Macroscopic dynamics of the ferroelectric smectic [Formula: see text] phase with [Formula: see text] symmetry.

We present the macroscopic dynamics of ferroelectric smectic A, smectic [Formula: see text], liquid crystals reported recently experimentally by three groups. In this fluid and orthogonal smectic phase, the macroscopic polarization, [Formula: see text], is parallel to the layer normal thus giving rise to [Formula: see text] overall symmetry for this phase in the spatially homogeneous limit. A combination of linear irreversible thermodynamics and symmetry arguments is used to derive the resulting dynamic equations applicable at sufficiently low frequencies and sufficiently long wavelengths. Compared to non-polar smectic A phases, we find a static cross-coupling between compression of the layering and bending of the layers, which does not lead to elastic forces, but to elastic stresses. In addition, it turns out that a reversible cross-coupling between flow and the magnitude of the polarization modifies the velocities of both, first and second sound. At the same time, the relaxation of the polarization gives rise to dissipative effects for second sound at the same order of the wavevector as for the sound velocity. We also analyze reversible cross-coupling terms between elongational flow and electric fields as well as temperature and concentration gradients, which lend themselves to experimental detection. Apparently this type of terms has never been considered before for smectic phases. The question how the linear [Formula: see text] coupling in the energy alters the macroscopic response behavior when compared to usual non-polar smectic A phases is also addressed.

Characterization of time-dependence for dissipative solitons stabilized by nonlinear gradient terms: Periodic and quasiperiodic vs chaotic behavior.

We investigate the properties of time-dependent dissipative solitons for a cubic complex Ginzburg-Landau equation stabilized by nonlinear gradient terms. The separation of initially nearby trajectories in the asymptotic limit is predominantly used to distinguish qualitatively between time-periodic behavior and chaotic localized states. These results are further corroborated by Fourier transforms and time series. Quasiperiodic behavior is obtained as well, but typically over a fairly narrow range of parameter values. For illustration, two examples of nonlinear gradient terms are examined: the Raman term and combinations of the Raman term with dispersion of the nonlinear gain. For small quintic perturbations, it turns out that the chaotic localized states are showing a transition to periodic states, stationary states, or collapse already for a small magnitude of the quintic perturbations. This result indicates that the basin of attraction for chaotic localized states is rather shallow.

External concentration gradients can drive a propagating wave in a coherently layered system of nanosheets.

We present a model for the dynamics observed recently by Sano et al. [Nat. Commun. 12, 6771 (2021)] in a coherently layered system made up of sheetlike colloidal particles (nanosheets) subjected to an external concentration gradient. Adding a new macroscopic variable characteristic for the nonequilibrium situation encountered in the experiments to the hydrodynamics of smectic A liquid crystals, we show that all salient dynamic features observed in the experiments can be accounted for. For this nonequilibrium phenomenon, we identify the symmetry of the underlying ground state as undulating smectic A-like layering and the applied concentration gradient applied in the layer planes as the nonequilibrium driving force. As a result of our analysis, we find a coherent motion of undulating layers generated by a Helfrich-Hurault type instability propagating at a fixed velocity in accordance with the observations. If the coherence of the layering is lost, there is no longer any coherent propagation to be expected-as is also observed.

Oscillatory dissipative solitons stabilized by nonlinear gradient terms: The transition to localized spatiotemporal disorder.

We investigate properties of oscillatory dissipative solitons (DSs) in a cubic complex Ginzburg-Landau equation stabilized by nonlinear gradient terms. As a main result we find a transition to dissipative solitons with spatiotemporal disorder as a function of the diffusion coefficient. This transition proceeds via quasiperiodicity and shows incommensurate satellites next to the fundamental frequency and its harmonics indicating a possible route to localized spatiotemporal chaos. The transition back to oscillatory DSs follows a similar scenario.

A two-fluid model for the macroscopic behavior of polar nematic fluids and gels in a nonchiral or a chiral solvent.

