Magnetic biochar serves as adsorbents and catalyst supports for the removal of antibiotics from wastewater: A review.

Numerous antibiotics are being released into the natural environment through wastewater. As antibiotic usage increases annually, its detrimental impact on the environment is escalating. Addressing environmental sustainability and human health requires significant attention towards antibiotic removal. In recent years, magnetic biochar (MBC) has gained widespread application in water treatment due to its exceptional adsorption and catalytic degradation capabilities. Antibiotics such as sulfamethoxazole (SMX), tetracycline (TC), ciprofloxacin (CIP), and others commonly exhibit an adsorption capacity by MBC ranging from 5 mg/g to 900 mg/g. Moreover, MBC typically removes over 90% of these antibiotics within 60 min. The effectiveness of antibiotic removal is significantly influenced by various preparation and modification methods. Furthermore, the incorporation of magnetism enables the material to be recycled and reused multiple times, thereby reducing consumption costs. This article discusses recent studies on antibiotic removal using MBC. It has been observed that variations in the selection of raw material and preparation procedures significantly affect antibiotic removal, while the mechanisms involved in antibiotic removal remain ambiguous. Additionally, it has been noted that the removal process may lead to secondary pollution and high preparation costs. Therefore, this review comprehensively outlines the utilization of MBC in the removal of antibiotics from wastewater, including aspects such as modification, preparation, removal mechanism, and factors influencing removal, and providing recommendations for antibiotic development. The aim is to offer researchers a clear understanding to advance the field of MBC materials.

Inorganic Flame-Retardant Coatings Based on Magnesium Potassium Phosphate Hydrate.

A magnesium potassium phosphate hydrate-based flame-retardant coating (MKPC) is formulated by dead-burnt magnesium oxide (magnesia) and potassium dihydrogen phosphate (KH2PO4), behaving as a matrix. Constituents of the MKPC include wollastonite, vermiculite, aluminum fluoride, aluminum trihydroxide, and calcium carbonate. Some of the ingredients inter-react to produce mullite whiskers at high temperatures, despite an acid-base hydration induced reaction between magnesia and KH2PO4. The MKPC's thermal, corrosion-resistant, mechanical, and flame-resistant properties were analyzed using scanning electron microscopy, electrochemical corrosion testing, compression testing, thermogravimetric analysis, and freeze/thaw tests. The results show that with the molar ratio = 4 of magnesia to KH2PO4, MKPC demonstrates lower thermal conductivity (0.19 W/m K), along with better corrosion resistance, stronger compressive strength (10.5 MPa), and higher bonding strength (6.62 kgf/cm2) to the steel substrate. Furthermore, acceptable additives to the formulation could enhance its flame-retardancy and increase its mechanical strength as well. Mullite whisker formed from the interaction of wollastonite, aluminum trihydroxide, and aluminum fluoride acts as an outer ceramic shield that enhances mechanical strength and compactness. In addition, Mg-containing minerals with calcium carbonate treated at high temperatures, transform into magnesium calcium carbonate after releasing CO2. At the optimum composition of MKPC (magnesia/KH2PO4 molar ratio = 4; wollastonite:vermiculite = 20:10 wt.%; aluminum trihydroxide = 10 wt.%; and calcium carbonate = 5 wt.%), coated on a steel substrate, the flame-resistance limit results exhibit below 200 °C on the back surface of the steel substrate after one hour of flaming (ca. 1000 °C) on the other surface, and the flame-resistance rating results demonstrate only 420 °C on the back surface of the steel substrate after three hours of flaming (>1000 °C) on the other surface. Both requirements for the flame-resistance limit and three-hour flame-resistance rating are met with the optimum compositions, indicating that MKPC plays an effective role in establishing flame-retardancy.

Simultaneously enhanced removal of PAHs and nitrogen driven by Fe2+/Fe3+ cycle in constructed wetland through automatic tidal operation.

