RESUMO
The goal of the present study is to assess the soil quality in Bulgaria using (i) an appropriate set of soil quality indicators, namely primary nutrients (C, N, P), acidity (pH), physical clay content and potentially toxic elements (PTEs: Cu, Zn, Cd, Pb, Ni, Cr, As, Hg) and (ii) respective data mining and modeling using chemometrical and geostatistical methods. It has been shown that five latent factors are responsible for the explanation of nearly 70% of the total variance of the data set available (principal components analysis) and each factor is identified in terms of its contribution to the formation of the overall soil quality-the mountain soil factor, the geogenic factor, the ore deposit factor, the low nutrition factor, and the mercury-specific factor. The obtained soil quality patterns were additionally confirmed via hierarchical cluster analysis. The spatial distribution of the patterns throughout the whole Bulgarian territory was visualized via the mapping of the factor scores for all identified latent factors. The mapping of identified soil quality patterns was used to outline regions where additional measures for the monitoring of the phytoavailability of PTEs were required. The suggested regions are located near to thermoelectric power plants and mining and metal production facilities and are characterized by intensive agricultural activity.
RESUMO
Establishment of geochemical background and threshold values of potentially toxic elements is essential for soil management activities. Available topsoil data collected in the Bulgarian soil quality monitoring network are explored for the concentrations of the potentially toxic elements (PTEs) of As, Cd, Cr, Cu, Hg, Ni, Pb and Zn. The 'medianâ¯+â¯2MAD' and TIF methods for obtaining geochemical threshold values, which differentiate sampling sites with background from those with unusually high element concentrations, are presented. Comparison of the derived national geochemical threshold values with those obtained in European studies outlines the specificity of the Bulgarian PTE background concentrations among the other southern European countries. The threshold values for Cd, Cu, Ni, Pb and Zn are more similar to those derived from the northern European countries since the As and Cr ones are more close to the values derived for southern Europe. The geochemical threshold of Hg is almost one order of magnitude as high as the southern European derived value. The usage of geochemical threshold values for soil risk assessment is suggested by comparison with soil quality guideline values adopted in other countries. The combination of threshold values based on 90th percentile with geochemical mapping identifies the priority areas for further assessment. Regions with more than 2 PTEs (2.26% of the Bulgarian territory) are suggested for detailed (eco)toxicological assessment.
RESUMO
Soil samples from the vicinity of a non-ferrous metal smelter near Plovdiv, Bulgaria contained very high concentrations of cadmium, lead and zinc (up to 140, 4900 and 5900 mg kg(-1), respectively). A roadside soil in a relatively uncontaminated area also contained high concentrations of the same metals (24, 1550 and 1870 mg kg(-1), respectively) indicating that the transport of ores could be a source of contamination. Even though the lead isotope ratios in all the samples fell within a very narrow range (for example, 1.186-1.195 for (206)Pb/(207)Pb), the samples could be differentiated into three distinct groups: ores ((206)Pb/(207)Pb and (208)Pb/(207)Pb ratios of 1.1874-1.1884 and 2.4755-2.4807, respectively), current deposition (1.1864 and 2.4704-2.4711, respectively) and local background (1.1927-1.1951 and 2.4772-2.4809, respectively). Although most of the current deposition has its origin in the ores used at the smelter, up to 12% could be from other sources such as petrol lead.
