The determination of volatile amines in aquatic marine systems: A review.

This review provides a critical assessment of knowledge regarding the determination of volatile, low molecular weight amines, and particularly methylamines, in marine aquatic; systems. It provides context for the motivation to determine methylamines in the marine aquatic environment and the analytical challenges associated with their measurement.While sensitive analytical methods have been reported in recent decades, they have not been adopted by the oceanographic community to investigate methylamines' biogeochemistry and advance understanding of these analytes to the degree achieved for other marine volatiles. Gas chromatography, high performance liquid chromatography, ion chromatography and infusion-mass spectrometry techniques are discussed and critically determined, alongside offline and online preconcentration steps. Interest in the marine occurrence and cycling of methylamines has increased within the last 10-15 years, due to their potential role in climate regulation. As such, the need for robust, reproducible methods to elucidate biogeochemical cycles for nitrogen and populate marine models is apparent. Recommendations are made as to what equipment would be most suitable for future research in this area.

Antarctic sea ice region as a source of biogenic organic nitrogen in aerosols.

Climate warming affects the development and distribution of sea ice, but at present the evidence of polar ecosystem feedbacks on climate through changes in the atmosphere is sparse. By means of synergistic atmospheric and oceanic measurements in the Southern Ocean near Antarctica, we present evidence that the microbiota of sea ice and sea ice-influenced ocean are a previously unknown significant source of atmospheric organic nitrogen, including low molecular weight alkyl-amines. Given the keystone role of nitrogen compounds in aerosol formation, growth and neutralization, our findings call for greater chemical and source diversity in the modelling efforts linking the marine ecosystem to aerosol-mediated climate effects in the Southern Ocean.