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1.
Sci Rep ; 14(1): 13228, 2024 Jun 09.
Artigo em Inglês | MEDLINE | ID: mdl-38853164

RESUMO

Petroleum fuels are commonly used for automobiles. However, the continuous depletion and exhaust gas emission causes serious problems. So, there is a need for an alternative eco-friendly fuel. Biodiesel is a type of fuel manufactured through a process called transesterification, which involves converting vegetable oils into a usable form. The process parameters of the transesterification process were optimized using the Taguchi method to achieve maximum biodiesel yield. However, the main problem of biodiesel is its high cost which could be reduced by using low-cost feedstock. To address this challenge, biodiesel (BCFAD) is derived from coconut fatty acid distillate (CFAD), a by-product obtained from refining coconut oil. This work uses BCFAD and BCFAD with Alumina nanoparticles as fuels. Alumina nanoparticles in the mass fraction of 25 ppm, 50 ppm, and 100 ppm are dispersed in BCFAD. The investigation results reveal an increase of 6.5% in brake thermal efficiency for BCFAD with 100 ppm nanoparticles when compared to BCFAD. There is a reduction of 29.29% of hydrocarbon and 34% of Carbon monoxide emissions with BCFAD100 in comparison with diesel. However, there is a marginal increase in NOx emission with the increase in nanoparticles. The heat release rate and cylinder pressure of BCFAD100 are comparable to diesel fuel. It was concluded that the utilization of BCFAD with a nanoparticle dispersion of 100 ppm is suitable for direct use as fuel in diesel engines.

2.
Sci Rep ; 14(1): 5726, 2024 Mar 08.
Artigo em Inglês | MEDLINE | ID: mdl-38459099

RESUMO

The spray characteristics of a fuel greatly influence the combustion as it affects the formation of an air-fuel mixture, which directly impacts the performance and emissions of the engine. This study investigates the physical injection spray characteristics of biofuels to optimize the engine operating parameters for their effective utilization. For the analysis of the spray characteristics of pure diesel (D100), 80% diesel-20% biodiesel (D80B20), 80% diesel-10% biodiesel-10% pure ethanol (D80B10E10), and 80% diesel-10% biodiesel-10% hydrous ethanol (D80B10HE10) are investigated. Computational Fluid Dynamics (CFD) modeling of a constant volume chamber under non-evaporative conditions is performed to conduct numerical analysis. The chamber pressure of 2 and 2.5 MPa and nozzle injection diameter of 0.126 mm, 0.15 mm, and 0.2 mm are considered to conduct the simulations. The variation in spray penetration length is analyzed and discussed for the injection of different fuel blends at different initial conditions. It is observed from numerical results that the high-density fuel blend D80B20 has a penetration length of 10.695% and 15.805% higher than pure diesel and D80B10HE10 blends, respectively. For pure diesel, with an increase in nozzle diameter from 0.126 mm to 0.15 mm and 0.2 mm, the penetration length is increased by 20% and 32%, respectively, and with an increase in pressure from 2 MPa to 2.5 MPa, penetration length is decreased by 14.62%. From this study, it can be concluded that biofuels like biodiesel and hydrous ethanol can be used with diesel in blended form over pure ethanol. Compared to pure ethanol, hydrous ethanol gives cost benefits and better spray characteristics.

3.
Environ Sci Pollut Res Int ; 31(18): 26497-26509, 2024 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-38446296

RESUMO

The increase in plastic products and disposal poses a severe environmental challenge because of their poor biodegradability and undesirable disposal by landfilling. Recycling is the best possible solution to the environmental challenges implemented by the plastic industry. Pyrolysis is a process that converts waste plastics into pyrolytic oil, and it can be used as fuel in a blended form. The viscosity and lubricity of the LDWP (low-density waste polyethylene) pyrolytic oil were lower than standard diesel. Capparis spinosa methyl ester (CME) is blended and experimented with to overcome the lubricity issue of pyrolytic oil. In this investigation, 5%, 10%, and 15% CME were blended with PD20 (20% LDWP oil + 80% diesel) blend on a volume basis. Experiments were conducted to examine the effects of CME on combustion, performance, and emissions using the combination of CME and PD20 blend tested at 0%, 25%, 50%, 75%, and 100% loading conditions. All three ternary mixtures showed enhanced combustion performance and increased NOx and smoke emissions. Due to better combustion, the efficiency of the blend PCD10 (10% CME + 20% LDWP oil + 70% diesel) was higher than the PD20 blend and significantly closer to diesel. Hence, PCD10 is suggested as an alternative to diesel fuel.