The lack of dissolved oxygen and weak substrate removal capacity in constructed wetlands (CW) leads to terrible removal of nitrogen and polycyclic aromatic hydrocarbons (PAHs). In this study, automatic tidal flow CW microcosms were constructed by improving the oxygen environment (siphon and air-duct) and substrate (magnetite) to enhance purification performance and the mechanism was explored. The results showed that the addition of air-duct could improve the oxygen collection and thus improved the NH4+ removal efficiency. Additionally, nitrogen removal was improved greatly due to the simultaneous nitrification and denitrification in aerobic layer with the addition of magnetite. Mass balance indicated the microbial degradation dominated (32-62%) the removal of PAHs. Metagenomic analysis proved the existence of magnetite enhanced the number of PAHs-degrading bacteria, functional groups and metabolic pathways and thus greatly improved the microbial degradation of PAHs. Furthermore, Fe2+/Fe3+ cycle played an important role in promoting the anaerobic degradation of PAHs, which might be served as an electron conduit to establish the direct interspecies electron transfer between iron-reducing bacteria (e.g. Deltaproteobacteria bacterium) and Anaerolineae bacterium to degrade PAHs efficiently. This study provided better understanding of the simultaneous removal of PAHs and nitrogen in tidal flow CWs.

Priming effects of root exudates on the source-sink stability of benzo[a]pyrene in wetlands: A microcosm experiment.

Although wetland is acknowledged as an effective ecosystem to remove persistent organic pollutants (POPs), the change of environmental factors would switch wetland from transient sink to permanent source. Thus, it is worthwhile to meticulously study its source-sink dynamics. In this study, root exudates' effect on the source-sink dynamics of benzo[a]pyrene (BaP) in a simulated wetland sediment system was investigated, and the identification results of labile, stable-adsorbed, and bound-residue fraction highlighted that root exudates' priming effects could accelerate fraction transformation and depuration of BaP in wetlands. The priming effects are the combination results of three different pathways, including decrease in the interfacial tension of BaP (1.21-4.19%), occurrence of co-metabolism processes (2.47-12.51%), and liberation of mineral-bound pathways (1.82-83.14%). All these pathways promoted the abiotic and biotic BaP removal processes, which reduced the half-life of BaP from 42 days to 13 days, and subsequently reduced the hazard potential of BaP in the wetland. Root exudates' priming effects accounted for over 99.84% in total dissipation of BaP, regulated the source-sink stability of the wetlands contaminated by BaP. The source-sink dynamics provides a conceptual framework for understanding environmental fate, risk assessment and further storage management of POPs in wetlands.

Intensive removal of PAHs in constructed wetland filled with copper biochar.

In this study, biochar-loading copper ions (Cu-BC), a novel composite for removing phenanthrene very efficiently from water, was prepared using the impregnation method. The performance of constructed wetlands (CWs) with these modified and original biochar as substrates was analyzed. CW with Cu-BC removed a large amount of phenanthrene (94.09 ± 3.02%). According to the surface characteristics analysis, Cu-BC can promote the removal of pollutants via complex absorption, hydrophobic adsorption, increasing the Lewis Pair and electrostatic attraction. Furthermore the higher nitrate removal rate in the treated system (91.11 ± 1.17%) was observed to have higher levels of bacterial metabolic diversity and denitrifier types. The phenanthrene accumulated in plants with this treatment system was enhanced by the role of copper in photosynthesis. It is able to boost the plant extraction of organic matter.

Effects of hydraulic retention time on the performance of algal-bacterial-based aquaponics (AA): focusing on nitrogen and oxygen distribution.

The effects of hydraulic retention time (HRT) on the performance of algal-bacterial-based aquaponics (AA) were investigated in this study. Both the highest fish growth and algal biomass increase were observed in the AA system at 2-day HRT, resulting in the highest nitrogen utilization efficiency (NUE) (39.28%) in this microcosm. On the contrary, ammonia oxidation bacteria (AOB) abundance at 4-day HRT was approximately ten times higher than that at 2-day HRT, since longer HRT would benefit bacterial growth. The 15N labeling study showed that microalgae assimilation was the main pathway of NH4+ removal in the AA system, and oxygen produced by microalgae could in situ support complete nitrification, thus leading to much lower NH4+ concentrations at 2-day HRT. Accordingly, better water quality was achieved at 2-day HRT. Considering all the factors, HRT of 2-day was considered to be optimal for the AA system.