Author Correction: Impact of pore anisotropy on the thermal conductivity of porous Si nanowires.

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Impact of pore anisotropy on the thermal conductivity of porous Si nanowires.

Porous materials display enhanced scattering mechanisms that greatly influence their transport properties. Metal-assisted chemical etching (MACE) enables fabrication of porous silicon nanowires starting from a doped Si wafer by using a metal template that catalyzes the etching process. Here, we report on the low thermal conductivity (κ) of individual porous Si nanowires (NWs) prepared from MACE, with values as low as 0.87 W·m-1·K-1 for 90 nm diameter wires with 35-40% porosity. Despite the strong suppression of long mean free path phonons in porous materials, we find a linear correlation of κ with the NW diameter. We ascribe this dependence to the anisotropic porous structure that arises during chemical etching and modifies the phonon percolation pathway in the center and outer regions of the nanowire. The inner microstructure of the NWs is visualized by means of electron tomography. In addition, we have used molecular dynamics simulations to provide guidance for how a porosity gradient influences phonon transport along the axis of the NW. Our findings are important towards the rational design of porous materials with tailored thermal and electronic properties for improved thermoelectric devices.

Influence of block copolymer feature size on reactive ion etching pattern transfer into silicon.

A successful realisation of sub-20 nm features on silicon (Si) is becoming the focus of many technological studies, strongly influencing the future performance of modern integrated circuits. Although reactive ion etching (RIE), at both micrometric and nanometric scale has already been the target of many studies, a better understanding of the different mechanisms involved at sub-20 nm size etching is still required. In this work, we investigated the influence of the feature size on the etch rate of Si, performed by a cryogenic RIE process through cylinder-forming polystyrene-block-polymethylmethacrylate (PS-b-PMMA) diblock copolymer (DBC) masks with diameter ranging between 19-13 nm. A sensible decrease of the etch depth and etch rate was observed in the mask with the smallest feature size. For all the DBCs under investigation, we determined the process window useful for the correct transfer of the nanometric cylindrical pattern into a Si substrate. A structural and physicochemical investigation of the resulting nanostructured Si is reported in order to delineate the influence of various RIE pattern effects. Feature-size-dependent etch, or RIE-lag, is proved to significantly affect the obtained results.

Enhanced fluorescence detection of miRNA-16 on a photonic crystal.

We report a novel sensing method for fluorescence-labelled microRNAs (miRNAs) spotted on an all-dielectric photonic structure. Such a photonic structure provides an enhanced excitation and a directional beaming of the emitted fluorescence, resulting in a significant improvement of the overall signal collected. As a result, the Limit of Detection (LoD) is demonstrated to decrease by a factor of about 50. A compact read-out system allows a wide-field imaging-based detection, with little or no optical alignment issues, which makes this approach particularly interesting for further development for example in microarray-type bioassays.

In-plane 2D focusing of surface waves by ultrathin refractive structures.

In an attempt to provide a fully dielectric platform for two-dimensional optical circuitry, we report on the focusing features of an ultrathin polymeric lens fabricated on a planar multilayer. The radiation coupled to surface modes sustained by the multilayer can be focused or waveguide-injected into linear ridges by exploiting a dielectric-loading mechanism successfully exploited for plasmons. The low losses of this photonic system also allow long propagation lengths in the visible spectral range. Experimental observations made by fluorescence imaging of the multilayer surface are well supported by computational data obtained through an effective index approach.

Size scaling of mesoporous silica membranes produced by nanosphere mediated laser ablation.

Monodisperse silica nanospheres with sizes ranging from 250 to 725 nm were prepared and assembled into monolayers to produce regularly distributed light hot spots at the surface of oxidized silicon substrates when illuminated by a laser. Single UV nanosecond laser pulses were employed with energies above the local ablation threshold for the silicon dioxide layer, resulting in the direct formation of 2D periodically porous membranes on top of the silicon. The periodicity of the array was driven by the size of the self-assembled nanospheres. While the local field enhancement was strongly dependent on the sphere size due to Mie resonances, the size and morphology of the produced features could be maintained for all tested situations by balancing the change in local fields with the laser pulse energy. This work demonstrates the fabrication of 90 nm thick porous membranes with pore size of about 100 nm and periodicity ranging from 250 to 725 nm.