RESUMO
Novel temperature-sensitive luminescent materials, Ba2Gd2Ge4O13 doped with Bi3+, Bi3+/Sm3+ or Bi3+/Eu3+ ions, have been prepared using a conventional solid-state reaction technique. The XRPD study has verified that all the synthesized germanates crystallize in the monoclinic system (space group C2/c, Z = 4). The crystal lattice of the compounds consists of zigzag chains of edge-sharing Me2O7 (Me = Bi3+, Eu3+ or Sm3+) dimers, [Ge4O13] units, and ten-coordinated Ba atoms. Under UV excitation the powders exhibit the luminescence corresponding to the 3P1 â 1S0 (310-550 nm) transition in Bi3+ and 4G5/2 â 6HJ (550-730 nm) in Sm3+ or 5D0 â 7FJ (570-720 nm) transitions in Eu3+ ions. Heating of Ba2Gd1.94Bi0.01Sm0.05Ge4O13 and Ba2Gd1.89Bi0.01Eu0.1Ge4O13 phosphors leads to an irregular decrease in the intensity of the main emission lines. It has been found that the fluorescence intensity ratio between a wide band in the 310-530 nm region and peaks at longer wavelengths may be successfully used as a temperature-dependent characteristic. Absolute/relative sensitivity values for Ba2Gd1.94Bi0.01Sm0.05Ge4O13 and Ba2Gd1.89Bi0.01Eu0.1Ge4O13 germanates reach 0.19% K-1/0.80% K-1 and 2.21% K-1/0.58% K-1, respectively. The above parameters indicate that Ba2Gd2Ge4O13:Bi3+/Sm3+ or Bi3+/Eu3+ samples can be used as potential luminescent materials for non-contact temperature measurement.
RESUMO
A new series of Ba2RE2Ge4O13 (RE = Pr, Nd, Gd, Dy) germanates and Ba2Gd2-xEuxGe4O13 (x = 0.1-0.8) solid solutions have been synthesized using the solid-state reaction technique and characterized by X-ray powder diffraction. All compounds crystallize in the monoclinic system, space group C2/c, Z = 4. The crystal lattice consists of RE2O12 dimers, zigzag C2-symmetric [Ge4O13]10- tetramers, and ten-coordinated Ba atoms located in voids between polyhedra. The density-functional theory (DFT) calculations performed on a rich set of Ba2RE2Ge4O13 compounds have confirmed the high thermodynamic stability of monoclinic modification. Under ultraviolet (UV) light excitation Ba2Gd2-xEuxGe4O13 phosphors exhibit an orange-red emission corresponding to the characteristic f-f transitions in Eu3+ ions. The highest intensity of lines at 580 nm (5D0â7F0), 582-602 nm (5D0â7F1), 602-640 nm (5D0â7F2), 648-660 nm (5D0â7F3), and 680-715 nm (5D0â7F4) is observed for the samples with x = 0.4-0.6. The possibility of their application has been assessed by studying their color characteristics, quantum efficiency, and thermal stability. The obtained data indicate that Ba2Gd2-xEuxGe4O13 solids can be considered as promising materials for UV-excited phosphor-converted light-emitting diodes (LEDs) if an aluminum nitride substrate (λex = 255 nm) is used as a semiconductor chip.