Chemical characterization and sources of personal exposure to fine particulate matter (PM2.5) in the megacity of Guangzhou, China.

Concurrent ambient and personal measurements of fine particulate matter (PM2.5) were conducted in eight districts of Guangzhou during the winter of 2011. Personal-to-ambient (P-C) relationships of PM2.5 chemical components were determined and sources of personal PM2.5 exposures were evaluated using principal component analysis and a mixed-effects model. Water-soluble inorganic ions (e.g., SO42-, NO3-, NH4+, C2O42-) and anhydrosugars (e.g., levoglucosan, mannosan) exhibited median personal-to-ambient (P/C) ratios < 1 accompanied by strong P-C correlations, indicating that these constituents in personal PM2.5 were significantly affected by ambient sources. Conversely, elemental carbon (EC) and calcium (Ca2+) showed median P/C ratios greater than unity, illustrating significant impact of local traffic, indoor sources, and/or personal activities on individual's exposure. SO42- displayed very low coefficient of divergence (COD) values coupled with strong P-C correlations, implying a uniform distribution of SO42- in the urban area of Guangzhou. EC, Ca2+, and levoglucosan were otherwise heterogeneously distributed across individuals in different districts. Regional air pollution (50.4 ± 0.9%), traffic-related particles (8.6 ± 0.7%), dust-related particles (5.8 ± 0.7%), and biomass burning emissions (2.0 ± 0.2%) were moderate to high positive sources of personal PM2.5 exposure in Guangzhou. The observed positive and significant contribution of Ca2+ to personal PM2.5 exposure, highlighting indoor sources and/or personal activities, were driving factors determining personal exposure to dust-related particles. Considerable discrepancies (COD values ranging from 0.42 to 0.50) were shown between ambient concentrations and personal exposures, indicating caution should be taken when using ambient concentrations as proxies for personal exposures in epidemiological studies.

Characterization of ambient-generated exposure to fine particles using sulfate as a tracer in the Chinese megacity of Guangzhou.

Total personal exposures can differ from the concentrations measured at stationary ambient monitoring sites. To provide further insight into factors affecting exposure to particles, chemical tracers were used to separate total personal exposure into its ambient and non-ambient components. Simultaneous measurements of ambient and personal exposure to fine particles (PM2.5) were conducted in eight districts of Guangzhou, a megacity in South China, during the winter of 2011. Considerable significant correlations (Spearman's Rho, rs) between personal exposures and ambient concentrations of sulfate (SO42-; rs>0.68) were found in contrast to elemental carbon (EC; rs>0.37). The average fraction of personal SO42- to ambient SO42- resulting in an adjusted ambient exposure factor of α=0.72 and a slope of 0.73 was determined from linear regression analysis when there were minimal indoor sources of SO42-. From all data pooled across the districts, the estimated average ambient-generated and non-ambient-generated exposure to PM2.5 were 55.3µg/m3 (SD=23.4µg/m3) and 18.1µg/m3 (SD=29.1µg/m3), respectively. A significant association was found between ambient-generated exposure and ambient PM2.5 concentrations (Pearson's r=0.51, p<0.001). As expected, the non-ambient generated exposure was not related to the ambient concentrations. This study highlights the importance of both ambient and non-ambient components of total personal exposure in the megacity of Guangzhou. Our results support the use of SO42- as a tracer of personal exposure to PM2.5 of ambient origin in environmental and epidemiological studies.

Characterization of particulate-bound PAHs in rural households using different types of domestic energy in Henan Province, China.

The concentrations and composition of sixteen PAHs adsorbed to respirable particulate matter (PM10≤10 µm) and inhalable particulate matter (PM2.5≤2.5 µm) were determined during autumn and winter in rural households of Henan Province, China, which used four types of domestic energy [crop residues, coal, liquid petroleum gas (LPG) and electricity] for cooking and heating. The present results show that there were significantly (p<0.05) seasonal variations of particulate-bound PAHs in the rural households. The daily mean concentrations of particulate-bound PAHs in the kitchens, sitting rooms and outdoors were apparently higher in winter than those in autumn, except those in the kitchens using coal. The present study also shows that there were obvious variations of particulate-bound PAHs among the four types of domestic energy used in the rural households. The households using LPG for cooking can, at least in some circumstances, have higher concentrations of PAHs in the kitchens than using crop residues or electricity. In addition, using coal in the sitting rooms seemed to result in apparently higher concentrations of particulate-bound PAHs than using the other three types of domestic energy during winter. The most severe contamination occurred in the kitchens using LPG in winter, where the daily mean concentrations of PM2.5-bound PAHs were up to 762.5±931.2 ng m(-3), indicating that there was serious health risk of inhalation exposure to PAHs in the rural households of Henan Province. Rural residents' exposure to PM2.5-bound PAHs in kitchens would be roughly reduced by 69.8% and 85.5% via replacing coal or crop residues with electricity in autumn. The pilot research would provide important supplementary information to the indoor air pollution studies in rural area.

