High-resolution electricity generation mixes in building operation: A methodological framework for energy and environmental impacts and the case study of an Italian net zero energy building.

Temporal fluctuations of the electricity grid generation composition, variability of electricity consumption in building operation over the year and of the on-site renewable energy systems are factors that should be properly considered, using high-resolution data in the building energy and environmental performance assessment. In this study a methodological framework is developed to model high-resolution electricity mixes in building operation and to assess the related energy and environmental impacts over the year, by means of a life cycle approach. For most impact categories, the imported electricity generation mixes, to meet the residual building demand, show impact variations not higher than +20 % and not lower than -38 % at seasonal and daily time compared with the annual average values. Temporal variations are even more relevant in building consumption electricity mixes, which are significantly characterized by self-consumption and show noticeable reductions compared to the annual electricity generation mix in both assessed scenarios. As an example, summer and spring energy generation mixes show the best results for climate change (0.09 kgCO2eq/kWh) compared to the annual ones, while in winter and autumn mixes the contribution to climate change overcomes the respective annual results. Both summer day-mixes contribute to climate change for about 0.12 kgCO2eq/kWh, with a reduction of nearly 30 % if compared the annual data. Conversely, in the winter day-mixes the contribution to climate change is about 0.20 kgCO2eq/kWh and comes mostly from the grid. The results highlight that assessed temporal variations are significant through the year for the most assessed environmental indicators. Furthermore, the use of high-resolution electricity generation mixes allows to optimize efficiently the temporal use of electricity in buildings, in sight of energy and environmental impact reduction also thanks to the employment of life cycle oriented approaches. The results also highlight the relevance of the storage system in fulfilling periods of peak demand or low renewable generation.

Bioenergy from anaerobic digestion plants: Energy and environmental assessment of a wide sample of Italian plants.

This study assesses the energy and environmental performances of electricity produced from Italian anaerobic digestion coupled with combined heat and power plants. The Life Cycle Assessment methodology is applied to a set of plants characterised by different power sizes (from 100 to 999 kW) and feedstock compositions (variable rates of agricultural products and by-products). Then, the average eco-profile of the produced electricity is compared with electricity produced by the national grid and photovoltaic panels. The analysis allows detection of the combinations of size and feedstock with the lowest impacts. They correspond to small and medium plants mainly fed by organic by-products. In addition, compared to electricity from the grid, the average biogas electricity is characterised by the lowest contribution in impacts categories, such as abiotic depletion potential and ozone layer depletion potential, while largest in acidification and eutrophication. Focusing on global warming potential and cumulative energy demand fossil, the impacts of average biogas electricity (155 kgCO2eq/MWh and 172 MJ/MWh) are about 35 % and 38 % of that generated by the grid. Furthermore, it could generate 47 % less of the impact in the abiotic depletion elements category of the solar system. To enhance the farms' environmental and economic sustainability and balance the electric grid, these outcomes point out that biogas electricity produced from the agriculture and livestock sector can contribute to the decarbonisation and self-sufficiency of European countries. The results strictly depend on the operative conditions and can aid policymakers at the global level in improving the energy supply security and sustainability. Further, they provide reliable information to stakeholders to select the most sustainable solution, according to the feedstock type, power supply, and management.

Sustainable production and consumption in remote working conditions due to COVID-19 lockdown in Italy: An environmental and user acceptance investigation.

In response to the disruptive changes brought upon our society by the COVID-19 pandemic, most work activities and service providers had to resort to remote working. This is credited to reduce emissions for transportation, however the role of forced confinement within dwellings, especially if not designed for hosting working stations, deserves to be properly evaluated in terms of both user acceptance and long-term environmental impact. In this work, a dedicated survey campaign is used for investigating the potential pros and cons of remote working. In more detail, logistic regression and generalized linear models are used for capturing the effect of several independent variables on user acceptance of remote working. At a later stage, the main greenhouse gas emissions produced by each participant before and during remote working are assessed. According to the obtained results, the greater the distance between their home and workplace, the higher the acceptance score declared by the survey participants about remote working. Additionally, higher incomes and better-quality lifestyles with larger devotion to leisure activities also provide higher acceptance. Finally, the existence of a comfortable room to be used for work activities plays a crucial role on the declared acceptance. From an environmental point of view, remote working is always sustainable in case of long commuting distances (above 10 km) are avoided on a daily routine. In conclusion, a sensible use of remote working could reduce the environmental impact of any organization employing desk-workers as well as improve their work satisfaction and lifestyle.

