Efficient nitrogen removal from municipal wastewater using an integrated fixed-film activated sludge process in a novel air-lifting loop reactor: A pilot-scale demonstration.

A novel air-lifting loop reactor combines anoxic, oxic, and settling zones to achieve organic and nutrient removal, as well as solid-liquid separation. To address sludge settling ability and operation stability issues caused by low dissolved oxygen in aerobic zones, this study proposes using modified polypropylene carriers to establish a fixed-film activated sludge (IFAS) system. A pilot-scale demonstration of the IFAS-based air-lifting loop reactor is conducted, and the results show successful operation for approximately 300 days. The pilot-scale reactor achieves a maximum aerobic granulation ratio of 16% in the bulk liquid. The IFAS system contributes to efficient removal of organic matter (96%) and nitrogen (94%) by facilitating simultaneous nitrification and denitrification, as well as fast solid-liquid separation with a low sludge volume index of 34 mL/g. Microbial analysis reveals enrichment of functional bacteria involved in nitrification, denitrification, and flocculation throughout the operation process.

Sustainable high-strength and dimensionally stable composites through in situ regulation and reconstitution of bamboo-derived lignin and hemicellulose contents.

The development of modern construction and transportation industries demands increasingly high requirements for thin, lightweight, high-strength, and highly tough composite materials, such as metal carbides and concrete. Bamboo is a green, low-carbon, fast-growing, renewable, and biodegradable material with high strength and toughness. However, the density of its inner layer is low due to the functional gradient (the volume fraction of vascular bundles decreases from the outer layer to the inner layer), resulting in low performance, high compressibility, and significant amounts of bamboo waste. We utilized chemical and mechanical treatments of bamboo's low-density, low-strength inner layers to create lightweight, ultra-thin, high-strength, and high-toughness composites. The treatment included the partial removal of lignin and hemicellulose to alter the chemical components, followed by mechanical drying and hot pressing. The treated bamboo had 100.8 % higher tensile strength (150.35 MPa), 47.7 % higher flexural strength (97.67 MPa), and 132.0 % higher water resistance and was approximately 68.9 % thinner than the natural bamboo. The excellent physical and mechanical properties of the treated bamboo are attributed to the contraction of parenchyma cells during delignification, the interlocking due to the collapse of parenchyma cells during mechanical drying, and an increase in the density of hydrogen bonds between cellulose molecular chains during hot pressing. Our research provides a new strategy for obtaining sustainable, ultra-thin, lightweight, high-strength, and high-toughness composite materials from bamboo for construction and transportation applications.

Coupling redox flow desalination with lithium recovery from spent lithium-ion batteries.

Electrochemical redox flow desalination is an emerging method to obtain freshwater; however, the costly requirement for continuously supplying and regenerating redox species limits their practical applications. Recycling of spent lithium-ion batteries is a growing challenge for their sustainable utilization. Existing battery recycling methods often involve massive secondary pollution. Here, we demonstrate a redox flow system to couple redox flow desalination with lithium recovery from spent lithium-ion batteries. The spontaneous reaction between a battery cathode material (LiFePO4) and ferricyanide enables the continuous regeneration of the redox species required for desalination. Several critical operating parameters are optimized, including current density, the concentrations of redox species, salt concentrations of brine, and the amounts of added LiFePO4. With the addition of 0.5920 g of spent LiFePO4 in five consecutive batches, the system can operate over 24 h, achieving 70.46 % lithium recovery in the form of LiCl aqueous solution at the concentration of 6.716 g·L-1. Simultaneously, the brine (25 mL, 10000 ppm NaCl) was desalinated to freshwater. Detailed cost analysis shows that this redox flow system could generate a revenue of ¥ 13.66 per kg of processed spent lithium-ion batteries with low energy consumption (0.77 MJ kg-1) and few greenhouse gas emissions indicating excellent economic and environmental benefits over existing lithium-ion battery recycling technologies, such as pyrometallurgical and hydrometallurgical methods. This work opens a new approach to holistically addressing water and energy challenges to achieve sustainable development.

Proteomic analysis reveals LRPAP1 as a key player in the micropapillary pattern metastasis of lung adenocarcinoma.

