RESUMO
When landfill leachate, with or without biological pretreatment, is discharged to publically owned treatment works (POTWs), it can interfere with the installed treatment facilities. Biological treatment is ineffective for the removal of some of the bio-refractory organic matter, including UV254 quenching substances. Fenton's reagent treatment for biologically treated landfill leachates is examined in this study as a polishing step to make landfill leachates acceptable to POTWs. The optimum conditions for the Fenton's reagent treatment are explored. The molecular weight and hydrophobic-hydrophilic nature based fractions of the Fenton's treated leachate samples are analyzed to provide insight into the leachate fractions targeted by the Fenton's reagent. The results indicate that Fenton's reagent can act as a good compliment to biological treatment as it can remove leachate fractions which are widely considered to be bio-refractory. It exhibited good UV254 absorbance removal by removing larger molecular weight humic substances and thus, can help solve the UV254 quenching problem due to leachates discharged to POTWs.
Assuntos
Peróxido de Hidrogênio/química , Ferro/química , Eliminação de Resíduos Líquidos/métodos , Poluentes Químicos da Água/química , Benzopiranos/análise , Reatores Biológicos , Carbono/análise , Substâncias Húmicas/análise , Concentração de Íons de Hidrogênio , Raios Ultravioleta , Instalações de Eliminação de ResíduosRESUMO
To explore the feasible treatment alternatives for organic contaminant, especially organic arsenic species in the landfill gas (LFG) condensate, a variety of treatment approaches were examined and evaluated in this study. Biological degradation, conventional and advanced oxidation, and physical absorption showed limited effectiveness to convert the methylated arsenic to inorganic arsenic. Reverse osmosis (RO) was found to be able to remove the organic arsenic and meet the discharge limits. Maximum removal efficiency and cost level were summarized for all treatment approaches tested, which can be a reference for the organic arsenic treatment method selection under different circumstances.