Potential cytotoxicity of water-soluble fraction of dust and particulate matters and relation to metal(loid)s based on three human cell lines.

Hepatocellular liver carcinoma (HepG2), human skin derived keratinocyte (KERTr,) and lung epithelial carcinoma (A549) were employed in MTT assay to evaluate the cytotoxicity of water-soluble fraction of road dust, air-conditioning (AC) filter dust and PM2.5 via ingestion, dermal contact and inhalation. Their effects on cell growth were dependent on exposure time and concentration. The LC20s of PM2.5 for A549 cell were approximately one order of magnitude lower than those of road dust and AC filter dust for KERTr cell and HepG2 cell. The LC20s of aqueous extracts were negatively correlated to the water-soluble metal(loid)s contained in dust coarse particles (KERTr: p=0.004; HepG2: p<0.001). However, no significant correlation between soluble metal(loid)s and LC20s of PM2.5 was observed for A549 cell (p>0.05). Other water-soluble components in dust and PM might cause the cell hazards synergistically or additively with metal(loid)s.

Levels of PM2.5/PM10 and associated metal(loid)s in rural households of Henan Province, China.

Although a majority of China's rural residents use solid fuels (biomass and coal) for household cooking and heating, clean energy such as electricity and liquid petroleum gas is becoming more popular in the rural area. Unfortunately, both solid fuels and clean energy could result in indoor air pollution. Daily respirable particulate matter (PM≤10 µm) and inhalable particulate matter (PM≤2.5 µm) were investigated in kitchens, sitting rooms and outdoor area in rural Henan during autumn (Sep to Oct 2012) and winter (Jan 2013). The results showed that PM (PM2.5 and PM10) and associated metal(loid)s varied among the two seasons and the four types of domestic energy used. Mean concentrations of PM2.5 and PM10 in kitchens during winter were 59.2-140.4% and 30.5-145.1% higher than those during autumn, respectively. Similar with the trends of PM2.5 and PM10, concentrations of As, Pb, Zn, Cd, Cu, Ni and Mn in household PM2.5 and PM10 were apparently higher in winter than those in autumn. The highest mean concentrations of PM2.5 and PM10 (368.5 and 588.7 µg m(-3)) were recorded in sitting rooms in Baofeng during winter, which were 5.7 and 3.9 times of corresponding health based guidelines for PM2.5 and PM10, respectively. Using coal can result in severe indoor air pollutants including PM and associated metal(loid)s compared with using crop residues, electricity and gas in rural Henan Province. Rural residents' exposure to PM2.5 and PM10 would be roughly reduced by 13.5-22.2% and 8.9-37.7% via replacing coal or crop residues with electricity. The present study suggested that increased use of electricity as domestic energy would effectively improve indoor air quality in rural China.

Contamination and risk assessment (based on bioaccessibility via ingestion and inhalation) of metal(loid)s in outdoor and indoor particles from urban centers of Guangzhou, China.

Road dust, household air-conditioning (AC) filter dust and PM2.5 were collected to investigate the contamination of metal(loid)s (Cr, Mn, Ni, Cu, Zn, As, Cd, Sn, Sb, Hg and Pb) in outdoor and indoor urban environments of Guangzhou. Zinc was found to be the most abundant element in road dust and household PM2.5, while the concentration of Pb was the highest in AC filter dust. Enrichment factor (EF) was used to assess the influence of human activity on the contamination of these metal(loid)s. Ingestion and inhalation were the two exposure pathways applied for risk assessment. Physiologically based extraction test (PBET) was used to estimate the oral bioaccessibilities of metal(loid)s in road dust and AC filter dust. Respiratory bioaccessible fraction of metal(loid)s via household PM2.5 was extracted with lung simulating solution. Household AC filter dust was more hazardous to human health than road dust, especially to children. Arsenic was found to be the most risky element based on the risk assessment.