Objectives: Lung adenocarcinomas have different prognoses depending on their histological growth patterns. Micropapillary growth within lung adenocarcinoma, particularly metastasis, is related to dismal prognostic outcome. Metastasis accounts for a major factor leading to mortality among lung cancer patients. Understanding the mechanisms underlying early stage metastasis can help develop novel treatments for improving patient survival. Methods: Here, quantitative mass spectrometry was conducted for comparing protein expression profiles among various histological subtypes, including adenocarcinoma in situ, minimally invasive adenocarcinoma, and invasive adenocarcinoma (including acinar and micropapillary [MIP] types). To determine the mechanism of MIP-associated metastasis, we identified a protein that was highly expressed in MIP. The expression of the selected highly expressed MIP protein was verified via immunohistochemical (IHC) analysis and its function was validated by an in vitro migration assay. Results: Proteomic data revealed that low-density lipoprotein receptor-related protein-associated protein 1 (LRPAP1) was highly expressed in MIP group, which was confirmed by IHC. The co-expressed proteins in this study, PSMD1 and HSP90AB1, have been reported to be highly expressed in different cancers and play an essential role in metastasis. We observed that LRPAP1 promoted lung cancer progression, including metastasis, invasion and proliferation in vitro and in vivo. Conclusion: LRPAP1 is necessary for MIP-associated metastasis and is the candidate novel anti-metastasis therapeutic target.

High-performance self-desalination powered by triboelectric-electromagnetic hybrid nanogenerator.

Freshwater is an essential resource in today's world, and how to produce freshwater with low or even zero power consumption is a major challenge. Here, a desalination system powered by a triboelectric-electromagnetic hybrid nanogenerator (TEHG) is presented, which can utilize the water's own energy to remove the salt ions from itself, demonstrating a new concept of "self-desalination". At a relatively low rotation speed of 150 rpm, the system can dilute NaCl brine from 4000 ppm to 145 ppm with a high salt removal rate of 147.1 µg cm-2 min-1 and a freshwater productivity of up to 31.1 L m-2 h-1. The actual seawater can also be treated with a total ion removal efficiency of 99.6 % and a freshwater productivity of 2.7 L m-2 h-1, which is superior to other renewable-energy-powered desalination systems. More importantly, fully self-powered desalination process can be realized by manual cranking and hydrokinetic energy impact, both of which are capable of treating 1000 ppm salt feed to the drinking water level. The TEHG-powered desalination system not only provides excellent desalination performance but also addresses the challenges of power consumption and limited capacity, which offers a completely new paradigm of "self-desalination".

Zinc-Organometallic Framework Vaccine Controlled-Release Zn2+ Regulates Tumor Extracellular Matrix Degradation Potentiate Efficacy of Immunotherapy.

Tumor extracellular matrix (ECM) not only forms a physical barrier for T cells infiltration, but also regulates multiple immunosuppressive pathways, which is an important reason for immunotherapy failure. The cyclic guanosine monophosphate-adenosine monophosphate synthase-stimulator of interferon genes (cGAS-STING) pathway plays a key role in activating CD8+ T cells, maintaining CD8+ T cells stemness and enhancing the antitumor effect. Herein, a zinc-organometallic framework vaccine (ZPM@OVA-CpG) prepared by self-assembly, which achieves site-directed release of Zn2+ in dendritic cell (DC) lysosomes and tumor microenvironment under acidic conditions, is reported. The vaccine actively targets DC, significantly enhances cGAS-STING signal, promotes DC maturation and antigen cross-presentation, and induces strong activation of CD8+ T cells. Meanwhile, the vaccine reaches the tumor site, releasing Zn2+ , significantly up-regulates the activity of matrix metalloproteinase-2, degrades various collagen components of tumor ECM, effectively alleviates immune suppression, and significantly enhances the tumor infiltration and killing of CD8+ T cells. ZPM@OVA-CpG vaccine not only solves the problem of low antigen delivery efficiency and weak CD8+ T cells activation ability, but also achieves the degradation of tumor ECM via the vaccine for the first time, providing a promising therapeutic platform for the development of efficient novel tumor vaccines.

Non-uniform dissolved oxygen distribution and high sludge concentration enhance simultaneous nitrification and denitrification in a novel air-lifting reactor for municipal wastewater treatment: A pilot-scale study.

