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1.
Front Chem ; 10: 926330, 2022.
Artigo em Inglês | MEDLINE | ID: mdl-35665064

RESUMO

[This corrects the article DOI: 10.3389/fchem.2022.818974.].

2.
Front Chem ; 10: 818974, 2022.
Artigo em Inglês | MEDLINE | ID: mdl-35372286

RESUMO

Hyperspectral imaging has recently gained increasing attention from academic and industrial world due to its capability of providing both spatial and physico-chemical information about the investigated objects. While this analytical approach is experiencing a substantial success and diffusion in very disparate scenarios, far less exploited is the possibility of collecting sequences of hyperspectral images over time for monitoring dynamic scenes. This trend is mainly justified by the fact that these so-called hyperspectral videos usually result in BIG DATA sets, requiring TBs of computer memory to be both stored and processed. Clearly, standard chemometric techniques do need to be somehow adapted or expanded to be capable of dealing with such massive amounts of information. In addition, hyperspectral video data are often affected by many different sources of variations in sample chemistry (for example, light absorption effects) and sample physics (light scattering effects) as well as by systematic errors (associated, e.g., to fluctuations in the behaviour of the light source and/or of the camera). Therefore, identifying, disentangling and interpreting all these distinct sources of information represents undoubtedly a challenging task. In view of all these aspects, the present work describes a multivariate hybrid modelling framework for the analysis of hyperspectral videos, which involves spatial, spectral and temporal parametrisations of both known and unknown chemical and physical phenomena underlying complex real-world systems. Such a framework encompasses three different computational steps: 1) motions ongoing within the inspected scene are estimated by optical flow analysis and compensated through IDLE modelling; 2) chemical variations are quantified and separated from physical variations by means of Extended Multiplicative Signal Correction (EMSC); 3) the resulting light scattering and light absorption data are subjected to the On-The-Fly Processing and summarised spectrally, spatially and over time. The developed methodology was here tested on a near-infrared hyperspectral video of a piece of wood undergoing drying. It led to a significant reduction of the size of the original measurements recorded and, at the same time, provided valuable information about systematic variations generated by the phenomena behind the monitored process.

3.
Plant Methods ; 15: 3, 2019.
Artigo em Inglês | MEDLINE | ID: mdl-30675175

RESUMO

BACKGROUND: Global warming is going to affect both agricultural production and carbon storage in soil worldwide. Given the complexity of the soil-plant-atmosphere continuum, in situ experiments of climate warming are necessary to predict responses of plants and emissions of greenhouse gases (GHG) from soils. Arrays of infrared (IR) heaters have been successfully applied in temperate and tropical agro-ecosystems to produce uniform and large increases in canopy surface temperature across research plots. Because this method had not yet been tested in the Arctic where consequences of global warming on GHG emission are expected to be largest, the objective of this work was to test hexagonal arrays of IR heaters to simulate a homogenous 3 °C warming of the surface, i.e. canopy and visible bare soil, of five 10.5-m2 plots in an Arctic meadow of northern Norway. RESULTS: Our results show that the IR warming setup was able to simulate quite accurately the target + 3 °C, thereby enabling us to simulate the extension of the growing season. Meadow yield increased under warming but only through the lengthening of the growing season. Our research also suggests that, when investigating agricultural systems on the Arctic, it is important to start the warming after the vegetation is established,. Indeed, differential emergence of meadow plants impaired the homogeneity of the warming with patches of bare soil being up to 9.5 °C warmer than patches of vegetation. This created a pattern of soil crusting, which further induced spatial heterogeneity of the vegetation. However, in the Arctic these conditions are rather rare as the soil exposed by snow melt is often covered by a layer of senescent vegetation which shelters the soil from direct radiation. CONCLUSIONS: Consistent continuous warming can be obtained on average with IR systems in an Arctic meadow, but homogenous spatial distribution requires that the warming must start after canopy closure.

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