Life Cycle Assessment of electricity production from refuse derived fuel: A case study in Italy.

Biomasses and bio-waste have an important role in decarbonizing the European energy mix, the latter contributing to the transition towards a circular economy. In particular, Refuse Derived Fuel (RFD) - a biofuel obtained from dry residue of waste - appears a really interesting energy option. In this framework this study aims at assessing the environmental profile of electricity generation from RDF in Italy, comparing two different kinds of RDF production and combustion plants. The functional unit is 1 kWh of net electricity from RDF delivered to the grid. Two Italian plants are examined: one located in Ravenna (RDF is produced in a direct flow treatment plant) and the other one in Bergamo (RDF is produced in a unique flow treatment plant and electricity is generated in a cogenerator). Results show that, comparing the plants, it is not possible to identify an option for RDF production or electricity generation characterized by lowest impacts for all the examined impact categories. However, cogeneration process and the avoided burdens due to the valorisation of ferrous metals and dry fractions during RDF production can reduce most of the environmental impacts. A dominance analysis reveals that chimney direct emissions generated during RDF combustion significantly contribute to some impact categories, as well as electricity consumption during RDF production. Furthermore, disposal of incineration wastes is a relevant contributor to human toxicity and freshwater eutrophication. The eco-profile of electricity from RDF is compared with electricity from the Italian grid and from multi-Si PV. The comparison highlights that electricity from RDF performs worse for relevant environmental impact categories such as climate change, human toxicity and photochemical oxidant formation. On the other hand, electricity from RDF performs better than electricity from the grid and from photovoltaic for resource depletion, an impact category of growing importance in the framework of circular economy.

Energy-environmental assessment of the UIA-OpenAgri case study as urban regeneration project through agriculture.

Sustainable agriculture is strongly promoted by Agenda 2030 and peri-urban agriculture is considered strategic for agri-food sustainability. Although, innovative farming practices are being implemented, the analysis of their impacts often does not reach the required depth. Within the EU project 'UIA-OpenAgri - New Skills for new Jobs in Peri-urban Agriculture', a regeneration process of a peri-urban area in Milan (Italy) was started, through the development of an innovative food hub. 28 innovative foodchains are assessed by a Life Cycle Assessment approach based on primary data collected from the involved start-ups. Non-Renewable Cumulative Energy Demand and the Global Warming Potential indicators are assessed and coupled with the productive land indicator. To effectively support involved operators in planning sustainable agriculture practices, the results are presented with GIS maps and insights for improving economic sustainability of involved start-ups are presented. The study shows that the impacts related to the practices implemented (i.e. organic agriculture, including intercropping, agroforestry, ancient grains, etc.) decrease by an average of 55% in energy consumption and 65% on Global Warming Potential if compared to conventional ones. Then, these practices can provide a positive contribution to the Agenda 2030 goal of ensuring sustainable farm production practices.

Life cycle energy and environmental impacts of a solid oxide fuel cell micro-CHP system for residential application.