Assuntos
Plásticos , Pirólise , Reciclagem
4.
Biotechnol Bioeng ; 121(3): 894-902, 2024 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-38164703

RESUMO

Biodiesel has the potential to serve as a feasible substitute for fossil fuels in many sectors, including transportation and internal combustion engines, without requiring extensive modifications. UsinHemg alternative energy sources, including biodiesel, is necessary to effectively tackle the growing demand predominantly observed in the transportation sector. This review is aimed to examine the technological progress, potential benefits, obstacles, and prospects associated with using biodiesel in India. India exhibits a significant potential for biodiesel production due to the abundance of various biofuel crops within its territory. The information supplied includes recent information from official government reports and literature. Collaborative efforts among all stakeholders in the energy industry can achieve the realization of reducing imports of petroleum-based fuel. However, it is essential to consider several significant elements specific to the Indian context when considering the utilization of biodiesel. The reported findings in this research are expected to shed light on the current and prospects of biodiesel deployment in India.


Assuntos
Biocombustíveis , Gasolina , Produtos Agrícolas , Índia
5.
Sci Rep ; 13(1): 18907, 2023 Nov 02.
Artigo em Inglês | MEDLINE | ID: mdl-37919426

RESUMO

Numerous countries are investigating alternative fuel sources in response to the escalating issue of energy inadequacy. Using environmentally sustainable biodiesel as a potential alternative to fossil fuels, particularly from waste sources, is a developing prospect. This study aims to examine the feasibility of utilizing industry leather waste as a diesel fuel substitute. Traditional transesterification was used to obtain methyl ester out of leather waste. After processing, 81.93% of methyl ester was produced. Bio-silica (Bio-Si) is used as a fuel additive to enhance combustion and decrease emissions. This work utilized a leather industry waste fat biodiesel (LIWFB), LIWFB blend (B50), LIWFB blend with Bio-Si nanoparticles (B50Bio-Si50, B50Bio-Si75, and B50Bio-Si100 ppm) to analyze the engine outcome parameters at standard operating conditions. Experimental results revealed that adding Bio-Si in the biodiesel blend increased thermal brake efficiency (BTE) but was lower in diesel fuel. The biodiesel blends reduced NOx emissions more than Bio-Si nanoparticle blends. Furthermore, the smoke opacity was reduced by 31.87%, hydrocarbon (HC) emissions were reduced by 34.14%, carbon monoxide (CO) emissions were decreased by 43.97%, and oxides of nitrogen (NOx) emissions were slightly increased by 4.45% for B50Bio-Si100 blend compared to neat diesel. This investigation determined that all the emissions remained lower for all combinations than neat diesel, with a small increase in NOx emissions. Therefore, the LIWFB blend with Bio-Si nanoparticles was a viable diesel fuel alternative in diesel engines.

6.
Sci Rep ; 13(1): 18362, 2023 Oct 26.
Artigo em Inglês | MEDLINE | ID: mdl-37884612

RESUMO

The objective of the present investigation is to enhance the performance of diesel engine using Capparis spinoza fatty acid distillate biodiesel (CFAB100) at various compression ratios. The experiments were carried out at compression ratios of 16.5:1, 17.5:1, 18.5:1, and 19.5:1. It was noted that an increase in compression ratio from 16.5 to 18.5 resulted in better engine characteristics for CFAB100 and reduced at compression ratio 19.5. Brake-specific fuel consumption of CFAB100 decreased from 0.42 to 0.33 kg/kWh with an increase in compression ratio. The brake thermal efficiency of CFAB100 at a compression ratio of 16.5 is 29.64% lower than diesel, whereas it is 11.32% low at a compression ratio of 18.5. The brake thermal efficiency of CFAB100 is 26.03% higher at a compression ratio of 18.5 compared to 16.5. Due to shorter ignition delay and reduced premixed combustion, the net heat release rate of CFAB100 is lower than diesel at all compression ratios. The peak cylinder pressure for diesel is 56.21 bar, and CFAB100 at compression ratios 16.5, 17.5, 18.5, and 19.5 were 52.36, 55.12, 61.02 and 58.25 bar at full load condition. CFAB100, at a compression ratio of 18.5, had the highest nitrogen oxide emissions (2400 ppm). Carbon monoxide, unburnt hydrocarbon, and smoke showed an average reduction of 46.58%, 40.68%, and 54.89%, respectively, when the compression ratio varied between 16.5 and 19.5. At an optimum compression ratio of 18.5, the CFAB100 resulted in improved performance and emission characteristics that can replace diesel to a possible extent.