We present the macroscopic dynamics of polar nematic liquid crystals in a two-fluid context. We investigate the case of a nonchiral as well as of a chiral solvent. In addition, we analyze how the incorporation of a strain field for polar nematic gels and elastomers in a solvent modifies the macroscopic dynamics. It turns out that the relative velocity between the polar subsystem and the solvent gives rise to a number of cross-coupling terms, reversible as well as irreversible, unknown from the other two-fluid systems considered so far. Possible experiments to study those novel dynamic cross-coupling terms are suggested. As examples we just mention that gradients of the relative velocity lead, in polar nematics to heat currents and in polar cholesterics to temporal changes of the polarization. In polar cholesterics, shear flows give rise to a temporal variation in the velocity difference perpendicular to the shear plane, and in polar nematic gels uniaxial stresses or strains generate temporal variations of the velocity difference.

Ferromagnetic nematics: A macroscopic two-fluid description.

We present the macroscopic dynamic description of a ferromagnetic nematic, where the nematic part and the magnetic part can move relative to each other. The relative velocity that describes such movements can be a slowly relaxing variable. Its couplings to the nematic and the magnetic degrees of freedom are particularly interesting since the symmetry properties (behavior under spatial inversion and time reversal) of the three vectorial quantities involved are all different. As a consequence, a number of new crosscouplings involving the relative velocity exist. Some of them are discussed in more detail. First, we demonstrate that transverse temperature gradients generate transverse relative velocities and, vice versa, that transverse relative velocities give rise to temperature gradients. Second, we show that a simple shear flow in the relative velocity with the preferred direction in the shear plane can lead in a stationary situation to a tilt of the magnetization.

Dissipative solitons stabilized by nonlinear gradient terms: Time-dependent behavior and generic properties.

We study the time-dependent behavior of dissipative solitons (DSs) stabilized by nonlinear gradient terms. Two cases are investigated: first, the case of the presence of a Raman term, and second, the simultaneous presence of two nonlinear gradient terms, the Raman term and the dispersion of nonlinear gain. As possible types of time-dependence, we find a number of different possibilities including periodic behavior, quasi-periodic behavior, and also chaos. These different types of time-dependence are found to form quite frequently from a window structure of alternating behavior, for example, of periodic and quasi-periodic behaviors. To analyze the time dependence, we exploit extensively time series and Fourier transforms. We discuss in detail quantitatively the question whether all the DSs found for the cubic complex Ginzburg-Landau equation with nonlinear gradient terms are generic, meaning whether they are stable against structural perturbations, for example, to the additions of a small quintic perturbation as it arises naturally in an envelope equation framework. Finally, we examine to what extent it is possible to have different types of DSs for fixed parameter values in the equation by just varying the initial conditions, for example, by using narrow and high vs broad and low amplitudes. These results indicate an overlapping multi-basin structure in parameter space.

Two-fluid model for a fluid with tetrahedral-octupolar order.

We investigate the macroscopic dynamics of a two-fluid system with tetrahedral order. As all normal-fluid two-fluid systems one has-compared to a simple fluid-the velocity difference between the two subsystems and the concentration of one component as additional macroscopic variables. Depending on the type of system, the concentration can either be a conserved quantity or relax on a long, but finite timescale. Due to the existence of the tetrahedral order such a system breaks parity symmetry. Here we discuss physical systems without preferred direction in real space, meaning that our description applies to optically isotropic materials. We find a number of reversible as well as dissipative dynamic cross-coupling terms due to the additional octupolar order, when compared to a fluid mixture. As the most interesting cross-coupling term from an experimental point of view, we identify a dissipative cross-coupling between the relative velocity and the usual velocity gradients. Applying a shear flow in a plane, this dissipative cross-coupling leads to a velocity difference perpendicular to the shear plane. As a result one can obtain a spatially homogeneous oscillation of the relative velocity. In addition, this induced relative velocity can couple as a function of time and space to the concentration, which gives rise to an overdamped propagating soundlike mode, where the overdamping arises from the fact that velocity difference is a macroscopic variable and not strictly conserved. We also show that electric field gradients are connected with an analogous reversible cross-coupling and can lead in a planar shear geometry to an overdamped propagating mode as well.

