High-power 2.3†µm Tm:YLF laser with intracavity upconversion pumping by a Nd:ASL laser at 1051†nm.

A Tm:LiYF4 laser operating on the 3H4 → 3H5 transition is embedded in a high-power diode-pumped Nd:ASL laser for intracavity upconversion pumping at 1.05 µm. This leads to a record-high output power at 2.3 µm for any bulk thulium laser pumped by an upconversion process. The continuous-wave Tm:LiYF4 laser delivers 1.81 W at 2.3 µm for 32 W of laser-diode pump power, making this kind of pumping competitive with direct diode pumping. The intracavity pumping process allows for counteracting the low absorption inherent to upconversion pumping and to dispatch the thermal loads on two separate laser crystals. The proposed laser architecture also features a relatively weak heating of the Tm:LiYF4 crystal and an increased tolerance to Tm3+ absorption. This laser design opens a new paradigm that holds great promise for high-power 2.3-µm solid-state lasers based on thulium ions.

Chirped pulse upconversion for femtosecond mid-infrared spectroscopy at 100 kHz.

We demonstrate that chirped pulse up-conversion (CPU), a method routinely used with systems based on 1-kHz Titanium:Sapphire lasers, can be extended to a repetition rate of 100 kHz with an Ytterbium diode-pumped femtosecond amplifier. Individual mid-infrared spectra can thus be measured directly in the near infrared using a fast CMOS linescan camera. After an appropriate Fourier processing, a spectral resolution of 1.1 cm-1 is reported, currently limited by our spectrometer. Additionally, we demonstrate the application of CPU to a pump-probe measurement of the vibrational relaxation in carboxy-hemoglobin, and we show that the combination of fast scanning and fast acquisition enables a straightforward removal of pump scattering interference.

Cascade laser optimization for 3H4 → 3H5 and 3F4 → 3H6 sequent transitions in Tm3+-doped materials.

We study a cascade laser scheme involving the 3H4 → 3H5 and 3F4 → 3H6 consecutive transitions in Tm3+-doped materials as a promising technique to favor laser emission at 2.3 µm. We examine the conditions in terms of the Tm3+ doping levels for which the cascade laser is beneficial or not. For this, Tm:LiYF4 lasers based on crystals with several doping levels in the range of 2.5 - 6 at.% with and without cascade laser are studied. For low doping of 2.5 at.% Tm3+, adding the laser emission at 1.9 µm allows to double the output power at 2.3 µm, whereas for high doping of 6 at.%, allowing the laser to operate at 1.9 µm totally suppresses the laser emission at 2.3 µm. An analytical model is developed and confronted with experimental results to predict this doping-dependent phenomenon and forecast the potential benefits. This study of cascade laser emission on the 3H4→ 3H5 and 3F4→ 3H6 transitions versus the Tm3+ doping level is finally extended to other well-known Tm3+-doped laser materials.

LED-pumped Er:Cr:YSGG light sources.

For, what we believe is, the first time, an Er:Cr:YSGG crystal is pumped by LEDs through a Ce:YAG luminescent concentrator. We demonstrate both laser emission at 2.79 µm and strong spontaneous emission at 1.6 µm. The luminescent concentrator delivers 1.5 ms pulses at 10 Hz in the visible (550-650 nm) to the Er:Cr:YSGG crystal, in a transverse pumping configuration. The Er:Cr:YSGG laser produces up to 6.8 mJ at 2.79 µm in a biconcave cavity. The Er:Cr:YSGG also stands out as a bright broadband incoherent source around 1.6 µm with a unique combination of peak power (351 mW) and brightness (1.4 W/sr/cm2).

Tm:CALGO lasers at 2.32†µm: cascade lasing and upconversion pumping.

