Nanoporous Amorphous Carbon Monolayer Derived from Fullerene Film.

Carbon materials derived from fullerene are reported recently with unique structures and properties. However, only micrometer size samples can be obtained that limits the studying and exploration for membrane applications. Here, the preparation of a centimeter-size nanoporous amorphous carbon monolayer is reported by rapid pyrolyzing a Langmuir-Blodgett film of fullerene. The sample is fully characterized and the results indicate that the amorphous carbon monolayer derived from fullerene is metastable and insulating. The ionic transmembrane transport study demonstrates that the membrane is porous and cation selective with a selectivity of 26%. This work provides new insights into the controlled synthesis of large-size metastable amorphous carbon monolayer.

Interface Engineering of CoFe-LDH Modified Ti: α-Fe2O3 Photoanode for Enhanced Photoelectrochemical Water Oxidation.

Effectively regulating and promoting the charge separation and transfer of photoanodes is a key and challenging aspect of photoelectrochemical (PEC) water oxidation. Herein, a Ti-doped hematite photoanode with a CoFe-LDH cocatalyst loaded on the surface was prepared through a series of processes, including hydrothermal treatment, annealing and electrodeposition. The prepared CoFe-LDH/Ti:α-Fe2O3 photoanode exhibited an outstanding photocurrent density of 3.06 mA/cm2 at 1.23 VRHE, which is five times higher than that of α-Fe2O3 alone. CoFe-LDH modification and Ti doping on hematite can boost the surface charge transfer efficiency, which is mainly attributed to the interface interaction between CoFe-LDH and Ti:α-Fe2O3. Furthermore, we investigated the role of Ti doping in enhancing the PEC performance of CoFe-LDH/Ti:α-Fe2O3. A series of characterizations and theoretical calculations revealed that, in addition to improving the electronic conductivity of the bulk material, Ti doping also further enhances the interface coupling of CoFe-LDH/α-Fe2O3 and finely regulates the interfacial electronic structure. These changes promote the rapid extraction of holes from hematite and facilitate charge separation and transfer. The informative findings presented in this work provide valuable insights for the design and construction of hematite photoanodes, offering guidance for achieving excellent performance in photoelectrochemical (PEC) water oxidation.