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1.
Medwave ; 23(8)2023 Sep 27.
Artigo em Inglês | MEDLINE | ID: mdl-37756680

RESUMO

Introduction: The COVID-19 pandemic resulted in an unpredictable healthcare crisis with a high psychological burden on healthcare workers. Objective: To evaluate burnout levels and their associated demographics and occupational factors among intensive care unit healthcare workers during the COVID-19 pandemic in a single hospital in the city of Temuco, Chile. Methods: A cross-sectional design in which a sociodemographic questionnaire and the Maslach Burnout Inventory for Human Services were sent to health care workers in a single Chilean Intensive Care Unit during the pandemic COVID-19. Burnout levels, demographic, and occupational factors are reported using descriptive statistics; correlations between burnout levels and demographic-occupational factors were analyzed using Spearman's and rank-biserial correlation coefficients; and multiple linear stepwise regression was used to assess the contribution of demographic and occupational factors to participants' burnout levels. Results: A total of 84 participants (46 women and 38 men) were included in the analysis. Depersonalization and low personal accomplishment were evidenced in 95.2% and 98.8% of the intensive care unit healthcare workers, respectively. Emotional exhaustion was positively correlated with having children ( = 0.72; < 0.01). Age ( = 0.79; < 0.05), sex ( = 0.30; < 0.05), and prior experience in intensive care unit facilities ( = 0.71; < 0.05) were correlated with depersonalization. Feeling of personal accomplishment was positively correlated with with sex ( = 0.70; < 0.05) and type of work shift ( = 0.29; < 0.01). Conclusions: The intensive care unit healthcare workers in this study reported high levels of depersonalization and low feelings of personal accomplishment during an advanced stage of the COVID-19 pandemic. Older age, being female, having children, having intensive care unit experience, and working at 4th shift were factors related to burnout dimensions.

2.
Medwave ; 23(8): e2720, 29-09-2023.
Artigo em Inglês | LILACS-Express | LILACS | ID: biblio-1511422

RESUMO

Introduction The COVID-19 pandemic resulted in an unpredictable healthcare crisis with a high psychological burden on healthcare workers. Objective To evaluate burnout levels and their associated demographics and occupational factors among intensive care unit healthcare workers during the COVID-19 pandemic in a single hospital in the city of Temuco, Chile. Methods A cross-sectional design in which a sociodemographic questionnaire and the Maslach Burnout Inventory for Human Services were sent to health care workers in a single Chilean Intensive Care Unit during the pandemic COVID-19. Burnout levels, demographic, and occupational factors are reported using descriptive statistics; correlations between burnout levels and demographic-occupational factors were analyzed using Spearman's and rank-biserial correlation coefficients; and multiple linear stepwise regression was used to assess the contribution of demographic and occupational factors to participants' burnout levels. Results A total of 84 participants (46 women and 38 men) were included in the analysis. Depersonalization and low personal accomplishment were evidenced in 95.2% and 98.8% of the intensive care unit healthcare workers, respectively. Emotional exhaustion was positively correlated with having children ( = 0.72; < 0.01). Age ( = 0.79; < 0.05), sex ( = 0.30; < 0.05), and prior experience in intensive care unit facilities ( = 0.71; < 0.05) were correlated with depersonalization. Feeling of personal accomplishment was positively correlated with with sex ( = 0.70; < 0.05) and type of work shift ( = 0.29; < 0.01). Conclusions The intensive care unit healthcare workers in this study reported high levels of depersonalization and low feelings of personal accomplishment during an advanced stage of the COVID-19 pandemic. Older age, being female, having children, having intensive care unit experience, and working at 4th shift were factors related to burnout dimensions.