7.
Sci Rep ; 13(1): 16718, 2023 10 04.
Artigo em Inglês | MEDLINE | ID: mdl-37794098

RESUMO

In typical manual material handling, the variations in walking pattern are decided by various factors, such as load being handled, frequency of handling, walking surface, etc. Traditional gait analysis protocols commonly evaluate individual factor within specified ranges associated with particular activities or pathologies. However, existing literature underscores the concurrent impact of multiple factors on gait. This study identifies five pivotal factors-walking speed, surface slope, load carried, carrying method, and footwear-as contributors to gait alterations. To address risk factors in manual material handling activities, we propose a unique design-of-experiment-based approach for multi-task gait analysis. Unraveling the relationship between manual handling attributes and human gait holds paramount importance in formulating effective intervention strategies. We optimized the five input factors across a cohort of 15 healthy male participants by employing a face-centered central composite design experimentation. A total of 29 input factor combinations were tested, yielding a comprehensive dataset encompassing 18 kinematic gait parameters (such as cadence, step length etc., measured using inertial measurement system), the isolated impacts of factors, and the interplay of two-factor interactions with corresponding responses. The results illuminate the optimal scenarios of input factors that enhance individual gait performance-these include wearing appropriate footwear, employing a backpack for load carriage, and maintaining a moderate walking pace on a medium slope with minimal load. The study identifies walking speed and load magnitude as primary influencers of gait mechanics, followed by the chosen carrying method. In consequence, the insights gained advocate for the refinement of manual material handling tasks based on the outcomes, effectively mitigating the risk of musculoskeletal disorders by suggesting the interventions for posture correction.


Assuntos
Marcha , Caminhada , Humanos , Masculino , Suporte de Carga/fisiologia , Marcha/fisiologia , Caminhada/fisiologia , Velocidade de Caminhada/fisiologia , Análise da Marcha , Fenômenos Biomecânicos
8.
Sci Rep ; 13(1): 17392, 2023 Oct 13.
Artigo em Inglês | MEDLINE | ID: mdl-37833446

RESUMO

Beam-column joints are crucial load transmission zones because they face concentrated forces from both the beams and the columns. High shear and axial stresses caused by these concentrated forces in the area of the joint may result in decreased joint strength. This article proposes a new beam-to-column connection developed for precast concrete-resisting frames. Concrete mixtures are enhanced mechanically by adding nano silica as it increases compressive strength, flexural strength, and abrasion resistance. Within the concrete, it creates a solid, gel-like matrix that fills voids and strengthens the whole construction. In this study, three reinforced concrete beam-column joint specimens were cast with fly ash, the other three with nano-silica and fly ash, and one sample with nano-silica and a control mix without admixtures was cast. Specimen cast using fly ash and nano-silica is subjected to cyclic loading after 28 days of curing. A load capacity of 100 kN was imposed on the column during testing. It was observed that a gradual increase in fly ash decreased the compressive and flexural strength of the beam-column joints. This decrease in strength was addressed by adding 2.5% nano-silica. Nano silica acts as a nucleus to bond tightly with cement particles during hydration. The results showed that the flexural strength equivalent to that of a controlled specimen can be achieved by adding nano-silica at 2.5% and fly ash at 60%. The highest loading of 38.1 kN can be applied to the specimen with nano-silica without fly ash. Although a higher axial compression ratio can improve the bearing capacity and initial stiffness, it can also reduce deformation capacity and flexibility.

