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1.
ACS Omega ; 9(26): 28268-28282, 2024 Jul 02.
Artigo em Inglês | MEDLINE | ID: mdl-38973927

RESUMO

This work characterizes technical scale flames of suspension firing of gaseous and solid fuel mixtures through in-flame measurements with focus on nitrogen oxide (NOx) formation. The aims are to investigate the impacts of substituting a solid fuel with a gaseous fuel on the important mechanisms for NOx formation and to highlight important considerations for burner design. The investigation was performed in a 100 kW test unit that fires mixtures of propane and lignite. The global emissions levels and in-flame compositions were measured. A detailed reaction model was used to interpret the experimental results. The study highlights the importance of the early release of volatile nitrogen to reduce the levels of NOx. The findings indicate that substituting lignite by propane is advantageous in terms of reducing NO emissions, primarily due to the diminished input of fuel-bound nitrogen to the flame. However, this holds true only if the flame temperature of the gaseous fuel does not increase excessively. Finally, introducing a relatively small quantity of solid fuel to a propane flame appears to alter the flame behavior to resembles that of the "solid fuel," with a longer and wider flame. Despite this, carbon monoxide and nitrogen oxide concentrations remain like gas combustion but more dispersed.

2.
Swiss Med Wkly ; 152: w30163, 2022 04 11.
Artigo em Inglês | MEDLINE | ID: mdl-35752951

RESUMO

BACKGROUND: In Switzerland, SARS-CoV-2 vaccination campaigns started in early 2021. Vaccine coverage reached 65% of the population in December 2021, mostly with mRNA vaccines from Moderna and Pfizer-BioNtech. Simultaneously, the proportion of vaccinated among COVID-19-related hospitalisations and deaths rose, creating some confusion in the general population. We aimed to assess vaccine effectiveness against severe forms of SARS-CoV-2 infection using routine surveillance data on the vaccination status of COVID-19-related hospitalisations and deaths, and data on vaccine coverage in Switzerland. METHODS: We considered all routine surveillance data on COVID-19-related hospitalisations and deaths received at the Swiss Federal Office of Public Health from 1 July to 1 December 2021. We estimated the relative risk of COVID-19-related hospitalisation or death for not fully vaccinated compared with fully vaccinated individuals, adjusted for the dynamics of vaccine coverage over time, by age and location. We stratified the analysis by age group and by calendar month. We assessed variations in the relative risk of hospitalisation associated with the time since vaccination. RESULTS: We included a total of 5948 COVID-19-related hospitalisations of which 1245 (21%) were fully vaccinated patients, and a total of 739 deaths of which 259 (35%) were fully vaccinated. We found that the relative risk of COVID-19 related hospitalisation was 12.5 (95% confidence interval [CI] 11.7-13.4) times higher for not fully vaccinated than for fully vaccinated individuals. This translates into a vaccine effectiveness against hospitalisation of 92.0% (95% CI 91.4-92.5%). Vaccine effectiveness against death was estimated to be 90.3% (95% CI 88.6-91.8%). Effectiveness appeared to be comparatively lower in age groups over 70 and during the months of October and November 2021. We also found evidence of a decrease in vaccine effectiveness against hospitalisation for individuals vaccinated for 25 weeks or more, but this decrease appeared only in age groups below 70. CONCLUSIONS: The observed proportions of vaccinated among COVD-19-related hospitalisations and deaths in Switzerland were compatible with a high effectiveness of mRNA vaccines from Moderna and Pfizer-BioNtech against hospitalisation and death in all age groups. Effectiveness appears comparatively lower in older age groups, suggesting the importance of booster vaccinations. We found inconclusive evidence that vaccine effectiveness wanes over time. Repeated analyses will be able to better assess waning and the effect of boosters.


Assuntos
COVID-19 , Idoso , COVID-19/epidemiologia , COVID-19/prevenção & controle , Vacinas contra COVID-19 , Pré-Escolar , Humanos , SARS-CoV-2 , Suíça/epidemiologia , Eficácia de Vacinas
3.
Proc Math Phys Eng Sci ; 477(2248): 20200606, 2021 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-35153552

RESUMO

In the context of the de Broglie-Bohm pilot-wave theory, numerical simulations for simple systems have shown that states that are initially out of quantum equilibrium-thus violating the Born rule-usually relax over time to the expected |ψ|2 distribution on a coarse-grained level. We analyse the relaxation of non-equilibrium initial distributions for a system of coupled one-dimensional harmonic oscillators in which the coupling depends explicitly on time through numerical simulations, focusing on the influence of different parameters such as the number of modes, the coarse-graining length and the coupling constant. We show that in general the system studied here tends to equilibrium, but the relaxation can be retarded depending on the values of the parameters, particularly to the one related to the strength of the interaction. Possible implications on the detection of relic non-equilibrium systems are discussed.

4.
Entropy (Basel) ; 20(10)2018 Oct 11.
Artigo em Inglês | MEDLINE | ID: mdl-33265868

RESUMO

Recently, the properties of bouncing oil droplets, also known as "walkers," have attracted much attention because they are thought to offer a gateway to a better understanding of quantum behavior. They indeed constitute a macroscopic realization of wave-particle duality, in the sense that their trajectories are guided by a self-generated surrounding wave. The aim of this paper is to try to describe walker phenomenology in terms of de Broglie-Bohm dynamics and of a stochastic version thereof. In particular, we first study how a stochastic modification of the de Broglie pilot-wave theory, à la Nelson, affects the process of relaxation to quantum equilibrium, and we prove an H-theorem for the relaxation to quantum equilibrium under Nelson-type dynamics. We then compare the onset of equilibrium in the stochastic and the de Broglie-Bohm approaches and we propose some simple experiments by which one can test the applicability of our theory to the context of bouncing oil droplets. Finally, we compare our theory to actual observations of walker behavior in a 2D harmonic potential well.

5.
Proc Math Phys Eng Sci ; 470(2171): 20140288, 2014 Nov 08.
Artigo em Inglês | MEDLINE | ID: mdl-25383020

RESUMO

We consider Bohm's second-order dynamics for arbitrary initial conditions in phase space. In principle, Bohm's dynamics allows for 'extended' non-equilibrium, with initial momenta not equal to the gradient of phase of the wave function (as well as initial positions whose distribution departs from the Born rule). We show that extended non-equilibrium does not relax in general and is in fact unstable. This is in sharp contrast with de Broglie's first-order dynamics, for which non-standard momenta are not allowed and which shows an efficient relaxation to the Born rule for positions. On this basis, we argue that, while de Broglie's dynamics is a tenable physical theory, Bohm's dynamics is not. In a world governed by Bohm's dynamics, there would be no reason to expect to see an effective quantum theory today (even approximately), in contradiction with observation.

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