3.
Chemosphere ; 339: 139463, 2023 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-37480952

RESUMO

The release of ammonia (as NH4+) into water bodies causes serious environmental problems. Therefore, the removal of ammonia from wastewater effluents has become a worldwide concern. New autotrophic biological alternatives for ammonia removal could reduce the limitations of conventional organic carbon-dependent nitrification-denitrification methods. Here, the potential of anaerobic ammonium oxidation coupled to Fe3+ reduction (a process known as Feammox) is studied in wastewater treatment plants of the yeast and beer production industry, not related to ammonium or iron treatment. This process is presented as a viable option to improve the efficiency of ammonia removal from wastewater. The results of this study show that enrichments under Feammox conditions achieved removals of 28.19-32.25% of the total NH4+. The highest rates of ammonium removal and Fe3+ reduction were achieved using FeCl3 as iron source and pH = 7.0. Different environmental conditions for the enrichments were studied and it was found that the use of sodium acetate as a carbon source and an incubation temperature of 35 °C presented higher rates of iron reduction and higher increase in nitrate concentration, related to ammonium oxidative processes. Likewise, the presence of relevant species of the iron and nitrogen cycles as Ferrovum myxofaciens, Geobacter spp, Shewanella spp, Albidiferax ferrireducens and Anammox was verified, supporting the findings of this study. These results provide information that may be relevant to the potential applicability of Feammox to treat wastewater with high ammonia load and could help develop cost-effective and environmentally friendly methods for ammonium removal in wastewater treatment plants.


Assuntos
Compostos de Amônio , Águas Residuárias , Amônia , Anaerobiose , Nitrogênio/análise , Ferro , Oxirredução , Reatores Biológicos , Desnitrificação
4.
Opt Express ; 30(8): 13540-13555, 2022 Apr 11.
Artigo em Inglês | MEDLINE | ID: mdl-35472964

RESUMO

We demonstrate an optical detection and decoding strategy to increase the information rate and spectral efficiency of free-space laser communication links affected by turbulence by means of dense orbital angular momentum (OAM) modulation. Using three candidate receiver architectures-based on a Shack-Hartmann sensor, a Mode Sorter, and a complex conjugate projection scheme as a base case-we demonstrate an algorithmic classification system based on the received OAM spectra produced by these architectures. This classification scheme allows low-error-rate data transmission in turbulence using 16-OAM, 32-OAM, and 64-OAM symbol constellations, with OAM states between -20 and 20. We evaluate and compare their performance under weak to strong atmospheric turbulence conditions using an accuracy metric and confusion matrices.

5.
Chaos ; 30(11): 113138, 2020 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-33261332

RESUMO

A single-species reaction-diffusion model is used for studying the coexistence of multiple stable steady states. In these systems, one can define a potential-like functional that contains the stability properties of the states, and the essentials of the motion of wave fronts in one- and two-dimensional space. Using a quintic polynomial for the reaction term and taking advantage of the well-known butterfly bifurcation, we analyze the different scenarios involving the competition of two and three stable steady states, based on equipotential curves and points in parameter space. The predicted behaviors, including a front splitting instability, are contrasted to numerical integrations of reaction fronts in two dimensions.

6.
Opt Lett ; 45(19): 5534-5537, 2020 Oct 01.
Artigo em Inglês | MEDLINE | ID: mdl-33001940

RESUMO

We propose a method for identifying orbital angular momentum (OAM) states within a vortex superposition using a Shack-Hartmann (SH) sensor as a spatial-diversity detector. We define a local OAM at every pixel of the SH image, from which we construct an OAM spectrum. The topological charges are determined from the OAM spectrum using a low-complexity algorithm, resulting in estimates that are robust to beam wandering. Data from a 200 m experimental transmission are successfully tested using the proposed technique.

7.
Chaos ; 30(7): 073134, 2020 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-32752625

RESUMO

The propagation of light pulses in dual-core nonlinear optical fibers is studied using a model proposed by Sakaguchi and Malomed. The system consists of a supercritical complex Ginzburg-Landau equation coupled to a linear equation. Our analysis includes single standing and walking solitons as well as walking trains of 3, 5, 6, and 12 solitons. For the characterization of the different scenarios, we used ensemble-averaged square displacement of the soliton trajectories and time-averaged power spectrum of the background waves. Power law spectra, indicative of turbulence, were found to be associated with random walks. The number of solitons (or their separations) can trigger anomalous random walks or totally suppress the background waves.