Fuel cells are considered one of the key technologies to reach the ambitious European goal of a low carbon economy, by reducing CO2 emissions and limiting the production of other pollutants. The manuscript presents an assessment of the life cycle energy and environmental performances of a solid oxide fuel cell system for household applications using primary data from the manufacturing phase and experimental data for the start-up and operation phases. The Life Cycle Assessment methodology is applied, based on a functional unit of 1 MJ of exergy and includes the life cycle steps from the raw materials extraction to the maintenance. The results show a particular relevance of the operation stage on the impacts (about 98% of cumulative energy demand and more than 63% of about half of the examined environmental impacts), mainly due to the fuel supply and, focusing on climate change, to the CO2 emissions during the conversion of chemical energy into electricity. Manufacturing step is the main responsible of the remaining half of the impacts, with a contribution higher than 38%, mainly imputable to the stacks production. For almost half of the examined impact, a contribution of 20-30% is caused by the maintenance step, with a relevant contribution of the stacks and DC/DC booster substitutions. The analysis highlights that eco-design solutions of the assessed system can be traced in the improvement of the energy system efficiency and reduction of emissions during the operation, and in the increase of the durability of the system components, thus reducing the number of their substitutions. The results of a sensitivity analysis on the selection of the functional unit also clarified the importance of the recovery of the thermal energy generated by the fuel cells, in order to avoid concurrent energy generation from conventional sources.

Energy and environmental assessment of a traction lithium-ion battery pack for plug-in hybrid electric vehicles.

Traction batteries are a key factor in the environmental sustainability of electric mobility and, therefore, it is necessary to evaluate their environmental performance to allow a comprehensive sustainability assessment of electric mobility. This article presents an environmental assessment of a lithium-ion traction battery for plug-in hybrid electric vehicles, characterized by a composite cathode material of lithium manganese oxide (LiMn2O4) and lithium nickel manganese cobalt oxide Li(NixCoyMn1-x-y)O2. Composite cathode material is an emerging technology that promises to combine the merits of several active materials into a hybrid electrode to optimize performance and reduce costs. In this study, the environmental assessment of one battery pack (with a nominal capacity of 11.4 kWh able to be used for about 140,000 km of driving) is carried out by using the Life Cycle Assessment methodology consistent with ISO 14040. The system boundaries are the battery production, the operation phase and recycling at the end of life, including the recovery of various material fractions. The composite cathode technology examined besides a good compromise between the higher and the lower performance of NMC and LMO cathodes, can present good environmental performances. The results of the analysis show that the manufacturing phase is relevant to all assessed impact categories (contribution higher than 60%). With regard to electricity losses due to battery efficiency and battery transport, the contribution to the use phase impact of battery efficiency is larger than that of battery transport. Recycling the battery pack contributes less than 11% to all of the assessed impact categories, with the exception of freshwater ecotoxicity (60% of the life cycle impact). The environmental credits related to the recovery of valuable materials (e.g. cobalt and nickel sulphates) and other metal fractions (e.g. aluminium and steel) are particularly relevant to impact categories such as marine eutrophication, human toxicity and abiotic resource depletion. The main innovations of this article are that (1) it presents the first bill of materials of a lithium-ion battery cell for plug-in hybrid electric vehicles with a composite cathode active material; (2) it describes one of the first applications of the life cycle assessment to a lithium-ion battery pack for plug-in hybrid electric vehicles with a composite cathode active material with the aim of identifying the "hot spots" of this technology and providing useful information to battery manufacturers on potentially improving its environmental sustainability; (3) it evaluates the impacts associated with the use phase based on primary data about the battery pack's lifetime, in terms of kilometres driven; and (4) it models the end-of-life phase of the battery components through processes specifically created for or adapted to the case study.

Energy and environmental life cycle assessment of an institutional catering service: An Italian case study.

Food production is recognised as one of the major drivers for global environmental pressure. In the last years, changes in consumption models result in an increasing population consuming food out of home that pose the catering service sector at the centre of the European Union policies aimed at improving the environmental sustainability of the food sector. In this framework, better technical knowledge on the environmental impacts of catering service is essential in order to identify potential actions towards a more sustainable food sector. This article presents an environmental assessment of a school catering service operating in Italy and delivering approximately 2,518,128 meals per year. Starting from primary data on the amount of each food consumed in the catering service examined, we perform an environmental analysis of an equivalent meal ready to be consumed in the schools canteens by using the Life Cycle Assessment methodology consistent with ISO 14040 standard. The system boundaries include food and tableware production, food transport, food storage and cooking and waste treatment. Due to a lack of primary data tableware production, food storage, cooking and waste treatment are modelled using literature data or models. The results of the analysis show that the food production phase is relevant to almost all assessed impact categories (contribution higher than 65%). The exception is represented by photochemical oxidation impact categories in which the larger impact is linked to the transportation phase. The environmental impacts associated to the tableware production, food storage and cooking are relevant to global warming and global energy requirement (contributions higher than 7%). The scenario analysis of potential actions aimed at reducing the environmental impacts of the catering service shows that, to obtain a more sustainable food sector, strategies must be implemented along the entire food supply chain and considering a wide range of environmental impact categories.

