RESUMO
A benzo[ghi]perylenetriimide (BPTI) derivative bearing a terminal azido group on the expanded π-conjugated backbone has been synthesized and characterized. This promising photo- and electroactive BPTI motif has been used to obtain an original penta(organo)fullerene as a promising multi-electron acceptor system. Our studies show its self-assembly resulting from aggregation via π-π stacking interaction in solution and in the solid state.
RESUMO
New penta(organo)fullerenes donor-acceptor systems bearing five tetrathiafulvalene recognition units have been synthesized to promote self-assemblies similar in appearance to shuttlecocks nested into each other thanks to the conical host cavity created around the fullerene together with the π-π and electronic interactions.