Multiplicative noise can induce a velocity change of propagating dissipative solitons.

We investigate the influence of spatially homogeneous multiplicative noise on propagating dissipative solitons (DSs) of the cubic complex Ginzburg-Landau equation stabilized by nonlinear gradient terms. Here we focus on the nonlinear gradient terms, in particular on the influence of the Raman term and the delayed nonlinear gain. We show that a fairly small amount of multiplicative noise can lead to a change in the mean velocity for such systems. This effect is exclusively due to the presence of the stabilizing nonlinear gradient terms. For a range of parameters we find a velocity change proportional to the noise intensity for the Raman term and for delayed nonlinear gain. We note that the dissipative soliton decreases the modulus of its velocity when only one type of nonlinear gradient is present. We present a straightforward mean field analysis to capture this simple scaling law. At sufficiently high noise strength the nonlinear gradient stabilized DSs collapse.

Interaction of dissipative solitons stabilized by nonlinear gradient terms.

We study the interaction of stable dissipative solitons of the cubic complex Ginzburg-Landau equation which are stabilized only by nonlinear gradient terms. In this paper we focus for the interactions in particular on the influence of the nonlinear gradient term associated with the Raman effect. Depending on its magnitude, we find up to seven possible outcomes of theses collisions: Stationary bound states, oscillatory bound states, meandering oscillatory bound states, bound states with large-amplitude oscillations, partial annihilation, complete annihilation, and interpenetration. Detailed results and their analysis are presented for one value of the corresponding nonlinear gradient term, while the results for two other values are just mentioned briefly. We compare our results with those obtained for coupled cubic-quintic complex Ginzburg-Landau equations and with the cubic-quintic complex Swift-Hohenberg equation. It turns out that both meandering oscillatory bound states as well as bound states with large-amplitude oscillations appear to be specific for coupled cubic complex Ginzburg-Landau equations with a stabilizing cubic nonlinear gradient term. Remarkably, we find for the large-amplitude oscillations a linear relationship between oscillation amplitude and period.

Two-fluid model for the breakdown of flow alignment in nematic liquid crystals.

We present a macroscopic two-fluid model to explain the breakdown of flow alignment in nematic liquid crystals under shear flow due to smectic clusters. We find that the velocity difference of the two fluids plays a key role to mediate the time-dependent behavior as soon as a large enough amount of smectic order is induced by flow. For the minimal model it is sufficient to keep the nematic degrees of freedom, the mass density of the smectic clusters and the degree of smectic order, the density, and two velocities as macroscopic variables. While frequently a smectic A or C phase arises at lower temperatures, this is not required for the applicability of the present model. Indeed, as pointed out before by Gähwiller, there are compounds showing a breakdown of flow alignment over a large temperature range and no smectic phase, but a solid phase at lower temperatures. We also demonstrate that, using a one velocity model, there is no coupling under shear flow between induced smectic order and the director orientation in stationary situations thus rendering such a model to be unsuitable to describe the breakdown of flow alignment. In a two-fluid description, flow alignment breaks down and becomes unstable with regard to a space- and time-dependent state due to an induced finite velocity difference. In an Appendix we outline a mesoscopic model to account for the sign change in the anisotropy of the electric conductivity observed in nematics with smectic clusters.

Dissipative soliton stabilization by several nonlinear gradient terms.