Achieving simultaneous carbon and nitrogen removal with sludge-liquid separation in a single reactor offers a solution to land shortages and improves treatment efficiency in municipal wastewater treatment plants of megacities. This study proposes a novel air-lifting continuous-flow reactor configuration with an alternative-aeration strategy that creates multi-functional zones for anoxic, oxic, and settlement processes. The optimal operating conditions for the reactor include a long anoxic hydraulic retention time, low dissolved oxygen (DO) in the oxic zone, and no specific reflux for external nitrifying liquid, which exhibit a high nitrogen removal efficiency of over 90% in treating real sewage with C/N < 4 in the pilot-scale study. Results show that a high sludge concentration and a low DO concentration facilitate simultaneous nitrification and denitrification, and a well mixing of sludge and substrate in different reaction zones promotes mass transfer and microbial activity. The long-term operation enriches functional microbes for carbon storage and nutrient removal.

Double-photoelectrode redox desalination of seawater.

High energy consumption and low salt removal rate are key barriers to realizing practical electrochemical seawater desalination processes. Here, we demonstrate a novel solar-driven redox flow desalination device with double photoelectrodes to achieve efficient desalination without electrical energy consumption. The device consists of three parts: one photoanode unit, one photocathode unit, and one redox flow desalination unit sandwiched between the two photoelectrode units. The photoelectrode units include a TiO2 photoanode and a NiO photocathode sensitized with N719 dye, triiodide/iodide redox electrolyte, and graphite paper integrated electrodes decorated with 3,4-ethylene-dioxythiophene. Two salt feeds are located between two ferro/ferricyanide redox flow chambers. Under light illumination, high-quality freshwater is obtained from brackish water containing different concentrations of NaCl from 1000 to 12,000 ppm with a high NaCl removal rate. The device can work in multiple desalination cycles without significant performance declines. Furthermore, natural seawater with an ionic conductivity of 53.45 mS cm-1 is desalinated to freshwater. This new design opens opportunities to realize efficient and practical solar-driven desalination processes.

Role of solvent in plasma-assisted peroxymonosulfate-hydrothermal process for plastic conversion.

Hydrothermal processes are considered a promising strategy for the conversion of ever-growing plastic wastes. Plasma-assisted peroxymonosulfate-hydrothermal process has attracted increasing attention in enhancing the efficiency of hydrothermal conversion. However, the role of solvent in this process is unclear and rarely researched. Herein, the conversion process with different water-based solvents was investigated based on a plasma-assisted peroxymonosulfate-hydrothermal reaction. As the ratio of the solvent effective volume in the reactor increased from 20% to 53.3%, the conversion efficiency displayed an obvious decrease from 7.1% to 4.2%. The results indicated that the increased pressure caused by the solvent greatly reduced the surface reaction and forced the hydrophilic groups to shift back to the carbon chain, thereby reducing the reaction kinetics. A further increase in the solvent effective volume ratio could promote the conversion in the inner layer of the plastics to achieve an increase of the conversion efficiency. These findings can provide valuable guidance for the design of hydrothermal conversion for plastic wastes.

The multi-functional system of electrochemical desalination, RhB degradation and Cr (VI) removal.

SYNOPSIS: : The single function of salt removal limits the further development of the CDI system. A multi-function CDI device is proposed to achieve electrochemical desalination, organics degradation and dichromate ion removal.

Effect of Accelerated Aging on Bamboo Fiber Lunch Box and Correlation with Soil Burial Degradation.

This study aimed to investigate the mechanical property decay that might occur during actual use and soil burial degradation of bamboo fiber lunch boxes. For this, the effects of three accelerated aging methods, namely damp-heat treatment, freeze-thaw cycle, and artificial weathering cycle, on the tensile strength, dynamic viscoelasticity, and chemical composition of bamboo fiber lunch boxes were compared, and a correlation of their mechanical property decay with soil burial degradation was established to obtain an acceleration factor (SAF) with aging time as a reference. The results showed that the mechanical properties of the bamboo fiber lunch box decreased to different degrees under the three accelerated methods, and the tensile strength decreased to less than 50% after 36 h of damp-heat treatment, 5 freeze-thaw cycles, and 11 artificial weathering cycles. However, after 10 days, the mechanical property of lunch box in soil degradation decreased by more than 50%. Infrared spectroscopy demonstrated rapid hemicellulose degradation during damp-heat treatment and freeze-thaw cycle, as well as a minor quantity of lignin, and a significant amount of lignin under artificial weathering cycle. With the freeze-thaw cycle and the artificial weathering cycle, the relative crystallinity dropped quickly, by 32.3% and 21.5%, respectively, but under damp-heat treatment, the crystallinity dropped barely, by 43.5%. The damage caused by the freeze-thaw cycle to the mechanical properties of bamboo fiber lunch boxes was greater than that by the damp-heat treatment and artificial weathering cycle. The fluctuation of SAF under freeze-thaw cycle was also more drastic. Compared to the artificial weathering cycle, the damp-heat treatment was more stable and reliable in predicting the decay law of soil burial degradation tensile strength of bamboo fiber lunch boxes.