Determining coefficients in a reconstructed aerosol concentrations model from observed visibility.

A model reconstructing aerosol loading from observed visibility was proposed by Rosenfeld et al. in 2007, and it has been adopted by many researchers. The validity of original coefficients of this model was examined by a correlation analysis between visibility and PM10 concentration. The results showed that the coefficients in this model are not applicable in the region studied and they needed to be adjusted. Optimized coefficients were determined using several approaches in this study. The authors suggest that the methodology put forward by this paper would be meaningful for not only the reconstruction of long-term aerosol concentration data but also the application of the model proposed by Rosenfeld et al.

Observation of elevated fungal tracers due to biomass burning in the Sichuan Basin at Chengdu City, China.

Fungal material (i.e., spores and fragments) is an important component of atmospheric aerosols. In order to examine the variability of fungal abundance in fine particles (PM(2.5)) during a biomass burning season, an intensive measurement campaign was conducted in the Sichuan Basin at Chengdu, a megacity in southwest China, in spring 2009. The aerosol samples were analyzed for carbonaceous species, including molecular tracers for biomass burning and fungal material, and water soluble ions. The results were interpreted with the help of principle component analysis, fire count maps, and the WRF model. Elevated concentrations of arabitol and mannitol were found with average concentrations of 21.5±16.6 ng m(-3) and 43.9±19.3 ng m(-3), respectively, which were unexpectedly higher than those measured in fine particles in any other study reported previously. Even higher concentrations were observed in cases with simultaneous enhancements in the biomass burning tracers levoglucosan and K(+). In the case of influence by pollution plumes from biomass burning regions, the fungal tracer concentrations reached maximum values of 79.6 ng m(-3) and 121.8 ng m(-3), coinciding with peak levels of levoglucosan and K(+). Statistically significant correlations were found between the simultaneously observed fungal tracers (arabitol and mannitol) and biomass burning tracers (levoglucosan and K(+)), suggesting that these species were emitted by co-located sources, and hence the elevated fungal tracers were likely associated with biomass burning activities.

Mercury levels in road dust and household TSP/PM2.5 related to concentrations in hair in Guangzhou, China.

Road dust, household total suspended particulate matters (TSP) and PM2.5 were collected in urban area of Guangzhou, south of China, to investigate the concentrations of total mercury (THg) and methyl mercury (MeHg). The household PM2.5 concentrations varied between 16.2 and 623 µg/m³. The average PM2.5 level (174 µg/m³) from all of the locations exceeded 24-h concentration from WHO air quality guideline The average concentrations of THg and MeHg were: 235 µg/kg and 0.392 µg/kg in road dust, 600 µg/kg and 1.49 µg/kg in TSP; 1006 µg/kg (104 pg/m³) and 1.40 µg/kg (0.134 pg/m³) in PM2.5. Risk assessment showed that the Hazardous quotients (HQs) of exposure to Hg and MeHg via road dust and TSP were less than 1, indicating that no adverse risk was manifested. Ingestion of dust was found to constitute a relatively minor pathway of Guangzhou residents' exposure to Hg. Furthermore, human hair samples from 88 Guangzhou citizens were also analyzed to investigate the mercury accumulation in human body in Guangzhou. The average concentrations of THg and MeHg in human hair samples were 869±831 µg/kg and 104±108 µg/kg respectively. However, no significant correlations of the mercury species were noted between human hair and road dust, TSP and PM2.5.

Characteristics and sources of non-methane hydrocarbons and halocarbons in wintertime urban atmosphere of Shanghai, China.

The characteristics and sources of major hydrocarbons and halocarbons in the wintertime ambient air of urban center of Shanghai, a mega city of China, were investigated. Propane, toluene, ethyl acetate, and benzene were the most abundant hydrocarbons. The majority of species showed significant variability in mixing ratios with occasional episodic increases. The more common use of liquefied petroleum gas fuel for taxis and light motorcycles was believed to lead to high levels of ambient propane over the urban center of Shanghai. Correlating with toluene, dichloromethane, and 1,2-dichloroethane (1,2-DCE), abundant chloromethane (up to a daily mean of 1.61 ± 0.99 ppbv and a maximum of 5.34 ppbv) was mainly associated with industrial emissions, although biomass burnings exist widely in east China. The Chinese New Year (CNY) holiday period with no industrial activity over China provides a platform for the study of industrial emissions over the urban atmosphere of Shanghai. The normal weekly cycles were characterized by higher and more variable mixing ratios during weekdays which dropped during weekends. Enhanced mixing ratios were observed in the fortnight before the CNY holidays due to increased industrial emissions as a result of overtime production to make up for the holiday losses. During the CNY holidays, lower level and less variable mixing ratios were observed. A benzene/toluene (B/T) ratio of 0.6 ± 0.4 (mean ± std.) for the morning rush hour samples was identified to be the characteristic ratio of vehicular emissions. However, a B/T ratio of 0.4 ± 0.2 from vehicles and other sources was derived for the ambient air.