Energy-related GHG emissions balances: IPCC versus LCA.

Addressing climate change is one of the greatest environmental challenges. Due to the impact of cities to energy consumption, the involvement of the local authorities in environmental policies is rapidly increasing. The Covenant of Mayors (CoM), launched by the European Commission, is an urban initiative aimed at reducing CO2 emissions. The signatories have to compile the greenhouse gas emissions (GHG) balance of their territory and, to do so, they can use the Intergovernmental Panel on Climate Change (IPCC) or the Life Cycle Assessment (LCA). Moreover, the signatories have to define strategies to reduce the GHG emissions. In this context, authors estimate the GHG balance of an Italian municipality using both methodologies in order to compare the results. In detail, the first application is the IPCC, the second one is the LCA approach for which two cases are analysed: i) LCA with fossil fuels and electricity GHG emission factors based on the European Reference Life Cycle Database, LCA (I); and ii) LCA with a site - specific GHG emissions for electricity generation, LCA (II). They propose energy strategies in order to quantify the achievable GHG emissions reduction by the exploitation of the renewable energy resources. The study shows that the GHG emissions results obtained with the LCA approach are higher by 20% than those calculated with the IPCC approach. This difference is relevant and it could be significant in identifying effective climate strategies. The LCA methodology ensures a systemic accounting of emissions, then, it can be more effective in order to achieve GHG emissions reduction at global level. The examined energy strategies allow for reducing the GHG emissions of about 7% of the total reduction required by the CoM. This confirms that a preliminary evaluation of the strategies is useful for the allocation of the financial resources to the environmental policies.

From the LCA of food products to the environmental assessment of protected crops districts: a case-study in the south of Italy.

In the present study, Life Cycle Assessment (LCA) methodology was applied to evaluate the energy consumption and environmental burdens associated with the production of protected crops in an agricultural district in the Mediterranean region. In this study, LCA was used as a 'support tool', to address local policies for sustainable production and consumption patterns, and to create a 'knowledge base' for environmental assessment of an extended agricultural production area. The proposed approach combines organisation-specific tools, such as Environmental Management Systems and Environmental Product Declarations, with the environmental management of the district. Questionnaires were distributed to producers to determine the life cycle of different protected crops (tomatoes, cherry tomatoes, peppers, melons and zucchinis), and obtain information on greenhouse usage (e.g. tunnel vs. pavilion). Ecoprofiles of products in the district were also estimated, to identify supply chain elements with the highest impact in terms of global energy requirements, greenhouse gas emissions, eutrophication, water consumption and waste production. These results of this study enable selection of the 'best practices' and ecodesign solutions, to reduce the environmental impact of these products. Finally, sensitivity analysis of key LCA issues was performed, to assess the variability associated with different parameters: vegetable production; water usage; fertiliser and pesticide usage; shared greenhouse use; substitution of plastics coverings; and waste recycling.

Life cycle assessment of Italian citrus-based products. Sensitivity analysis and improvement scenarios.