8.
Phys Rev E ; 101(6-1): 062140, 2020 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-32688580

RESUMO

It is well established that ensembles of globally coupled stochastic oscillators may exhibit a nonequilibrium phase transition to synchronization in the thermodynamic limit (infinite number of elements). In fact, since the early work of Kuramoto, mean-field theory has been used to analyze this transition. In contrast, work that directly deals with finite arrays is relatively scarce in the context of synchronization. And yet it is worth noting that finite-number effects should be seriously taken into account since, in general, the limits N→∞ (where N is the number of units) and t→∞ (where t is time) do not commute. Mean-field theory implements the particular choice first N→∞ and then t→∞. Here we analyze an ensemble of three-state coupled stochastic units, which has been widely studied in the thermodynamic limit. We formally address the finite-N problem by deducing a Fokker-Planck equation that describes the system. We compute the steady-state solution of this Fokker-Planck equation (that is, finite N but t→∞). We use this steady state to analyze the synchronic properties of the system in the framework of the different order parameters that have been proposed in the literature to study nonequilibrium transitions.

9.
Proc Math Phys Eng Sci ; 476(2236): 20190712, 2020 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-32398931

RESUMO

The CO oxidation on platinum-group metals under ultra-high-vacuum conditions is one of the most studied surface reactions. However, the presence of disturbing species and competing reactions are often neglected. One of the most interesting additional gases to be treated is hydrogen, due to its importance in technical applications and its inevitability under vacuum conditions. Adding hydrogen to the reaction of CO and O2 leads to more adsorbed species and competing reaction steps towards water formation. In this study, a model for approaching the competing surface reactions CO+O 2 + H2 is presented and discussed. Using the framework of bifurcation theory, we show how the steady states of the extended system correspond to a swallowtail catastrophe set with a tristable regime within the swallowtail. We explore numerically the possibility of reaching all stable states and illustrate the experimental challenges such a system could pose. Lastly, an approximative first-principle approach to diffusion illustrates how up to three stable states balance each other while forming heterogeneous patterns.

10.
Phys Rev E ; 100(5-1): 052218, 2019 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-31869896

RESUMO

We present a feedback mechanism for dissipative solitons in the cubic complex Ginzburg-Landau (CGL) equation with a nonlinear gradient term. We are making use of a mechanical analog containing contributions from a potential and from a nonlinear viscous term. The feedback mechanism relies on the continuous supply of energy as well as on dissipation of the stable pulse. Our picture is corroborated by the numerical solution of the full equation. A quintic contribution is not necessary for stabilization in the presence of a suitable nonlinear gradient term as we show by using a linear stability analysis for the stationary pulses. We find that the limit of vanishing magnitude of the nonlinear gradient term is singular: For exactly vanishing nonlinear gradient terms stable pulses do not exist. This situation is qualitatively different from that found for the cubic-quintic complex Ginzburg-Landau equation with a nonlinear gradient term: In this case the limit of a vanishing nonlinear gradient contribution is completely smooth. We demonstrate that, for small magnitude of the nonlinear gradient term simple types of scaling behavior are found for the amplitude, the full width at half maximum (FWHM), the velocity, and the effective frequency of the stable pulse as a function of the magnitude of the nonlinear gradient term.

11.
Chaos ; 28(7): 075505, 2018 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-30070531

RESUMO

Solitons, which describe the propagation of concentrated beams of light through nonlinear media, can exhibit a variety of behaviors as a result of the intrinsic dissipation, diffraction, and the nonlinear effects. One of these phenomena, modeled by the complex Ginzburg-Landau equation, is chaotic explosions, transient enlargements of the soliton that may induce random transversal displacements, which in the long run lead to a random walk of the soliton center. As we show in this work, the transition from nonmoving to moving solitons is not a simple bifurcation but includes a sequence of normal and anomalous random walks. We analyze their statistics with the distribution of generalized diffusivities, a novel approach that has been used successfully for characterizing anomalous diffusion.