Levoglucosan and carbonaceous species in the background aerosol of coastal southeast China: case study on transport of biomass burning smoke from the Philippines.

INTRODUCTION: Levoglucosan and carbonaceous species in the background aerosol of coastal southeast China were measured at Jianfengling (JFL), a background mountain site in a National Reserve Park on Hainan Island, and at Hok Tsui (HT), a rural site on the southern coast of Hong Kong from April to May of 2004 during an intensive field study. METHODS: We integrated the information from field study, satellite and backward trajectory model to examine the long-range transport of biomass burning smoke from the Philippines and assess its impact on background aerosol in coastal southeast China. RESULTS AND DISCUSSION: The average levoglucosan concentrations were 42 and 30 ng m(-3) at JFL and HT, respectively, while the organic and elemental carbon concentrations were 3.1 and 0.4 µg C m(-3) respectively at JFL, and 4.1 and 1.3 µg C m(-3) respectively at HT. Elevated levoglucosan concentrations of 85-106 ng m(-3) (250-340% extra loadings) at JFL and 57 ng m(-3) (170% extra loading) at HT were observed during transport events in which air masses originated from the Philippines. Fire hot spot counts and aerosol index derived from satellite data showed that the spread of biomass burning smoke from the Philippines resulted in large-scale dense aerosol clouds in the adjacent South China Sea and the western Pacific Ocean. The observed high ratio of two biomass-burning tracers (levoglucosan to mannosan) at JFL (7-36) and HT (27) indicated that the biomass smoke originating from the Philippines had significant contributions from open-field burning of agricultural residues, such as rice straw. The pollution plumes were transported to southeast China resulting in elevated concentrations of carbonaceous aerosol and levoglucosan in particular. Using a simplified receptor-based approach, biomass smoke aerosol was estimated to account for 16-28% of OC in the background atmosphere of Hainan and 4.9% of OC at the rural site of Hong Kong during these episode cases, indicating that biomass burning smoke generated in the Philippines could have a significant contribution to background ambient aerosol of southeast coastal China.

Change of air quality and its impact on atmospheric visibility in central-western Pearl River Delta.

Ambient air quality data, including atmospheric visibility, of Foshan city, a highly polluted city in the Pearl River Delta (PRD), and data obtained by the On-line Air Pollutant Exhaust Monitoring Network (OAPEMN), recently established by the National Emission Monitoring and Control Network for major industrial enterprises, were analyzed and are reported here for the first time, revealing the change in air pollution patterns and its impact on visibility degradation in the last decade. Reduced visibility of less than 8 km (after elimination of rainy and foggy periods) was found 22% of the time from 1998 to 2008, accompanied by elevated levels of pollutants, especially SO2 and PM10, in comparison with that of other developed cities. However, PM10 showed a steady decreasing trend (0.004 mg m⁻³) year⁻¹) during 2001-2008, in contrast to the noticeable increase in ambient NO2 concentrations from ~0.020 mg m⁻³ before 2005 to above 0.050 mg m⁻³ afterward. Multiple regression analysis revealed that the percentage of reduced visibility strongly correlated with PM10 concentration, suggesting that visibility degradation was directly proportional to the loading of particles. Moreover, the fairly significant correlation between reduced visibility and NO2 concentration also implied that the impact of primary emissions of NO2 and enhanced secondary pollutants, formed via photochemical processes in the atmosphere, could not be ignored. The decreased PM10levels were obviously the predominant factor for the improvement in visibility (5.0% per 0.01 mg m⁻³) and were likely due to the implementation of stricter air pollution control measures for industrial exhaust, which also resulted in reduced SO2 pollution levels in the recent 2 years. In particular, the OAPEMN records showed an overall enhanced SO2 removal by 64% in major industrial sectors. The continuous increase in road traffic and lack of efficient NO(x) control strategies in the PRD region, however, caused an increase in ambient NO2 concentrations.