Though many studies concern the agro-food sector in the EU and Italy, and its environmental impacts, literature is quite lacking in works regarding LCA application on citrus products. This paper represents one of the first studies on the environmental impacts of citrus products in order to suggest feasible strategies and actions to improve their environmental performance. In particular, it is part of a research aimed to estimate environmental burdens associated with the production of the following citrus-based products: essential oil, natural juice and concentrated juice from oranges and lemons. The life cycle assessment of these products, published in a previous paper, had highlighted significant environmental issues in terms of energy consumption, associated CO(2) emissions, and water consumption. Starting from such results the authors carry out an improvement analysis of the assessed production system, whereby sustainable scenarios for saving water and energy are proposed to reduce environmental burdens of the examined production system. In addition, a sensitivity analysis to estimate the effects of the chosen methods will be performed, giving data on the outcome of the study. Uncertainty related to allocation methods, secondary data sources, and initial assumptions on cultivation, transport modes, and waste management is analysed. The results of the performed analyses allow stating that every assessed eco-profile is differently influenced by the uncertainty study. Different assumptions on initial data and methods showed very sensible variations in the energy and environmental performances of the final products. Besides, the results show energy and environmental benefits that clearly state the improvement of the products eco-profile, by reusing purified water use for irrigation, using the railway mode for the delivery of final products, when possible, and adopting efficient technologies, as the mechanical vapour recompression, in the pasteurisation and concentration of juice.

Life cycle assessment-driven selection of industrial ecology strategies.

The paper presents an application of the Life-Cycle Assessment (LCA) to the planning and environmental management of an "eco-industrial cluster." A feasibility study of industrial symbiosis in southern Italy is carried out, where interlinked companies share subproducts and scraps, services, structures, and plants to reduce the related environmental impact. In particular, the research focuses on new recycling solutions to create open recycling loops in which plastic subproducts and scraps are transferred to external production systems. The main environmental benefits are the reduction of resource depletion, air emissions, and landfilled wastes. The proposed strategies are also economically viable and they suggest cost abatement for the involved companies. This research shows the need for a multidisciplinary approach to data processing and to complexity managing of the investigated systems. In this context, life-cycle thinking is required to be promoted throughout the economy, as well to be as a part of all decisions on products and other criteria such as functionality, health, and safety. The Life-Cycle Assessment approach can be assumed as a methodology for influencing decision makers to make sustainable choices.

Resource consumption and environmental impacts of the agrofood sector: life cycle assessment of italian citrus-based products.

Food production and consumption cause significant environmental burdens during the product life cycles. As a result of intensive development and the changing social attitudes and behaviors in the last century, the agrofood sector is the highest resource consumer after housing in the EU. This paper is part of an effort to estimate environmental impacts associated with life cycles of the agrofood chain, such as primary energy consumption, water exploitation, and global warming. Life cycle assessment is used to investigate the production of the following citrus-based products in Italy: essential oil, natural juice, and concentrated juice from oranges and lemons. The related process flowcharts, the relevant mass and energy flows, and the key environmental issues are identified for each product. This paper represents one of the first studies on the environmental impacts from cradle to gate for citrus products in order to suggest feasible strategies and actions to improve their environmental performance.

POEMS: a case study of an Italian wine-producing firm.

Over the last decade, researchers paid much attention to concepts such as Design for Environment, Extended Producer Responsibility, Responsible Chain Management, and Eco-design. Many management tools and standards (such as EMAS, ISO 14001, LCA, EPD, Ecolabel) have been developed to support companies in the evaluation and management of their environmental performance and to pursue continual environmental improvement. The more recent development of the aforesaid fields looks at interorganizational environmental management. Such an approach can complement the more traditional intraorganizational corporate environmental management approaches and tools. A typical example of this new trend is the Product Oriented Environmental Management System (POEMS), which represents the natural evolution of the above-mentioned tools, combining the features of EMS, EPD and Ecolabel. Although the structure of the POEMS is still not standardized, many experimental applications have yet been carried out in Europe. In developing a POEMS, a company needs to determine all of the environmental impacts caused at all life-cycle stages of the product and, ideally, to reduce all of them through a continual commitment. The aim of the present study was to perform a survey of the developed POEMS models and to analyze their peculiarities and drawbacks in the application to Small and Medium Enterprises. A case study regarding an Italian winery company is presented. The study analyzes the structure and the activities of the examined firm, in order to estimate direct and indirect environmental impacts following a life-cycle approach. The chosen functional unit is a 0.75-L bottle of red wine. The article also suggests some solutions to improve the environmental performances of the firm's products.