High Performance Concretes with Highly Reactive Rice Husk Ash and Silica Fume.

The search for new sources of high-quality non-crystalline silica as a construction material for high-performance concrete has attracted the interest of researchers for several decades. Numerous investigations have shown that highly reactive silica can be produced from rice husk, an agricultural waste that is abundantly available in the world. Among others, the production of rice husk ash (RHA) by chemical washing with hydrochloric acid prior to the controlled combustion process has been reported to provide higher reactivity because such a process removes alkali metal impurities from RHA and provides an amorphous structure with higher surface area. This paper presents an experimental work in which a highly reactive rice husk ash (TRHA) is prepared and evaluated as a replacement for Portland cement in high-performance concretes. The performance of RHA and TRHA was compared with that of conventional silica fume (SF). Experimental results showed that the increase in compressive strength of concrete with TRHA was clearly observed at all ages, generally higher than 20% of the strength obtained with the control concrete. The increase in flexural strength was even more significant, showing that concrete with RHA, TRHA and SF increased by 20%, 46%, and 36%, respectively. Some synergistic effect was observed when polyethylene-polypropylene fiber was used for concrete with TRHA and SF. The chloride ion penetration results also indicated that the use of TRHA had similar performance compared to that of SF. Based on the results of statistical analysis, the performance of TRHA is found to be identical to that of SF. The use of TRHA should be further promoted considering the economic and environmental impact that will be achieved by utilizing agricultural waste.

The Effect of Changes in the Separation Process for the Performance of Recycled Cement Powder: A Comparison with a Previous Study for Radioactive Waste Immobilization.

Separation of hydrated cement paste from aggregate is a key technology to reduce the amount of radioactive concrete waste during the decommissioning process. If separated cement-paste portions can be recycled as a solidifying agent for other radioactive waste, the amount of radioactive concrete waste could be close to "zero". A study was conducted to achieve circular economy in the area of concrete decommissioning and found it to be successfully used as a solidifying agent for immobilization of liquid radioactive waste. However, previous work used a process that requires large amounts of energy (heat treatment was applied to most of the concrete fraction) because the objective was to completely remove hydrated cement powder from the aggregate. In this work, the separation system was modified to increase energy efficiency (heat treatment was applied to separated powder only), but such a change decreased the surface area of the recycled cement powder due to a higher inclusion of aggregate powder. A relatively lower solution to binder ratio could have been achieved for the preparation of wasteform specimens, and as a result, a 28 day compressive strength of wasteform could have become higher, but the final leachability indices were lower than the results observed from previous work. The results from 28 day compressive strength, thermal cycling and 90 day leaching experiments met the acceptance criteria for wasteform, indicating that this modified system can also be used for immobilization of liquid radioactive waste to meet the "zero" production of concrete waste during the decommissioning of a nuclear power plant. It should be noted that accurate monitoring of aggregate content in recycled cement powder during production is important to maintain proper reactivity of recycled cement powder.

Frost Resistance Number to Assess Freeze and Thaw Resistance of Non-Autoclaved Aerated Concretes Containing Ground Granulated Blast-Furnace Slag and Micro-Silica.

Aerated concrete (AC), such as cellular concrete, autoclaved aerated concrete (AAC), and non-autoclaved aerated concrete (NAAC), having excellent insulation properties, is commonly used in buildings located in cold regions, such as Nur-Sultan in Kazakhstan, the second coldest capital city in the world, because it can contribute to a large energy saving. However, when the AC is directly exposed to the repeated freeze and thaw (F-T) cycles, its F-T resistance can be critical because of lower density and scaling resistance of the AC. Moreover, the evaluation of the F-T resistance of the AC based on the durability factor (DF) calculated by using the relative dynamic modulus of elasticity may overestimate the frost resistance of the AC due to the millions of evenly distributed air voids in spite of its weak scaling resistance. In the present study, the F-T resistance of NAAC mixtures with various binary or ternary combinations of ground granulated blast-furnace slag (GGBFS) and micro-silica was assessed mainly using the ASTM C 1262/C1262M-16 Standard Test Method for Evaluating the Freeze-Thaw Durability of Dry-Cast Segmental Retaining Wall Units and Related Concrete Units. Critical parameters to affect the F-T resistance performance of the NAAC mixture such as compressive strength, density, water absorption, air-void ratio (VR), moisture uptake, durability factor (DF), weight loss (Wloss), the degree of saturation (Sd), and residual strength (Sres) were determined. Based on the determined parameter values, frost resistance number (FRN) has been developed to evaluate the F-T resistance of the NAAC mixture. Test results showed that all NAAC mixtures had good F-T resistance when they were evaluated with DF. Binary NAAC mixtures generally showed higher Sd and Wloss and lower DF and Sres than those of ternary NAAC mixtures. It was determined that the Sd was a key factor for the F-T resistance of NAAC mixtures. Finally, the developed FRN could be an appropriate tool to evaluate the F-T resistance of the NAAC mixture.