9.
Sci Rep ; 13(1): 15301, 2023 09 15.
Artigo em Inglês | MEDLINE | ID: mdl-37714888

RESUMO

Bioactive substances such as phenolic compounds, antioxidants, and antibacterial agents are found in natural fibres. In this study, banana fibre was extracted from the trunks of banana plants. Antibacterial activity, FTIR, XRD, and SEM analysis were performed to characterize the banana cellulose fibre, and also raw and alkali-treated banana fibre composite was fabricated with an epoxy matrix. Results of the antibacterial analysis indicate that this banana cellulose fibre strongly impedes bacterial growth with elevated inhibitory zones. The primary peaks observed at 1170 cm-1 and 1426 cm-1 by FTIR analysis correspond to C-O stretching, O-H bending, aliphatic ether, secondary alcohol, and carboxylic acid. The morphological analysis reveals the fibre quality, and the EDX analysis confirms the elements present in the banana cellulose fibre. The XRD results demonstrated a more significant proportion (76.8%) of the amorphous region. This study indicates that banana cellulose fibre could be a promising source of antimicrobial compounds. In addition, the mechanical properties of alkali-treated banana fibre composite were preferable to raw fibre composite by an average of 3% for this banana fibre composite. As a result, this composite can be used to manufacture automobile interior components, as it can reduce the sanitizing periods of interior components during winter months.


Assuntos
Anti-Infecciosos , Musa , Celulose , Árvores , Anti-Infecciosos/farmacologia , Antibacterianos/farmacologia , Álcalis
10.
Sci Rep ; 13(1): 16291, 2023 Sep 28.
Artigo em Inglês | MEDLINE | ID: mdl-37770492

RESUMO

In recent trends, the usage of synthetic materials has been reduced by introducing natural fibres for lightweight applications. In this study, Madar (Calotropis gigantea) fibre is selected for the reinforcement phase (40%), and the epoxy polymer is blended with bran filler selected as a matrix material. To calculate hybrid composite mechanical characteristics, five composite laminates with different fibre/filler weight ratios were made. The results show that when the weight ratio of madar fibre increased, the superior mechanical properties were observed in the composite laminate sample (A), such as tensile strength (20.85 MPa), flexural strength (24.14 MPa), impact energy absorption (23 J) compared with an increasing the weight ratio of bran nanofiller to this composite material. At the same time, increasing bran nanofillers can improve thermal stability up to 445 °C of degrading temperature. To analyse the surface interaction between the madar fibres, bran nanofillers, and epoxy matrix by conducting the scanning electron microscope (SEM) analysis before subjecting to the mechanical test and also to identify the failure mode by conducting the SEM test after the laminates are broken during the mechanical tests of the hybrid composite.

11.
Sci Rep ; 13(1): 12579, 2023 Aug 03.
Artigo em Inglês | MEDLINE | ID: mdl-37537228

RESUMO

Natural fibre is renewable and extensively utilized for structural and medicinal applications. The current research concentrates on surface modification for fibre enhancement using an alkaline treatment technique to extract raw fibre from banyan (Ficus benghalensis) aerial root bark. Using a 10% NaOH solution, attempts have been made to improve the crystalline, surface, thermal, physical, and chemical properties of banyan aerial root fibre (BAF). Five samples of BAF were produced by soaking the unprocessed fibre in an alkaline solution for variable amounts of time. On the surface of the treated BAF, a higher concentration of cellulose could be seen. The X-Ray Diffraction test revealed that the crystallinity index improved by 52%, with a crystalline dimension of 51.2 nm. It was observed that the crystalline content is increased in treated Banyan aerial root fiber due to this alkali treatment. The significance of natural fibre characterization is also briefly discussed, and this summary will serve as a resource for future studies on natural fibre composites by other researchers.

12.
Biotechnol Bioeng ; 120(11): 3137-3147, 2023 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-37605619

RESUMO

Biodiesel outperforms diesel in emissions and engine performance. They burn efficiently in diesel engines and are eco-friendly. Since cashew nut shell liquid (CNSO) is waste, commercial biodiesel production from it should be profitable. CNSO is cheap and can reduce cashew processing factory waste. From cashew kernels, CNSL is extracted using various mechanical, thermal, and solvent extraction techniques. This article examines current research into using cashew nutshell liquid biodiesel (CNSLBD) in diesel engines. The work also discusses Indian biodiesel demand, availability, export information, life cycle cost analysis, cost economics of per hectare yield, Indian government initiative of CNSO. This review also evaluates the viability of this fuel as an alternative energy source. CNSLBD is a prospective alternative fuel that has the potential to benefit both the cashew nut industry and the energy industry. In addition to this, the study examines the procedures for extracting CNSO. According to the findings of the study, CNSO is a prospective alternative fuel that has the potential to benefit both the cashew nut industry and the energy industry.