We study a single cubic complex Ginzburg-Landau equation with nonlinear gradient terms analytically and numerically. This single equation allows for the existence of stable dissipative solitons exclusively due to nonlinear gradient terms. We shed new light on the feedback loop, leading to dissipative solitons (DSs) by analyzing a mechanical analog as a function of the magnitude of the amplitude. In addition, we present analytic results incorporating four nonlinear gradient terms and derive necessary conditions for the existence of DSs. We also elucidate in detail for the case of the Raman contribution the scaling behavior for the limit of the vanishing Raman term.

Breaking of symmetry of interacting dissipative solitons can lead to partial annihilation.

We show that for a large range of approach velocities and over a large interval of stabilizing cubic cross-coupling between counterpropagating waves, a collision of stationary pulses leads to a partial annihilation of pulses via a spontaneous breaking of symmetry. This result arises for coupled cubic-quintic complex Ginzburg-Landau equations for traveling waves for sufficiently large values of the stabilizing cubic cross-coupling and for large enough approach velocities of the pulses. Briefly, we show in addition that the collision of counterpropagating pulses in a system of two coupled cubic Ginzburg-Landau equations with nonlinear gradients (Raman effect) might also lead to partial annihilation, indicating that this breaking of symmetry is generic. Systems of experimental interest include surface reactions, convective onset, biosolitons, and nonlinear optics.

Macroscopic two-fluid effects in magnetorheological fluids.

We investigate macroscopic two-fluid effects in magnetorheological fluids generalizing a one-fluid model studied before. In the bulk of the paper we use a model in which the carrier fluid, with density ρ_{1}, moves with velocity v_{1}, while the magnetic component (density ρ_{2}) and, therefore, the magnetization and the magnetic-field-induced relaxing strain field move with velocity v_{2}. In the framework of macroscopic dynamics we find, in particular, reversible dynamic and dissipative cross-coupling terms between the magnetization and the velocity difference. Experiments to detect some of these cross-coupling terms are suggested. We also compare the results of the two-fluid model presented here with two-fluid models available for electrorheological fluids. In two appendices we discuss the simplifying assumptions made to arrive at the model used in this paper and we also outline how to detect potential deviations from this model.

Mechanism of dissipative soliton stabilization by nonlinear gradient terms.

We present a feedback mechanism for dissipative solitons in the cubic complex Ginzburg-Landau (CGL) equation with a nonlinear gradient term. We are making use of a mechanical analog containing contributions from a potential and from a nonlinear viscous term. The feedback mechanism relies on the continuous supply of energy as well as on dissipation of the stable pulse. Our picture is corroborated by the numerical solution of the full equation. A quintic contribution is not necessary for stabilization in the presence of a suitable nonlinear gradient term as we show by using a linear stability analysis for the stationary pulses. We find that the limit of vanishing magnitude of the nonlinear gradient term is singular: For exactly vanishing nonlinear gradient terms stable pulses do not exist. This situation is qualitatively different from that found for the cubic-quintic complex Ginzburg-Landau equation with a nonlinear gradient term: In this case the limit of a vanishing nonlinear gradient contribution is completely smooth. We demonstrate that, for small magnitude of the nonlinear gradient term simple types of scaling behavior are found for the amplitude, the full width at half maximum (FWHM), the velocity, and the effective frequency of the stable pulse as a function of the magnitude of the nonlinear gradient term.

Cubic and tetragonal liquid crystal phases composed of non-chiral molecules: Chirality and macroscopic properties.

We discuss the symmetry properties as well as the macroscopic behavior of the cubic liquid crystal phases showing large chiral domains of either hand in some non-chiral compounds reported recently in the group of Tschierske. These phases are tricontinuous. While they have O or I432 symmetry in each chiral domain, the overall symmetry is [Formula: see text] as there is no net chirality for compounds composed of non-chiral molecules. It turns out that a rather similar type of phase has also been reported for triblock copolymers. Here we analyze in detail the macroscopic static and dynamic behavior of such phases and we predict, among other results, that they show the analog of static and dissipative Lehmann-type effects in their chiral domains. A description of a cubic liquid crystalline phase of Th symmetry, which has not yet been found experimentally, is also included. Suggestions for experiments are outlined to identify such a phase. In addition, we discuss tetragonal liquid crystalline phases of D4h and D4 (I422) symmetry as they have been reported last year experimentally in connection to the Q phase.

