RESUMO
The chemical composition of spontaneous volatile emission from Rubus ulmifolius flowers and fruits during different stages of development was evaluated by HS-SPME-GC/MS. In total, 155 chemical compounds were identified accounting 84.6 - 99.4% of whole aroma profile of flowers samples and 92.4 - 96.6% for fruit samples. The main constituents were α-copaene, ß-caryophyllene, germacrene D, (E,E)-α-farnesene, 1,7-octadien-3-one,2-methyl-6-methylene, tridecane, (E)-2-hexenol acetate, (E)-3-hexenol acetate and cyperene. The results give a chemotaxonomic contribution to the characterization of the VOCs emitted from flowers and fruits during their ontogenic development.
Assuntos
Flores/química , Frutas/química , Odorantes/análise , Rubus/química , Rubus/crescimento & desenvolvimento , Compostos Orgânicos Voláteis/análise , Cromatografia Gasosa , Flores/crescimento & desenvolvimento , Frutas/crescimento & desenvolvimento , Espectrometria de Massas , Microextração em Fase Sólida , Compostos Orgânicos Voláteis/químicaRESUMO
The composition of the essential oil (EO) obtained from dry leaves of Chiliadenus bocconei Brullo (Asteraceae subfam. Inulae), a Maltese endemic aromatic plant, collected in two different seasons, was evaluated in this work. The main EO components identified in the summer foliage were camphor (25.6%), borneol (27.1%) and τ-cadinol (13.9%). In the winter foliage τ-cadinol was the most represented compound (59.5%), followed by camphor (13.1). A comparison is also made between the EO composition of the two samples of C. bocconei and the EO obtained from different aerial parts of C. lopadusanus, an endemic plant of Lampedusa Island, another Mediterranean Island.
Assuntos
Asteraceae/química , Óleos Voláteis/química , Folhas de Planta/química , Estações do AnoRESUMO
The essential oil obtained from the bark of Cinnamomum zeylanicum Blume (Lauraceae) and three of its main components, eugenol, (E)-cinnamaldehyde, and linalool (representing 82.5% of the total composition), were tested in two in vitro models of peroxynitrite-induced nitration and lipid peroxidation. The essential oil and eugenol showed very powerful activities, decreasing 3-nitrotyrosine formation with IC50 values of 18.4 microg/mL and 46.7 microM, respectively (reference compound, ascorbic acid, 71.3 microg/mL and 405.0 microM) and also inhibiting the peroxynitrite-induced lipid peroxidation showing an IC50 of 2.0 microg/mL and 13.1 microM, respectively, against 59.0 microg/mL (235.5 microM) of the reference compound Trolox. On the contrary, (E)-cinnamaldehyde and linalool were completely inactive.