12.
J Chem Phys ; 149(4): 044706, 2018 Jul 28.
Artigo em Inglês | MEDLINE | ID: mdl-30068191

RESUMO

It has been shown that CO oxidation on Pd(111) under ultrahigh vacuum conditions can suffer rare transitions between two stable states triggered by weak intrinsic perturbations. Here we study the effects of adding controlled noise by varying the concentrations of O2 and CO that feed the vacuum chamber, while the total flux stays constant. In addition to the regime of rare transitions between states of different CO2 reaction rates induced by intrinsic fluctuations, we found three distinct effects of external noise depending on its strength: small noise suppresses transitions and stabilizes the upper rate state; medium noise induces bursting; and large noise gives rise to reversible transitions in both directions. To explain some of the features present in the dynamics, we propose an extended stochastic model that includes a global coupling through the gas phase to account for the removal of CO gas caused by the adsorption of the Pd surface. The numerical simulations based in the model show a qualitative agreement with the noise-induced transitions found in experiments, but suggest that more complex spatial phenomena are present in the observed fluctuations.

13.
Front Neurosci ; 12: 235, 2018.
Artigo em Inglês | MEDLINE | ID: mdl-29740268

RESUMO

Electroencephalography (EEG) is the standard diagnosis method for a wide variety of diseases such as epilepsy, sleep disorders, encephalopathies, and coma, among others. Resting-state functional magnetic resonance (rs-fMRI) is currently a technique used in research in both healthy individuals as well as patients. EEG and fMRI are procedures used to obtain direct and indirect measurements of brain neural activity: EEG measures the electrical activity of the brain using electrodes placed on the scalp, and fMRI detects the changes in blood oxygenation that occur in response to neural activity. EEG has a high temporal resolution and low spatial resolution, while fMRI has high spatial resolution and low temporal resolution. Thus, the combination of EEG with rs-fMRI using different methods could be very useful for research and clinical applications. In this article, we describe and show the results of a new methodology for processing rs-fMRI using seeds positioned according to the 10-10 EEG standard. We analyze the functional connectivity and adjacency matrices obtained using 65 seeds based on 10-10 EEG scheme and 21 seeds based on 10-20 EEG. Connectivity networks are created using each 10-20 EEG seeds and are analyzed by comparisons to the seven networks that have been found in recent studies. The proposed method captures high correlation between contralateral seeds, ipsilateral and contralateral occipital seeds, and some in the frontal lobe.

14.
Phys Rev Lett ; 116(20): 203901, 2016 May 20.
Artigo em Inglês | MEDLINE | ID: mdl-27258868

RESUMO

We demonstrate the occurrence of anomalous diffusion of dissipative solitons in a "simple" and deterministic prototype model: the cubic-quintic complex Ginzburg-Landau equation in two spatial dimensions. The main features of their dynamics, induced by symmetric-asymmetric explosions, can be modeled by a subdiffusive continuous-time random walk, while in the case dominated by only asymmetric explosions, it becomes characterized by normal diffusion.

15.
J Math Neurosci ; 5(1): 2, 2015 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-26458901

RESUMO

The formation of oscillating phase clusters in a network of identical Hodgkin-Huxley neurons is studied, along with their dynamic behavior. The neurons are synaptically coupled in an all-to-all manner, yet the synaptic coupling characteristic time is heterogeneous across the connections. In a network of N neurons where this heterogeneity is characterized by a prescribed random variable, the oscillatory single-cluster state can transition-through [Formula: see text] (possibly perturbed) period-doubling and subsequent bifurcations-to a variety of multiple-cluster states. The clustering dynamic behavior is computationally studied both at the detailed and the coarse-grained levels, and a numerical approach that can enable studying the coarse-grained dynamics in a network of arbitrarily large size is suggested. Among a number of cluster states formed, double clusters, composed of nearly equal sub-network sizes are seen to be stable; interestingly, the heterogeneity parameter in each of the double-cluster components tends to be consistent with the random variable over the entire network: Given a double-cluster state, permuting the dynamical variables of the neurons can lead to a combinatorially large number of different, yet similar "fine" states that appear practically identical at the coarse-grained level. For weak heterogeneity we find that correlations rapidly develop, within each cluster, between the neuron's "identity" (its own value of the heterogeneity parameter) and its dynamical state. For single- and double-cluster states we demonstrate an effective coarse-graining approach that uses the Polynomial Chaos expansion to succinctly describe the dynamics by these quickly established "identity-state" correlations. This coarse-graining approach is utilized, within the equation-free framework, to perform efficient computations of the neuron ensemble dynamics.