13.
Environ Res ; 234: 116537, 2023 10 01.
Artigo em Inglês | MEDLINE | ID: mdl-37402432

RESUMO

The depletion of fossil fuel and the concerns for harmful emissions and global warming has instigated researchers to use alternative fuels. Hydrogen (H2) and natural gas (NG) are attractive fuels for internal combustion engines. The dual-fuel combustion strategy is promising to reduce emissions with efficient engine operation. The concern for using NG in this strategy is the lower efficiency at low load conditions and the emission of exhaust gases like carbon monoxide and unburnt hydrocarbon. Mixing fuel with a wide flammability limit and a faster burning rate with NG is an effective method to compensate for the limitations of using NG alone. Hydrogen (H2) is the best fuel added with NG to cover NG limitations. This study investigates the in-cylinder combustion phenomenon of reactivity-controlled compression ignition (RCCI) engines using hydrogen-added NG as a low-reactive fuel (H2 addition to NG on a 5% energy basis) and diesel as a highly reactive fuel. The numerical study was done on a 2.44 L heavy-duty engine using CONVERGE CFD code. Three low, mid, and high load conditions were analyzed in six stages by varying the diesel injection timing from -11 to -21 O after top dead centre (ATDC). The H2 addition to NG had shown deficient harmful emissions generation like carbon monoxide (CO) and unburnt hydrocarbon with marginal NOx generation. At low load conditions, the maximum imep was achieved at the advanced injection timing of -21OATDC, but with the increase in load, the optimum timing was retarded. The diesel injection timing varied the optimum performance of the engine for these three load conditions.


Assuntos
Gasolina , Gás Natural , Óxidos de Nitrogênio/análise , Hidrogênio , Monóxido de Carbono/análise , Hidrocarbonetos , Emissões de Veículos , Biocombustíveis
14.
Sci Rep ; 13(1): 8200, 2023 May 21.
Artigo em Inglês | MEDLINE | ID: mdl-37211551

RESUMO

Thermal losses through weak building envelope is responsible for global current energy crises. Application of artificial intelligence and drone setups in green buildings can help in providing the sustainable solution the world is striving for years. The contemporary research incorporates a novel concept of measuring the wearing thermal resistances in the building envelope with the aid of a drone system. The above procedure conducts a throughout building analysis by considering three prime environmental parameters such as wind speed (WS), relative humidity (RH) and dry bulb temperature (DBT) with the aid of drone heat mapping procedure. The novelty of the study can be interpreted by the fact that prior researches have never explored the building envelope through a combination of drone and climatic conditions as variables in building areas difficult to access, thereby providing an easier, risk free, cost effective and efficient reading. Validation of the formula is authenticated by employing artificial intelligence-based software's which are applied for data prediction and optimization. Artificial models are established to validate the variables for each output from the specified number of climatic inputs. The pareto-optimal conditions attained after analysis are 44.90% RH, 12.61 °C DBT and 5.20 km/h WS. The variables and thermal resistance were validated with response surface methodology method, thereby presenting lowest error rate and comprehensive R2 value, which are 0.547 and 0.97, respectively. Henceforth, employing drone-based technology in estimating building envelope discrepancies with the novel formula, yields consistent and effective assessment for development of green building, simultaneously reducing time and cost of the experimentation.

