NATURAL RADIONUCLIDES IN AGRICULTURAL PLANTS FROM NORTHERN THAILAND.

Thailand is predominantly an agricultural country. The Northern Region occupies the second largest cultivated land area in the country. To establish baseline data for future environmental monitoring, seventy-nine plant samples including vegetables, fruits and tobaccos and their relevant soils were collected from the major plantation zones of Northern Thailand. Activity concentrations of natural radionuclides in the samples were determined using gamma-ray spectrometry technique. The median activity concentrations of 226Ra and 228Ra in the soil samples were higher than worldwide value, while as those of 40K were comparable with worldwide value. There was a large variation and non-uniform distribution in the soil samples. The activity concentrations of 226Ra, 228Ra and 40K in the plant samples varied widely within plants and between species and were very low compared to their relevant soils. A decreasing trend of their activity concentration has been observed in the order leaf > stem > rhizome/root (as found in galangal); and leaf > stalk/stem (as found in lemongrass).

DEVELOPMENT OF THE CHARCOAL ADSORPTION TECHNIQUE FOR DETERMINATION OF RADON CONTENT IN NATURAL GAS.

A technique for the determination of the radon concentration in natural gas using charcoal adsorption has been developed to study the effects of parameters that influence the adsorption efficiency of radon onto activated charcoal. Several sets of experiments were conducted both in the laboratory and in an actual natural gas field for comparison. The results show that the adsorption capability of radon onto activated charcoal varies inversely with temperature, hydrocarbon concentration and the humidity contained within the natural gas. A technique utilizing dry ice as a coolant was found to be the most effective for trapping radon in natural gas samples at the production site. A desiccant can be used to remove moisture from the sampling gas. The technique described here increases the adsorption efficiency of activated charcoal by 10-20% compared to our previous study.

Baseline data of naturally occurring radionuclides in some native vegetables and fruits in Southern Thailand.

The aim of this study was to provide the baseline data information on natural radioactivities in vegetables and fruits produced and consumed locally in the areas of potential nuclear power plant sites in Thailand. Four provinces (Prajuab-Kirikhan, Chumphon, Surat-Thani and Nakhon-Si-thammarat) were selected for collection of native vegetables and fruits samples, together with their corresponding soils. The activities of (226)Ra, (228)Ra, (40)K and (210)Po were determined in all these samples. The obtained results for (226)Ra, (228)Ra, (40)K and (210)Po for all vegetable and fruit samples were in the range of 1-34, 1-108, 32-4392 and 0.2-47 Bq kg(-1), respectively, which were much lower than those obtained for their corresponding soils.

Systematic approach to characterisation of NORM in Thailand.

The aim of this article is to provide information on the systematic approach that has been developed for the measurement of natural radiation exposure and the characterisation of naturally occurring radioactive materials (NORM) in terms of occurrence and distribution in various industrial processes, including the produced waste from the mineral industries in Thailand. The approach can be adapted for various types of study areas. The importance of collaboration among research institutions is discussed. Some developments include 25 documents; the redesign of the field equipment, such as the gamma survey meter, for convenient access to conduct measurement in various study areas; the method to collect and analyse radon gas from a natural gas pipeline and the manganese dioxide fibre to adsorb radium on-site for laboratory analysis. The NORM project in Thailand has been carried out for more than 10 y to support the development of NORM regulation in Thailand. In the previous studies as well as current, international standards for action levels have been adopted for safety purpose.

Natural radionuclide concentrations in processed materials from Thai mineral industries.

The naturally occurring radioactive materials (NORMs) distributed in products, by-products and waste produced from Thai mineral industries were investigated. Samples were analysed for radioactivity concentrations of two principal NORM isotopes: (226)Ra and (228)Ra. The enrichment of NORM was found to occur during the treatment process of some minerals. The highest activity of (226)Ra (7 × 10(7) Bq kg(-1)) was in the scale from tantalum processing. The radium concentration in the discarded by-product material from metal ore dressing was also enriched by 3-10 times. Phosphogypsum, a waste produced from the production of phosphate fertilisers, contained 700 times the level of (226)Ra concentration found in phosphate ore. Hence, these residues were also sources of exposure to workers and the public, which needed to be controlled.

Comparative dosimetry of radon and thoron.

There is a well-known discrepancy between dosimetrically derived dose conversion factor (DCF) and epidemiologically derived DCF for radon. As the latter DCFs, International Commission on Radiological Protection (ICRP) recommends a value of ∼6.4 nSv (Bq h m(-3))(-1) and 7.9 nSv (Bq h m(-3))(-1) for radon decay products (RnDP) in dwellings and workplaces, respectively. On the other hand, the dosimetric calculations based on the ICRP-66 respiratory tract model derived a DCF of 13 nSv (Bq h m(-3))(-1) and 17 nSv (Bq h m(-3))(-1) for RnDP in dwellings and workplaces, respectively, and 83 nSv (Bq h m(-3))(-1) for thoron decay products (TnDP) in dwellings. In addition, the DCFs derived from both approaches and UNSCEAR were applied to comparative dosimetry for two thoron-enhanced areas (cave dwellings in China and dwellings at a spa town in Japan), where the equilibrium equivalent concentration of radon and equilibrium equivalent concentration of thoron have been measured. In the case of the spa town dwellings, the dose from TnDP was larger than the dose from RnDP.

Experience in using radon and thoron data to solve environmental and water problems.

This study aims to introduce thoron ((220)Rn), a naturally occurring isotope, as a new groundwater tracer for detecting groundwater seepage into Bangkok canals. Previous studies by the group using radioactive radon ((222)Rn) and conductivity as groundwater tracers suggested that there is shallow groundwater seeping into the man-made canals ('klongs') around Bangkok. Furthermore, the groundwater was shown to be an important pathway of nutrient contamination to the surface waters. Thoron is a member of the natural (232)Th decay chain, has exactly the same chemical properties as radon, but has a much shorter half-life (56 s) than radon (3.84 d). By using its advantage of rapid decay, if one detects thoron in the environment, there must be a source nearby. Thus, thoron is potentially an excellent prospecting tool. In the case of measurements in natural waters, sources of thoron should indicate the point of groundwater discharges more precisely than radon. During the surveys in the canals of Bangkok, thoron was successfully measured and its distribution was more variable than that of radon, suggesting that seepage into the canals is not uniform.

A comparative study of thorium activity in NORM and high background radiation area.

Several industrial processes are known to enrich naturally occurring radioactive materials (NORM). To assess such processes with respect to their radiological relevance, characteristic parameters describing this enrichment will lead to interesting information useful to UNSCEAR. In case of mineral treatment plants, the high temperatures used in smelting and refining processes lead to high concentrations of (238)U and (232)Th. Also due to thermal power combustion, concentration of U and Th in the fly ash increases manifold. NORM samples were collected from a Thailand mineral treatment plant and Philippine coal-fired thermal power plants for investigation. Some studies are initiated from a high background radiation area near Gopalpur of Orissa state in India. These NORM samples were analysed by gamma-ray spectrometry as well as inductively coupled plasma mass spectrometry. The radioactivity in case of Orissa soil samples is found to be mainly contributed from thorium. This study attempts to evaluate levels of thorium activity in NORM samples.