add the spectral function inside the different blocks of a kaleidoscope-based camera: the front lens, the kaleidoscope, or the reimaging lens. The studied camera uses an uncooled infrared detector and thus must deal with the issue of having a large aperture.

Study of disordered metallic groove arrays with a one-mode analytical model.

Sub-wavelength metallic grooves behave as Fabry-Perot nanocavities able to resonantly enhance the absorption of light as well as the intensity of the electromagnetic field. Here, with a one-mode analytical model, we investigate the effect of a correlated disorder on 1D groove arrays i.e., randomly shaped and positioned grooves on a metallic layer. We show that a jitter-based disorder leads to a redistribution of energy compared to the periodic case. In an extreme case, a periodic diffracting array can be converted into a highly scattering array (98% at λ = 2.8 µm with a 1 µm full width at half maximum). Eventually, we show that the optical response of combinations of variously shaped grooves can be well described by the individual sub-set behaviors.

Near-Field and Far-Field Thermal Emission of an Individual Patch Nanoantenna.

The far-field spectral and near-field spatial responses of an individual metal-insulator-metal nanoantenna are reported, using thermal fluctuations as an internal source of the electromagnetic field. The far-field spectra, obtained by combining Fourier transform infrared spectroscopy with spatial modulation based on a light falloff effect in a confocal geometry, have revealed two distinct emission peaks attributed to the excitation of the fundamental mode of the nanoantenna at two distinct wavelengths. Superresolved near-field images of the thermally excited mode have been obtained by thermal radiation scanning tunneling microscopy. Experimental results are supported by numerical simulations showing that it is possible to excite the same mode at different wavelengths near a resonance of the insulating dielectric material forming the antenna.

High-quality-factor double Fabry-Perot plasmonic nanoresonator.

Fabry-Perot (FP)-like resonances have been widely described in nanoantennas. In the original FP resonator, a third mirror can be added, resulting in a multimirror interferometer. However, in the case of a combination of nanoantennas, it has been reported that each cavity behaves independently. Here, we evidence the interferences between two FP absorbing nanoantennas through a common mirror, which has a strong impact on the optical behavior. While the resonance wavelength is only slightly shifted, the level of absorption reaches nearly 100%. Moreover, the quality factor increases up to factor 7 and can be chosen by geometric design over a range from 11 to 75. We demonstrate, thanks to a simple analytical model, that this coupling can be ascribed to a double FP cavity resonance, with the unique feature that each cavity is separately coupled to the outer medium.

Two-mode model for metal-dielectric guided-mode resonance filters.

Symmetric metal-dielectric guided-mode resonators (GMR) can operate as infrared band-pass filters, thanks to high-transmission resonant peaks and good rejection ratio. Starting from matrix formalism, we show that the behavior of the system can be described by a two-mode model. This model reduces to a scalar formula and the GMR is described as the combination of two independent Fabry-Perot resonators. The formalism has then been applied to the case of asymmetric GMR, in order to restore the properties of the symmetric system. This result allows designing GMR-on-substrate as efficient as free-standing systems, the same high transmission maximum value and high quality factor being conserved.

Extraordinary transmission in optical Helmholtz resonators.

Optical Helmholtz resonators (OHRs) have been adapted from acoustics designs for light absorbing structures, exhibiting extreme light confinement. Here, extraordinary transmission of light is theoretically demonstrated through symmetric OHRs, comprising a cavity with two λ/500 narrow slits on either side. This device has appealing features to act as a spectral bandpass filter in the context of multispectral imaging, in particular its high angular tolerance because of the localized nature of the resonance. Besides, the cavity can be modeled as an inductor and the two slits can be modeled as capacitors, the whole design acting as a LC circuit thus preventing any harmonic features.

Electromagnetic modelization of spherical focusing on a one-dimensional grating thanks to a conical B-spline modal method.

Focusing light onto nanostructures thanks to spherical lenses is a first step in enhancing the field and is widely used in applications. Nonetheless, the electromagnetic response of such nanostructures, which have subwavelength patterns, to a focused beam cannot be described by the simple ray tracing formalism. Here, we present a method for computing the response to a focused beam, based on the B-spline modal method adapted to nanostructures in conical mounting. The eigenmodes are computed in each layer for both polarizations and are then combined for the computation of scattering matrices. The simulation of a Gaussian focused beam is obtained thanks to a truncated decomposition into plane waves computed on a single period, which limits the computation burden.

Analytical description of subwavelength plasmonic MIM resonators and of their combination.

We show that a periodic array of metal-insulator-metal resonators can be described as a high refractive index metamaterial. This approach permits to obtain analytically the optical properties of the structure and thus to establish conception rules on the quality factor or on total absorption. Furthermore, we extend this formalism to the combination of two independent resonators.

Fast modal method for crossed grating computation, combining finite formulation of Maxwell equations with polynomial approximated constitutive relations.

We present a modal method for the fast analysis of 2D-layered gratings. It combines exact discrete formulations of Maxwell equations in 2D space with polynomial approximations of the constitutive equations, and provides a sparse formulation of the eigenvalue equations. In specific cases, the use of sparse matrices allows us to calculate the electromagnetic response while solving only a small fraction of the eigenmodes. This significantly increases computational speed up to 100×, as shown on numerical examples of both dielectric and metallic subwavelength gratings.