Selectivity adsorption of sulfate by amino-modified activated carbon during capacitive deionization.

ABSTRACTCapacitive deionization (CDI) is an environmentally friendly desalination technique with low energy consumption. However, unmodified carbon electrode materials have poor sulfate selectivity and adsorption capacity. In this work, to improve sulfate selectivity, we prepared activated carbon materials loaded with different amino contents by grafting amino groups via acid treatment for different times. In the competitive ion adsorption experiments, the sulfate selectivity of AC was only 0.64 and the amino-modified AC increased by 1.98-2.52 times due to the formation of stronger hydrogen bonds between the amino group and sulfate. AC-NH2-4 had the best selectivity and the sulfate selective coefficient was 2.25. The desorption of sulfate was 92.46% within one hour. In addition, the surface of the amino-modified activated carbon showed significantly improved electrochemical properties and better capacitance. The specific capacitance of amino-modified AC in different electrolyte solutions was consistent with the competitive adsorption results. The specific capacitance of amino-modified AC in Na2SO4 electrolyte solution was the highest. The modified electrode material also had the advantages of a higher adsorption capacity and excellent regeneration performance after continuous electric adsorption-desorption cycles. Therefore, it may have development potential to selectively adsorb sulfate in practical applications.

Regulation, quantification and application of the effect of functional groups on anion selectivity in capacitive deionization.

Capacitive deionization (CDI) has been widely studied as a highly efficient method for the removal of charged pollutants in sewage. However, the control of ion selectivity has always been challenging, limiting the application of this approach. In this article, the regulation of different acid/base functional group distributions on the selectivity of four anions are comprehensively discussed. The effects are quantified through simulations and statistical analysis. Finally, optimized CDI is used for the simultaneous denitrification and dephosphorization of municipal wastewater. The results show that carboxyl groups significantly promote the selectivity of dihydrogen phosphate and that amino groups promote the selectivity of sulfate and dihydrogen phosphate. Density functional theory is used to calculate the influence of the functional groups on the anion adsorption energy. Compared with other anions, the energy released is improved when carboxyl groups are included in the adsorption of dihydrogen phosphate. The increase in the released energy is highest when amino groups participate in the adsorption of sulfate and is second-highest when they participate in the adsorption of dihydrogen phosphate. Statistical analysis shows that the valence and hydration energy of the anion and the effect of the functional groups on anion adsorption are significantly related to anion adsorption (P < 0.05), and the correlation coefficient of the model is 0.7253. A CDI stack for the removal of phosphorus and nitrogen under high background ion concentrations is constructed and applied, and it is shown that the treated wastewater meets higher discharge standards. Moreover, the method reaches nearly 80% water production under optimized operating modes. This study reveals the importance of functional groups in ion-selective regulation and provides a potential method for high-standard wastewater treatment.

Metformin Inhibits Lipid Droplets Fusion and Growth via Reduction in Cidec and Its Regulatory Factors in Rat Adipose-Derived Stem Cells.

Metformin is still being investigated due to its potential use as a therapeutic agent for managing overweight or obesity. However, the underlying mechanisms are not fully understood. Inhibiting the adipogenesis of adipocyte precursors may be a new therapeutic opportunity for obesity treatments. It is still not fully elucidated whether adipogenesis is also involved in the weight loss mechanisms by metformin. We therefore used adipose-derived stem cells (ADSCs) from inguinal and epididymal fat pads to investigate the effects and mechanisms of metformin on adipogenesis in vitro. Our results demonstrate the similar effect of metformin inhibition on lipid accumulation, lipid droplets fusion, and growth in adipose-derived stem cells from epididymal fat pads (Epi-ADSCs) and adipose-derived stem cells from inguinal fat pads (Ing-ADSCs) cultures. We identified that cell death-inducing DFFA-like effector c (Cidec), Perilipin1, and ras-related protein 8a (Rab8a) expression increased ADSCs differentiation. In addition, we found that metformin inhibits lipid droplets fusion and growth by decreasing the expression of Cidec, Perilipin1, and Rab8a. Activation of AMPK pathway signaling in part involves metformin inhibition on Cidec, Perilipin1, and Rab8a expression. Collectively, our study reveals that metformin inhibits lipid storage, fusion, and growth of lipid droplets via reduction in Cidec and its regulatory factors in ADSCs cultures. Our study supports the development of clinical trials on metformin-based therapy for patients with overweight and obesity.

Selective adsorption of phosphate by carboxyl-modified activated carbon electrodes for capacitive deionization.

Capacitive deionization (CDI) has been considered as a promising technology for removing phosphate from water but suffer inferior selectivity and electrosorption performances for phosphate of current carbon electrodes in CDI. Herein, we achieved highly selective phosphate removal from a ternary effluent of Cl-, PO43-, and SO42- by using nitric acid-treated activated carbon (AC) with various modification times and pure AC as the anode and cathode, a novel phosphate selective asymmetric CDI reactor. The results showed that carboxyl groups greatly grafted on the materials after modification (varying from 0.00084 to 0.0012 mol g-1). The phosphate selectivity of the present research was higher than that of unmodified CDI, and it increased with the increase of carboxyl groups content. The highest phosphate selectivity (2.01) in modified materials is almost six times higher than that of pure AC. Moreover, the modified electrodes exhibited good regenerative ability with a phosphate desorption efficiency of around 72.12% during the adsorption/desorption process and great stability during the cycling experiment. These results demonstrated that the innovative application of nitric acid-modified AC can effectively selectively remove phosphate from mixed anion solution, opening a hopeful window to selective adsorption in water treatment by CDI.

Quantitative analysis of soil sustainability after applying stabilizing amendments in long-term Cd-contaminated paddy soils.

Considering the biomagnification in food chains, cadmium (Cd) contamination in paddy fields has become concerning. The remediation of soil cadmium by the addition of amendments is a common agricultural practice. However, it remains ambiguous whether amendment use decreases soil environmental quality (SEQ) and sustainability. In this study, five compound amendments with different pH were utilized in long-term Cd-contaminated paddy soils. The SEQ of all treatments was quantitatively assessed according to a comprehensive evaluation mathematical model (Criteria Importance Through Inter-criteria Correlation (CRITIC)-Technique for Order Preference by Similarity to Ideal Solution (TOPSIS)), and the indicators involved in microbial functional gene (MFG) abundance, soil physicochemical and microbiological properties (CMP) and soil microbial function (N-related enzyme and transformation rate, N-ET) were measured. The results show that the SQE and remediation effect (expressed by the decrease in available Cd (ACd), %) in our treatments were alkaline > natural > acidic except for D alkaline treatment. The significant contradiction between soil SQE and remediation effect in D treatment attribute to its dose effects, which inhibiting microbial nitrogen assimilation and dissimilation and therefore counteracts the promoting effect of the decrease in ACd. Based on this discussion, three alkaline amendments (A, B and D) with similar effective remediation effect were employed in four other Cd-contaminated soils. Results indicated that both negative effect (D treatment) and promoting effect (A and B treatment) existed in the next 3 years.