RESUMO
The electrical and electromechanical responses of ~200 µm thick extruded nanocomposite films comprising of 4 wt.% and 5 wt.% multiwall carbon nanotubes mixed with polypropylene are investigated under an alternating current (AC) and compared to their direct current (DC) response. The AC electrical response to frequency (f) and strain (piezoimpedance) is characterized using two configurations, namely one that promotes resistive dominance (resistive configuration) and the other that promotes the permittivity/capacitive contribution (dielectric configuration). For the resistive configuration, the frequency response indicated a resistive-capacitive (RC) behavior (negative phase angle, θ), with a significant contribution of capacitance for frequencies of 104 Hz and above, depending on the nanotube content. The piezoimpedance characterization in the resistive configuration yielded an increasing impedance modulus (|Z|) and an increasing (negative) value of θ as the strain increased. The piezoimpedance sensitivity at f = 10 kHz was ~30% higher than the corresponding DC piezoresistive sensitivity, yielding a sensitivity factor of 9.9 for |Z| and a higher sensitivity factor (~12.7) for θ. The dielectric configuration enhanced the permittivity contribution to impedance, but it was the least sensitive to strain.
RESUMO
The emergence of modern technologies, such as Wireless Sensor Networks (WSNs), the Internet-of-Things (IoT), and Machine-to-Machine (M2M) communications, involves the use of batteries, which pose a serious environmental risk, with billions of batteries disposed of every year. However, the combination of sensors and wireless communication devices is extremely power-hungry. Energy Harvesting (EH) is fundamental in enabling the use of low-power electronic devices that derive their energy from external sources, such as Microbial Fuel Cells (MFC), solar power, thermal and kinetic energy, among others. Plant Microbial Fuel Cell (PMFC) is a prominent clean energy source and a step towards the development of self-powered systems in indoor and outdoor environments. One of the main challenges with PMFCs is the dynamic power supply, dynamic charging rates and low-energy supply. In this paper, a PMFC-based energy harvester system is proposed for the implementation of autonomous self-powered sensor nodes with IoT and cloud-based service communication protocols. The PMFC design is specifically adapted with the proposed EH circuit for the implementation of IoT-WSN based applications. The PMFC-EH system has a maximum power point at 0.71 V, a current density of 5 mA cm - 2 , and a power density of 3.5 mW cm - 2 with a single plant. Considering a sensor node with a current consumption of 0.35 mA, the PMFC-EH green energy system allows a power autonomy for real-time data processing of IoT-based low-power WSN systems.
