Free-Standing Ion-Conductive Gels Based on Polymerizable Imidazolium Ionic Liquids.

A free-standing ion-conductive gel is formed by spontaneous self-assembly of the amphiphilic ionic liquid 1-tetradecyl-3-methylimidazolium chloride (C14MIm·Cl) and the cross-linkable monomer 6-hexanediol diacrylate (HDODA) in a mixed solvent of 1-octene, 1-butanol, and water. The ionic conductivity of this ion gel is 24 mS cm-1 at 33 °C. To enhance the mechanical strength of the ion gels, the acrylate ionic liquid 1-(2-acryloyloxyundecyl)-3-methylimidazolium bromide (A-C11MIm·Br) was added, leading to significant morphological changes of the HDODA phase from spherical, ellipsoid, angular platelets to interconnected with increasing addition of the acrylate ionic liquid and consequent enhancement in the mechanical strength of the resulting ion gels. Small angle X-ray scattering data reveal that the ion gels are composed of bicontinuous phase. The formation of the anisotropic HDODA structures upon introduction of the acrylate ionic liquid was accompanied by a change of the bicontinuous phase to be undulated, which increased the ionic path through the formed film, resulting in reduced ionic conductivity. Such coaxial structured gels may be a promising route for developing highly ion-conductive as well as mechanically stable solid electrolyte systems.

Interesting phase behaviors and ion-conducting properties of dicationic N-alkylimidazolium tetrafluoroborate salts.

A series of dicationic imidazolium bis(tetrafluoroborate) salts were newly synthesized, and their phase transition behaviors were correlated with thermal, scattering, optical and conductivity results. The bis-imidazolium salts having side-chain lengths of C6-C10 showed plastic crystal mesophases, while a liquid crystal mesophase was formed in the bis-imidazolium salts with long side-chains (C11 and C12). Soft plastic and liquid crystalline phases were also confirmed by wide-angle X-ray diffraction. For the bis-imidazolium salts exhibiting a plastic crystal mesophase, the ionic conductivity suddenly increased at the melting temperature. However, the bis-imidazolium salts with long side-chains showed a slope increase during the liquid crystal-liquid crystal transition.