1.
Carbohydr Res
; 499: 108228, 2021 Jan.
Artigo
em Inglês
| MEDLINE
| ID: mdl-33429168
RESUMO
In this note, an hydrozirconation/bromination/Michaelis-Arbuzov sequence was developped to introduce a trimethylene phosphonate unit on ketopyranosides. Performed on polyfunctional substrates bearing orthogonal protecting groups, this new approach provided a straightforward entry towards a large diversity of glycophosphomimetics having a quaternary anomeric position.