15.
Artigo em Inglês | MEDLINE | ID: mdl-37178285

RESUMO

Electrical and electronic equipment like light bulbs, computing systems, gaming systems, DVD players, and drones experiences heat generation during extensive use. The heat energy should be liberated to ensure uninterrupted performance and prevent premature failure of the devices. This study uses an experimental setup of the heat sink, phase change material, silicon carbide nanoparticles, thermocouple, and data acquisition system to control heat generation and increase heat lost to the surroundings in electronic equipment. The silicon carbide nanoparticles are mixed in varying compositions, i.e., 1wt.%, 2wt.%, and 3wt.%, in paraffin wax as the phase change material. The influence of the heat input (15W, 20W, 35W, and 45W) through the plate heater is also studied. The operating temperature of the heat sink was allowed to fluctuate between 45 and 60 °C while experimenting. The fluctuation in the temperature of the heat sink was recorded to monitor and compare the charging, dwell, and discharging periods in the heat sink. It is observed that increasing the percentage composition of silicon carbide nanoparticles in the paraffin wax resulted in increasing the peak temperature and the dwell period of the heat sink. Increasing the heat input above 15W benefited in controlling the duration of the thermal cycle. It is inferred that high heat input is beneficial in enhancing the heating period, while the percentage composition of silicon carbide in the PCM benefits by increasing the heat sink's peak temperature and dwell period. It is concluded that high heat input, i.e., 45W, is beneficial in enhancing the heating period, while the percentage composition of silicon carbide in the PCM benefits by increasing the heat sink's peak temperature and dwell period.

16.
Waste Manag ; 162: 63-71, 2023 May 01.
Artigo em Inglês | MEDLINE | ID: mdl-36948114

RESUMO

The current study aims to attain a higher yield of biodiesel from Bauhinia tree seed wastes through process optimization using response surface methodology (RSM) and assess its compatibility in the diesel engine blended with water and Di-tert-butyl peroxide (DTBP). The Bauhinia parviflora biodiesel (BPB) transesterification originated using a fixed quantity of catalyst, and the transesterification process parameters such as oil-molar ratio (OMR), process temperature (PT), and reaction time (RT) were optimized. Fourier transform infrared spectroscopy (FTIR) and Gas chromatography-mass spectrometry (GC-MS)analysis were applied to characterize and quantify the BPB, and ASTM standards were followed to measure the properties. The prepared BPB (30%) was blended with 10% water and 2% BTBP to enhance the performance and emission characteristics of the BPB in the diesel engine. The optimization result implies that the higher yield of BPB (91.4%) was attained for OMR of 9.2:1, PT of 76 °C, and RT of 67 min. The FTIR report indicates that the carbon-based components are pretty good in the prepared BPB. The GC-MS report indicates that the fatty acids are converted into corresponding methyl esters, and the measured fuel properties are within the prescribed limits. The diesel engine's performance is effectively improved for the BPB blended with water and DTBP. The proposed fuel's overall improvement in hydrocarbon, carbon monoxide, smoke, and oxides of nitrogen emissions is 27.2%, 34.9%, 16.7%, and 11.2%, respectively.


Assuntos
Bauhinia , Água , Biocombustíveis/análise , Emulsões , Emissões de Veículos/análise , Gasolina/análise
17.
Environ Sci Pollut Res Int ; 30(60): 125066-125076, 2023 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-36826774

RESUMO

Diesel fuel reformulation is an attractive method to reduce hazardous smoke emissions because it does not require modifications to the existing engine infrastructure. As the concerns about global warming and air pollution are mounting, high-efficiency diesel engines with low smoke emissions have become more attractive. This study demonstrates that three alcohols, viz. cyclohexanol, polyethylene glycol, and 2-methoxyethanol, can be added to fossil diesel up to 3% by vol. to reduce carcinogenic smoke emissions in a one-cylinder, common rail direct injection (CRDI) diesel engine. The experimental investigations revealed that smoke could be reduced by up to 66.2%, 39.6% and 14% using 3% by vol. addition of cyclohexanol, polyethylene glycol, and 2-methoxyethanol to diesel, respectively, when compared to pure diesel operation. 1% addition by vol. of cyclohexanol and 2-methoxyethanol could reduce NOx and smoke emissions under all load conditions. CO emissions are slightly higher for all alcohol at high load conditions. HC emissions for the test fuels are lower than pure diesel operation at low load conditions, increasing at high loads. These emissions, however, can be reduced by using suitable after-treatment devices.