Revisiting the Effect of Slag in Reducing Heat of Hydration in Concrete in Comparison to Other Supplementary Cementitious Materials.

Blast furnace slag (SL) is an amorphous calcium aluminosilicate material that exhibits both pozzolanic and latent hydraulic activities. It has been successfully used to reduce the heat of hydration in mass concrete. However, SL currently available in the market generally experiences pre-treatment to increase its reactivity to be closer to that of portland cement. Therefore, using such pre-treated SL may not be applicable for reducing the heat of hydration in mass concrete. In this work, the adiabatic and semi-adiabatic temperature rise of concretes with 20% and 40% SL (mass replacement of cement) containing calcium sulfate were investigated. Isothermal calorimetry and thermal analysis (TGA) were used to study the hydration kinetics of cement paste at 23 and 50 °C. Results were compared with those with control cement and 20% replacements of silica fume, fly ash, and metakaolin. Results obtained from adiabatic calorimetry and isothermal calorimetry testing showed that the concrete with SL had somewhat higher maximum temperature rise and heat release compared to other materials, regardless of SL replacement levels. However, there was a delay in time to reach maximum temperature with increasing SL replacement level. At 50 °C, a significant acceleration was observed for SL, which is more likely related to the pozzolanic reaction than the hydraulic reaction. Semi-adiabatic calorimetry did not show a greater temperature rise for the SL compared to other materials; the differences in results between semi-adiabatic and adiabatic calorimetry are important and should be noted. Based on these results, it is concluded that the use of blast furnace slag should be carefully considered if used for mass concrete applications.

Enhancement of thermal neutron shielding of cement mortar by using borosilicate glass powder.

Concrete has been used as a traditional biological shielding material. High hydrogen content in concrete also effectively attenuates high-energy fast neutrons. However, concrete does not have strong protection against thermal neutrons because of the lack of boron compound. In this research, boron was added in the form of borosilicate glass powder to increase the neutron shielding property of cement mortar. Borosilicate glass powder was chosen in order to have beneficial pozzolanic activity and to avoid deleterious expansion caused by an alkali-silica reaction. According to the experimental results, borosilicate glass powder with an average particle size of 13µm showed pozzolanic activity. The replacement of borosilicate glass powder with cement caused a slight increase in the 28-day compressive strength. However, the incorporation of borosilicate glass powder resulted in higher thermal neutron shielding capability. Thus, borosilicate glass powder can be used as a good mineral additive for various radiation shielding purposes.

Effect of Microorganism Sporosarcina pasteurii on the Hydration of Cement Paste.

Years of research have shown that the application of microorganisms increases the compressive strength of cement-based material when it is cured in a culture medium. Because the compressive strength is strongly affected by the hydration of cement paste, this research aimed to investigate the role of the microorganism Sporosarcina pasteurii in hydration of cement paste. The microorganism's role was investigated with and without the presence of a urea-CaCl2 culture medium (i.e., without curing the specimens in the culture medium). The results showed that S. pasteurii accelerated the early hydration of cement paste. The addition of the urea-CaCl2 culture medium also increased the speed of hydration. However, no clear evidence of microbially induced calcite precipitation appeared when the microorganisms were directly mixed with cement paste.

Flocculation and sedimentation in suspensions using ultrasonic wave reflection.

This work was undertaken to help understand and interpret the ultrasonic wave reflection response of Portland cement paste as it transforms from a fluid-like suspension to a solid in the first hours after mixing. A high impact polystyrene buffer (delay line) was used to measure small changes in the P- and S-wave reflection coefficients. Two materials were studied: a non-hydrating colloidal alumina suspension whose microstructure was manipulated between dispersed and flocculated states by adjusting the pH and a coarse silica suspension that readily sedimented. The S-wave reflection coefficient clearly distinguished between dispersed and flocculated states. Sedimentation of particles in dispersed suspensions was distinguished using the P-wave reflection coefficient. Based on these findings, the observed P- and S-wave responses from hydrating Portland cement paste are interpreted in terms of flocculation and sedimentation processes.

Using ultrasonic wave reflection to measure solution properties.

Ultrasonic wave reflection coefficients of aqueous solutions were measured using high-impact polystyrene as a buffer material to provide enhanced sensitivity over metal or ceramic buffer materials. The wave reflection values showed linear reduction when the concentration of chemical species in solution was increased, but a distinct relation between concentration and reflection coefficient was obtained for each solute species tested. However, more unified relationships were observed between reflection coefficient and other solution parameters - solution density, acoustic impedance, and P-wave velocity - that were consistent for all solution species. Based on this behavior an expression to compute solution density solely from reflection coefficient is derived, which can be applied to estimate solution density in solutions of unknown solute species and concentration when other measurements, such as wave velocity, are not possible.