Simultaneous influence of additive and multiplicative noise on stationary dissipative solitons.

We investigate the simultaneous influence of spatially homogeneous multiplicative noise as well as of spatially δ-correlated additive noise on the formation of localized patterns in the framework of the cubic-quintic complex Ginzburg-Landau equation. Depending on the ratio between the strength of additive and multiplicative noise we find a number of distinctly different types of behavior including explosions, collapse, filling in, and spatio-temporal disorder as well as intermittent behavior of all types listed. Techniques used to analyze the results include snapshots, x-t plots and plots of the spatially and temporally averaged amplitude as a function of the strength of multiplicative noise while keeping the strength of additive noise fixed. Typically 50 realizations are used for averaging to obtain the corresponding data points in these diagrams. For the widths of these distribution as a function of additive noise we obtain a linear decrease in the limit of fairly large, but fixed values of the multiplicative noise. To summarize our findings concisely we show three-dimensional plots of the mean pattern amplitude and the generalized susceptibility as a function of the strengths of additive and multiplicative noise. We critically compare the results of our investigations with those obtained in the two limiting cases of purely additive and of purely multiplicative noise.

Continuum model of magnetic field induced viscoelasticity in magnetorheological fluids.

An effective macroscopic model of magnetorheological fluids in the viscoelastic regime is proposed. Under the application of an external magnetic field, columns of magnetizable particles are formed in these systems. The columns are responsible for solidlike properties, such as the existence of elastic shear modulus and yield stress, and are captured by the strain field, while magnetic properties are described by the magnetization. We investigate the interplay of these variables when static shear or normal pressure is imposed in the presence of the external magnetic field. By assuming a relaxing strain field, we calculate the flow curves, i.e., the shear stress as a function of the imposed shear rate, for different values of the applied magnetic field. Focusing on the small amplitude oscillatory shear, we study the complex shear modulus, i.e., the storage and the loss moduli, as a function of the frequency. We demonstrate that already such a minimal model is capable of furnishing many of the key physical features of these systems, such as yield stress, enhancement of the shear yield stress by pressure, threshold behavior in the spirit of the frequently employed Bingham law, and several features in the frequency dependence of storage and loss moduli.

Influence of tetrahedral order on ferromagnetic gel phases.

We investigate the macroscopic dynamics of gels with tetrahedral/octupolar symmetry, which possess in addition a spontaneous permanent magnetization. We derive the corresponding static and dynamic macroscopic equations for a phase, where the magnetization is parallel to one of the improper fourfold tetrahedral symmetry axes. Apart from elastic strains, we take into account relative rotations between the magnetization and the elastic network. The influence of tetrahedral order on these degrees of freedom is investigated and some experiments are proposed that are specific for such a material and allow to indirectly detect tetrahedral order. We also consider the case of a transient network and predict that stationary elastic shear stresses arise when a temperature gradient is applied.

A dynamic preferred direction model for the self-organization dynamics of bacterial microfluidic pumping.

It is known that some flagellated bacteria like Serratia marcescens, when deposited and affixed onto a surface to form a "bacterial carpet", self-organize in a collective motion of the flagella that is capable of pumping fluid through microfluidic channels. We set up a continuum model comprising two macroscopic variables that is capable of describing this self-organization mechanism as well as quantifying it to the extent that an agreement with the experimentally observed channel width dependence of the pumping is reached. The activity is introduced through a collective angular velocity of the helical flagella rotation, which is an example of a dynamic macroscopic preferred direction. Our model supports and quantifies the view that the self-coordination is due to a positive feedback loop between the bacterial flagella and the local flow generated by their rotation. Moreover, our results indicate that this biological active system is operating close to the self-organization threshold.