Assuntos
Fumaça , Emissões de Veículos , Emissões de Veículos/análise , Polietilenoglicóis , Carcinógenos , Gasolina/análise , Biocombustíveis
18.
Environ Res ; 224: 115432, 2023 05 01.
Artigo em Inglês | MEDLINE | ID: mdl-36791837

RESUMO

Uncontrolled emissions, massive price increases, and other factors encourage searching for a suitable diesel engine fuel alternative. In its processed form, vegetable oil biodiesel is an appealing green alternative fuel for compression ignition engines. Vegetable oil esters have qualities comparable to those of standard diesel fuel. As a result, biodiesel may be utilized to run a diesel engine without any further alterations. This article analyses the potential of Phoenix sylvestris oil, which may be found in forest belts across the globe, as a viable feedstock for biodiesel extraction. Phoenix sylvestris oil is found to be abundant in different forest belts worldwide. The free fatty acid must first be transformed into esters using catalytic acid esterification before proceeding to alkaline catalytic esterification. The molar ratio (6:1), catalyst concentration (1 wt%), reaction temperature (60 °C), and reaction time (2 h) have all been optimized for biodiesel extraction. Biodiesel produced had characteristics that were similar to standard biodiesel specifications. The biodiesel yield from Phoenix sylvestris oil was 92.3% under optimum conditions. The experimental results revealed that the Phoenix sylvestris oil biodiesel performed better than neat Phoenix sylvestris oil and its blends. Phoenix sylvestris oil blend produced better brake thermal efficiency with lower smoke, hydrocarbon, and CO emissions. The biodiesel produced from non-edible Phoenix sylvestris oil has the potential to be employed as a viable alternative to diesel fuel.


Assuntos
Biocombustíveis , Gasolina , Gasolina/análise , Biocombustíveis/análise , Emissões de Veículos/análise , Hidrocarbonetos , Óleos de Plantas , Ésteres
19.
Sci Total Environ ; 825: 153897, 2022 Jun 15.
Artigo em Inglês | MEDLINE | ID: mdl-35182637

RESUMO

Water is one of the important gifts to mankind. In recent days the accessibility of pharmaceuticals in the environment is progressively a worldwide concern. The significant wellspring of these contaminations in water assets is drugs for human use or veterinary medications. Intermediates, active metabolites and raw materials present in water from pharmaceutical industry waste because of incomplete sewage treatment systems. Various pharmaceutical components such as analgesic/antipyretics such as Ibuprofen (57.9-104 ng/L), Diclofenac (17-129 ng/L), antibiotics such as Sulfamethoxazole (28.7-124.5 ng/L), Sulfamethazine (29.2-83.9 ng/L), Azithromycin (10-68 ng/L), psychiatric drug such as Carbamazepine (9.3-92.4 ng/L), stimulants such as caffeine greater than 55 ng/L, antidepressants, antihypertensive, contraceptives etc., are present in water resources and have been detected in mg/L to µg/L range. The synergic effects and ecotoxicological hazard assessment must be developed. Studies demonstrate that these drugs might cause morphological, metabolic and sex alterations on sea-going species, and interruption of biodegradation activities. Hazard analysis and assessments are in progress. However, the conventional effluent treatment methods are not sufficient to remove API (active pharmaceutical ingredients) from this water effectively. There is necessitate for continuous monitoring of the pharmaceutical compounds in aquatic ecosystem to save the environment and living form of lives from health hazards. This work highlights the hazards, environmental assessment and the mitigation measures of pharmaceutical pollutants.


Assuntos
Monitoramento Ambiental , Poluentes Químicos da Água , Ecossistema , Monitoramento Ambiental/métodos , Humanos , Preparações Farmacêuticas , Medição de Risco , Águas Residuárias/química , Água , Poluentes Químicos da Água/análise , Recursos Hídricos
20.
Environ Sci Pollut Res Int ; 29(32): 48411-48423, 2022 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-35190988

RESUMO

The work aims to analyse an ejector refrigeration system powered with solar energy through serially connected collectors to lower greenhouse gases. The collectors chosen for the work are Scheffler and parabolic collectors with an area of 2.5 m2 and 6 m2, respectively. The steam generated by the collectors is stored temporarily in a 15-l storage tank. The thermic fluid transfers heat between the steam storage tank and refrigerant, and thus the generator temperature increases. This design was intended as an alternate for a traditional 3.5 kW room air conditioner with substantially lower energy consumption. This modified system consumed lesser energy input of about 20-30% than conventional air conditioners. Further, for the same specification, the ejector system has consumed less power of about 2.475 kW than the traditional refrigeration system.

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