RESUMO
A six section widely tunable laser based on slots etched into the waveguide is presented. This laser is re-growth free which makes it suitable for photonics integration. To improve the laser performance, the front and the back facets are anti- reflection (AR) coated and the laser is integrated with a semiconductor optical amplifier. A tuning range of 55nm covering 12 supermodes with side mode suppression ratio (SMSR) >30dB is reported for the fabricated device using the Vernier tuning effect. This laser platform requires very simple fabrication compared with more complex superstructure gratings.
RESUMO
We investigate with state of the art density functional theory the structural, electronic, and transport properties of a class of recently synthesized nanostructures based on triarylamine derivatives. First, we consider the single molecule precursors in the gas phase and calculate their static properties, namely (i) the geometrical structure of the neutral and cationic ions, (ii) the electronic structure of the frontier molecular orbitals, and (iii) the ionization potential, hole extraction potential, and internal reorganization energy. This initial study does not evidence any direct correlation between the properties of the individual molecules and their tendency to self-assembly. Subsequently, we investigate the charge transport characteristics of the triarylamine derivatives nanowires, by using Marcus theory. For one derivative we further construct an effective Hamiltonian including intermolecular vibrations and evaluate the mobility from the Kubo formula implemented with Monte Carlo sampling. These two methods, valid respectively in the sequential hopping and polaronic band limit, give us values for the room-temperature mobility in the range 0.1-12 cm(2)/Vs. Such estimate confirms the superior transport properties of triarylamine-based nanowires, and make them an attracting materials platform for organic electronics.
