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1.
Environ Monit Assess ; 193(10): 677, 2021 Sep 29.
Artigo em Inglês | MEDLINE | ID: mdl-34590176

RESUMO

International harmonisation of management goals for eutrophication processes in coastal waters, requiring reduction of discharges and depositions of nutrients and organic matter, needs coordinated assessments and measures. This is especially necessary in open areas, connected by currents and mixing processes with trans-boundary exchanges. Management goals, defined nationally as local thresholds for nutrients and chlorophyll-a, had been applied recently (2006-2014) within international eutrophication assessments in the North Sea (OSPAR) and Baltic Sea (HELCOM). Consistency of thresholds for nitrogen nutrients and chlorophyll-a concentrations is tested by mixing diagrams and correlations between nitrogen nutrients (total and inorganic nitrogen) and chlorophyll-a. Results indicate mean consistent relations, but single deviations as in the continental coastal water of the North Sea surpassed means by a factor up to 5 for chlorophyll-a in relation to inorganic nitrogen. Thresholds differed across national borders significantly. Correlations of thresholds and assed data reflect the degree of regional deviations by comparison. Consistency of regionally applied thresholds can be achieved stepwise, by application of regionally correlated means, by adaptation to mixing and parameter relations, and finally by relations of thresholds to natural background concentrations. By this, consistency of international assessments can be improved generally, allowing coordinated management of open coastal waters.


Assuntos
Monitoramento Ambiental , Eutrofização , Países Bálticos , Nitrogênio/análise , Nutrientes , Fósforo/análise
2.
Mar Pollut Bull ; 136: 68-78, 2018 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-30509843

RESUMO

The eutrophication status of the German Bight (North Sea) has been assessed the third time since 1998 according to the OSPAR-Comprehensive Procedure between 2006 and 2014. Since the 1980s nutrient discharges and atmospheric nitrogen deposition had declined significantly but chlorophyll a and nutrient concentrations remained above assessment levels inshore and in inner coastal waters, reflecting continuing eutrophication. Recently local river discharges stagnated or increased again and total nitrogen remained above a reduction target of 200 µM. Most nutrients and conversion products were imported by a coastal current, passing the German Bight. Organic matter was trapped in offshore bottom waters in the ancient Elbe valley, causing repeated annual oxygen minima (<6 mg/L) and a classification as Problem Area. Effects of national reduction measures are limited in the transit area German Bight because improvements in open coastal waters require international efforts, based on comprehensive analyses.


Assuntos
Monitoramento Ambiental/métodos , Eutrofização , Água do Mar/química , Alemanha , Nitrogênio/análise , Mar do Norte , Oxigênio/análise , Rios/química , Salinidade , Estações do Ano
3.
Mar Pollut Bull ; 99(1-2): 5-27, 2015 Oct 15.
Artigo em Inglês | MEDLINE | ID: mdl-26234616

RESUMO

Seasonal mean oxygen depletion in offshore and coastal North Sea bottom waters was shown to range between 0.9 and 1.8 mg/L, corresponding to 95-83% saturation, between July and October over a 30-year assessment period (1980-2010). The magnitude of oxygen depletion was controlled by thermal stratification, modulated by water depth and nitrogen availability. Analyses were based on about 19,000 combined data sets. Eutrophication problem areas were identified mainly in coastal waters by oxygen minima, the lower 10th percentile of oxygen concentrations, and deviations of oxygen depletion from correlated stratification values. Connections between oxygen consumption and nitrogen sources and conversion, including denitrification, were indicated by correlations. Mean oxygen consumption reflected a minimum seasonal turnover of 3.1 g N/m(2) in the south-eastern North Sea, including denitrification of 1 g N/m(2). Oxygen depletion was underestimated in shallow coastal waters due to repeated erosion of stratification as indicated by local high variability.


Assuntos
Oxigênio/análise , Água do Mar/análise , Monitoramento Ambiental/métodos , Eutrofização , Nitrogênio/análise , Mar do Norte , Estações do Ano
4.
Environ Monit Assess ; 174(1-4): 361-88, 2011 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-20437265

RESUMO

Natural background concentrations of nutrients are needed for the assessments of eutrophication processes and their status. Natural background concentrations of total nitrogen (TN) and total phosphorus (TP) were modelled for the rivers discharging into the German Bight and the Rhine considering individual catchment sizes, freshwater flows and soil types. These data were validated by comparison with data from unpolluted rivers. The consistency of modelled and some compiled nutrient concentrations was confirmed by their area-specific load dependency on freshwater discharges. Pristine inorganic nutrient concentrations were deduced from modelled relations to TN and TP in unpolluted rivers. Pristine nutrient gradients between rivers and offshore waters were estimated by linear mixing until a salinity of 32, continued by hyperbolic fits towards recent mean offshore values (salinity 34.5-35). Based on these gradients and recent mean salinities, maps of pristine surface gradients were plotted for the whole German Bight. Variability was transferred from recent conditions as percentage of standard deviation. Reported historical nutrient data and concentrations from unpolluted rivers, coastal and offshore North Sea waters are discussed concerning their relations to natural background conditions.


Assuntos
Nitrogênio/análise , Fósforo/análise , Água do Mar/química , Eutrofização , Alemanha
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