16.
J Chem Phys ; 141(16): 164106, 2014 Oct 28.
Artigo em Inglês | MEDLINE | ID: mdl-25362271

RESUMO

In this work, we study a surface reaction on Pd(111) crystals under ultra-high-vacuum conditions that can be modeled by two coupled reaction-diffusion equations. In the bistable regime, the reaction exhibits travelling fronts that can be observed experimentally using photo electron emission microscopy. The spatial profile of the fronts reveals a coverage-dependent diffusivity for one of the species. We propose a method to solve the nonlinear eigenvalue problem and compute the direction and the speed of the fronts based on a geometrical construction in phase-space. This method successfully captures the dependence of the speed on control parameters and diffusivities.

17.
Artigo em Inglês | MEDLINE | ID: mdl-24032897

RESUMO

Dissipative solitons show a variety of behaviors not exhibited by their conservative counterparts. For instance, a dissipative soliton can remain localized for a long period of time without major profile changes, then grow and become broader for a short time-explode-and return to the original spatial profile afterward. Here we consider the dynamics of dissipative solitons and the onset of explosions in detail. By using the one-dimensional complex Ginzburg-Landau model and adjusting a single parameter, we show how the appearance of explosions has the general signatures of intermittency: the periods of time between explosions are irregular even in the absence of noise, but their mean value is related to the distance to criticality by a power law. We conjecture that these explosions are a manifestation of attractor-merging crises, as the continuum of localized solitons induced by translation symmetry becomes connected by short-lived trajectories, forming a delocalized attractor. As additive noise is added, the extended system shows the same scaling found by low-dimensional systems exhibiting crises [J. Sommerer, E. Ott, and C. Grebogi, Phys. Rev. A 43, 1754 (1991)], thus supporting the validity of the proposed picture.

18.
Phys Rev Lett ; 109(17): 178303, 2012 Oct 26.
Artigo em Inglês | MEDLINE | ID: mdl-23215228

RESUMO

We investigate a two-dimensional extended system showing chaotic and localized structures. We demonstrate the robust and stable existence of two types of exploding dissipative solitons. We show that the center of mass of asymmetric dissipative solitons undergoes a random walk despite the deterministic character of the underlying model. Since dissipative solitons are stable in two-dimensional systems we conjecture that our predictions can be tested in systems as diverse as nonlinear optics, parametric excitation of granular media and clay suspensions, and sheared electroconvection.

19.
J Chem Phys ; 137(6): 064105, 2012 Aug 14.
Artigo em Inglês | MEDLINE | ID: mdl-22897253

RESUMO

In this article we consider the CO oxidation on Ir(111) surfaces under large external noise with large autocorrelation imposed on the composition of the feed gas, both in experiments and in theory. We report new experimental results that show how the fluctuations force the reaction rate to jump between two well defined states. The statistics of the reaction rate depend on those of the external noise, and neither of them have a gaussian distribution, and thus they cannot be modeled by white or colored noise. A continuous-time discrete-state Markov process is proposed as a suitable model for the observed phenomena. The model captures the main features of the observed fluctuations and can be modified to accommodate other surface reactions and other systems under non-gaussian external noise.

20.
Phys Rev E Stat Nonlin Soft Matter Phys ; 83(5 Pt 2): 056214, 2011 May.
Artigo em Inglês | MEDLINE | ID: mdl-21728637

RESUMO

We investigate the route to exploding dissipative solitons in the complex cubic-quintic Ginzburg-Landau equation, as the bifurcation parameter, the distance from linear onset, is increased. We find for a large class of initial conditions the sequence: stationary localized solutions, oscillatory localized solutions with one frequency, oscillatory localized solutions with two frequencies, and exploding localized solutions. The transition between localized solutions with one and with two frequencies, respectively, is analyzed in detail. It is found to correspond to a forward Hopf bifurcation for these localized solutions as the bifurcation parameter is increased. In addition, we make use of power spectra to characterize all time-dependent states. On the basis of all information available, we conclude that the sequence oscillatory localized solutions with one frequency, oscillatory localized solutions with two frequencies, and exploding dissipative solitons can be interpreted as the analog of the Ruelle-Takens-Newhouse route to chaos for spatially localized solutions.

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