Taguchi optimization of 3D printed short carbon fiber polyetherketoneketone (CFR PEKK).

In this study, the Taguchi method was utilized to optimize fused filament fabrication (FFF) additive manufacturing with the goal of maximizing the flexural strength of 3D printed polyaryletherketone specimens. We analyzed 3D printed (3DP) carbon fiber reinforced poly-etherketoneketone (CFR PEKK), 3D printed and pressed (3DP + P) CFR PEKK, and injection molded medical grade polyetheretherketone (PEEK) as a control. Fracture surfaces were analyzed via scanning electron microscopy (SEM). The parameters that were varied in the optimization included nozzle diameter, layer height, print speed, raster angle, and nozzle temperature. We analyzed the flexural strength and flexural modulus determined from 3-point bending (ASTM D790). Using Taguchi optimization, the signal to noise ratio (SNR) was calculated to determine the relationship between the input parameters and flexural strength and to determine optimal print settings. Results were confirmed with analysis of variance (ANOVA). The raster angle and layer height were determined to have the greatest impact on the flexural strength of specimens printed in the FFF process for 3DP CFR PEKK. The optimized printing parameters were found to be 0/90 Raster Angle, 0.25 mm layer height, 0.8 mm Nozzle Diameter, 375 °C nozzle temperature, and 1100 mm/min print speed. The optimized 3DP CFR PEKK test samples had a flexural strength of 111.3 ± 5.3 MPa and a flexural modulus of 3.5 GPa. 3DP + P CFR PEKK samples had a flexural strength of 257.2 ± 17.8 MPa and a flexural modulus of 8.2 GPa. Statistical comparisons between means demonstrated that pressing significantly improves both flexural strength and flexural modulus of 3DP CFR PEKK. The results of this study support the hypothesis that post consolidation of 3DP specimens improves mechanical properties. Post-processing composites via pressing may allow greater design freedom within the 3DP process while improving mechanical properties.

Development of an architecture-property model for triply periodic minimal surface structures and validation using material extrusion additive manufacturing with polyetheretherketone (PEEK).

Additively manufactured structures designed from triply periodic minimal surfaces (TPMSs) have been receiving attention for their potential uses in the medical, aerospace, and automobile industries. Understanding how these complex geometries can be designed to achieve particular architectural and mechanical properties is essential for tuning their function to certain applications. In this study, we created design tools for visualizing the interplay between TPMS design parameters and resulting architecture and aimed to validate a model of the relationship between structure architecture and Young's modulus. A custom MATLAB script was written to analyze structural properties for families of Schoen gyroid and Schwarz diamond structures, and a numerical homogenization scheme was performed to predict the effective Young's moduli of the structures based on their architecture. Our modeling methods were validated experimentally with polyetheretherketone (PEEK) structures created using material extrusion additive manufacturing. The architectural characteristics of the structures were determined using micro-computed tomography, and compression testing was performed to determine yield strength and Young's modulus. Two different initial build orientations were tested to determine the behavior both perpendicular and parallel to the layer deposition direction (referred to as z-direction and xy-direction, respectively). The z-direction Young's modulus ranged from 289.7 to 557.5 MPa and yield strength ranged from 10.12 to 20.3 MPa. For the xy-direction, Young's modulus ranged from 133.8 to 416.4 MPa and yield strength ranged from 3.8 to 12.2 MPa. For each initial build orientation, the mechanical properties were found to decrease with increasing porosity, and failure occurred due to both strut bending and interlayer debonding. The mechanical properties predicted by the modeling agreed with the values found for z-direction samples (difference 2-11%) but less so for xy-direction samples (difference 27-62%) due to weak interlayer bonding and print path irregularities. Ultimately, the findings presented here provide better understanding of the range of properties achievable for additive manufacturing of PEEK and encouraging results for a TPMS architecture-property model.