A novel vertical dual-loop reactor for rapid start-up of simultaneous partial nitrification and anammox process in treating landfill leachate: Performances and mechanisms.

A novel vertical dual-loop reactor (VDLR) was developed to start and conduct a single-stage partial nitritation (PN) and anammox (PN/A) process for treating landfill leachate. Results showed that the total nitrogen (TN) removal reached 1.54 kg N/m3·d in the VDLR. It exhibited excellent mixing uniformity and buffer performance, which can increase the nitrogen removal performance up to 42.1 % via the improvement of anammox granular sludge activity (a particle size of 0.5-1 mm). Mass balance and microbial analysis indicated that the VDLR achieved efficient TN removal via anammox (99.24 %) and AOB (Nitrosomonas and Ellin6067) and anAOB (Candidatus kuenenia) played a vital role in this process.

Bamboo-Inspired Renewable, Lightweight, and Vibration-Damping Laminated Structural Materials for the Floor of a Railroad Car.

It is important for the floor of railroad cars to be fitted with vibration- and noise-reducing, fire-resistant, and durable materials. In this study, inspired by a delicate and ordered bamboo gradient structure and excellent multilevel interfaces, we fabricated a laminated composite with characteristics similar to those of the bamboo structure using a simple and effective "top-down" method by laminating fast-growing wood, waste rubber, and bamboo charcoal plastic sheets made of bamboo processing residues. This composite material combines the unique advantages of a laminated structure design and composite interface bionics. The low density (0.73 g/cm3) of the laminated composite results in a specific modulus of 13.03 GPa cm3/g, a vibration damping ratio of 6.61%, and an impact toughness of 14.16 J/cm2, which is significantly higher than that of other wood-based composites used for high-speed rail floors, such as Birch plywood (BP). In addition, we also investigated the laminated composite bonding property, fire resistance, and fatigue performance. This biomimetic bamboo-wood composite material has great potential for application in fitting the floor of eco-friendly railway cars.

High-Performance Photoelectrochemical Desalination Based on the Dye-Sensitized Bi2O3 Anode.

In this work, a solar-driven redox flow desalination system is reported, which combines a solar cell based on a Bi2O3 photoanode and a redox flow desalination cell through an integrated electrode. The Bi2O3 film was prepared through a simple one-step water bath deposition method and served as a photoanode after the coating of the N719 dye. The activated carbon (AC)-coated graphite paper served as both the integrated electrode and counter electrode. The I3-/I- redox electrolyte circulates in the solar cell channel between the photoanode and intergrated electrode, while the [Fe(CN)6]4-/[Fe(CN)6]3- electrolyte circulates in the redox flow desalination part between the integrated electrode and counter electrode. This dye-sensitized solar-driven desalination cell is capable of achieving a maximum salt removal rate of 62.89 µg/(cm2·min) without consuming any electrical power. The combination of the solar cell and redox flow desalination is highly efficient with double functions of desalination and energy release using light as a driving force. This current research work is significant for the development of efficient and stable photoanode materials in photoelectrochemical desalination.

Photo-Assisted Rechargeable Battery Desalination.

Herein, we propose a novel design of photo-assisted battery desalination, which provides the tri-function within a single device including the photo-assisted charge (electrical energy saving), energy storage, and desalination (salt removal). The photoelectrode (N719/TiO2) is directly integrated into the zinc-iodide (Zn-I) battery with the desalination stream in the middle portion of the device. This architecture can provide a reduced energy consumption up to 50%, an energy output of 42 W h mol-1NaCl, and a desalination rate of 13 µg/cm2 min-1. This work is significant for the inter-discipline study of the redox flow energy storage and energy-saving desalination.

Towards Dendrite-Free Potassium-Metal Batteries: Rational Design of a Multifunctional 3D Polyvinyl Alcohol-Borax Layer.

K metal is the optimal anode for K-ion batteries because of its high capacity and low operating potential, but it suffers from fast capacity fading and safety issues due to an unstable solid electrolyte interphase (SEI) and continuous K-dendrite growth. Herein, to obtain promising potassium-metal batteries, a 3D polyvinyl-alcohol (PVA)-borax layer is designed, which enables a dendrite-free K-plating/stripping process. The protective layer possesses good wettability, high K-ion diffusivity, and good structural stability, which enables a "uniform and underneath plating" behavior, therefore exhibiting a stable electrochemical performance. As a result, Cu current collector with PVA-borax (PVA-borax@Cu) exhibits a stable cycling lifetime for 700 h at 0.5 mA cm-2 and 500 h at 1 mA cm-2 at 10 % depth of discharge (DOD) without dendrite formation. Even at a high utilization of 25 % DOD and 50 % DOD, the PVA-borax@Cu shows a stable cycle for 180 h and 100 h, respectively.

Efficient elimination of the pollutants in eutrophicated water with carbon strengthened expanded graphite based photocatalysts: Unveiling the synergistic role of metal sites.

Metal sites (Ni, Bi or Ag) were introduced into carbon strengthened expanded graphite (CEG) based photocatalysts, and performed as a novel strategy to enhance the elimination of Microcystis aeruginosa and microcystin-LR from water. Results show that metal doping can efficiently improve the adsorption of harmful algae and enhance the photocatalytic activities in inactivation of harmful algae and degradation of MC-LR. Among the CEG catalysts, Ni-CEG can achieve the highest removal rate up to 90.6% for algal cells with 5 h visible light irradiation, while Bi-CEG catalyst provides the best performance for MC-LR degradation with the removal rate of 80.9% in 6 h visible light irradiation. In general, considering the coexistence of algal cells and microcystin-LR, Bi-CEG is proved to be an excellent candidate for the remediation of eutrophicated waters since it can achieve the efficient removal of both harmful algae and MC-LR. DFT calculations indicate that metal doping can transform the photocatalysts into n-type semiconductor, and provide the mid-gap state. In addition, the partial charge density distribution near Fermi level was mainly composed by the metal dopants, which can enhance the interaction with harmful algae and MC-LR.

Defect-Rich Amorphous Iron-Based Oxide/Graphene Hybrid-Modified Separator toward the Efficient Capture and Catalysis of Polysulfides.

The sluggish sulfur reduction reaction, severe shuttle effect, and poor conductivity of sulfur species are three main problems in lithium-sulfur (Li-S) batteries. Functional materials with a strong affinity and catalytic effect toward polysulfides play a key role in addressing these issues. Herein, we report a defect-rich amorphous a-Fe3O4-x/GO material with a nanocube-interlocked structure as an adsorber as well as an electrocatalyst for the Li-S battery. The composition and defect structure of the material are determined by X-ray diffraction, high-resolution transmission electron microscopy, Raman spectroscopy, and X-ray photoelectron spectroscopy measurements. The distinctive open framework architecture of the as-engineered composite inherited from the metal-organic framework precursor ensures the stability and activity of the catalyst during extended cycles. The oxygen defects in the amorphous structure are capable of absorbing polysulfides and similarly work as catalytic centers to boost polysulfide conversion. Taking advantage of a-Fe3O4-x/GO on the separator surface, the Li-S battery shows a capacity over 610 mA h g-1 at 1 C and a low decay rate of 0.12% per cycle over 500 cycles and superior rate capability. The functional material made via the low-cost synthesis process provides a potential solution for advanced Li-S batteries.

Electrocatalytic desalination with CO2 reduction and O2 evolution.

Multifunctional electrocatalytic desalination is a promising method to increase the production of additional valuable chemicals during the desalination process. In this work, a multifunctional desalination device was demonstrated to effectively desalinate brackish water (15 000 ppm) to 9 ppm while generating formate from captured CO2 at the Bi nanoparticle cathode and releasing oxygen at the Ir/C anode. The salt feed channel is sandwiched between two electrode chambers and separated by ion-exchange membranes. The electrocatalytic process accelerates the transportation of sodium ions and chloride ions in the brine to the cathode and anode chamber, respectively. The fastest salt removal rate to date was obtained, reaching up to 228.41 µg cm-2 min-1 with a removal efficiency of 99.94%. The influences of applied potential and the concentrations of salt feed and electrolyte were investigated in detail. The current research provides a new route towards an electrochemical desalination system.