We report on the first laser operation of a disordered Tm:CaGdAlO4 crystal on the 3H4 → 3H5 transition. Under direct pumping at 0.79 µm, it generates 264 mW at 2.32 µm with a slope efficiency of 13.9% and 22.5% vs. incident and absorbed pump power, respectively, and a linear polarization (σ). Two strategies to overcome the bottleneck effect of the metastable 3F4 Tm3+ state leading to the ground-state bleaching are exploited: cascade lasing on the 3H4 → 3H5 and 3F4 → 3H6 transitions and dual-wavelength pumping at 0.79 and 1.05 µm combining the direct and upconversion pumping schemes. The cascade Tm-laser generates a maximum output power of 585 mW at 1.77 µm (3F4 → 3H6) and 2.32 µm (3H4 → 3H5) with a higher slope efficiency of 28.3% and a lower laser threshold of 1.43 W, out of which 332 mW are achieved at 2.32 µm. Under dual-wavelength pumping, further power scaling to 357 mW at at 2.32 µm is observed at the expense of increased laser threshold. To support the upconversion pumping experiment, excited-state absorption spectra of Tm3+ ions for the 3F4 → 3F2,3 and 3F4 → 3H4 transitions are measured for polarized light. Tm3+ ions in CaGdAlO4 exhibit broadband emission at 2.3 - 2.5 µm making this crystal promising for ultrashort pulse generation.

Excited-state absorption and upconversion pumping of Tm3+-doped potassium lutetium double tungstate.

We report on a bulk thulium laser operating on the 3H4 → 3H5 transition with pure upconversion pumping at 1064 nm by an ytterbium fiber laser (addressing the 3F4 → 3F2,3 excited-state absorption (ESA) transition of Tm3+ ions) generating 433 mW at 2291 nm with a slope efficiency of 7.4% / 33.2% vs. the incident / absorbed pump power, respectively, and linear laser polarization representing the highest output power ever extracted from any bulk 2.3 µm thulium laser with upconversion pumping. As a gain material, a Tm3+-doped potassium lutetium double tungstate crystal is employed. The polarized ESA spectra of this material in the near-infrared are measured by the pump-probe method. The possible benefits of dual-wavelength pumping at 0.79 and 1.06 µm are also explored, indicating a positive effect of co-pumping at 0.79 µm on reducing the threshold pump power for upconversion pumping.

Ce:LYSO, from scintillator to solid-state lighting as a blue luminescent concentrator.

Cerium-doped lutetium-yttrium oxyorthosilicate (Ce:LYSO) is a well-known single crystal scintillator used in medical imaging and security scanners. Recent development of high power UV LED, matching its absorption band, questions the possibility to use Ce:LYSO in a new way: as LED-pumped solid-state light source. Since Ce:LYSO is available in large size crystals, we investigate its potential as a luminescent concentrator. This paper reports an extensive study of the performance in close relation to the spectroscopic properties of this crystal. It gives the reasons why the Ce:LYSO crystal tested in this study is less efficient than Ce:YAG for luminescent concentration: limited quantum efficiency and high losses coming from self-absorption and from excited-state absorption are playing key roles. However, we demonstrate that a Ce:LYSO luminescent concentrator is an innovative source for solid-state lighting. Pumped by a peak power of 3400 W in quasi-continuous wave regime (40 µs, 10 Hz), a rectangular (1 × 22 × 105 mm3) Ce:LYSO crystal delivers a broadband spectrum (60 nm FWHM) centered at 430 nm. At full output aperture (20 × 1 mm2), it emits a peak power of 116 W. On a squared output surface (1 × 1 mm2) it emits 16 W corresponding to a brightness of 509 W cm-2 sr-1. This combination of spectrum power and brightness is higher than blue LEDs and opens perspectives for Ce:LYSO in the field of illumination namely for imaging.

Dual-wavelength-pumping of mid-infrared Tm:YLF laser at 2.3†µm: demonstration of pump seeding and recycling processes.

Upconversion pumping of thulium lasers emitting around 2.3 µm (the 3H4 → 3H5 transition) has recently attracted a lot of attention as it is compatible with the mature Yb-laser technology. To explore this possibility, we built a mid-infrared Tm:LiYF4 laser pumped by an Yb:CaF2 laser at 1.05 µm delivering an output power of 110 mW at 2.31 µm for a maximum incident pump power of 2.0 W. A strong absorption issue appeared in the Tm laser: the slope efficiency vs. the incident pump power was 7.6% while that vs. the absorbed pump power reached 29%. To overcome this issue, a dual-wavelength pumping at 0.78 µm and 1.05 µm was explored (combining both the direct and upconversion pumping schemes). The reciprocal interplay between the two pumps was studied to evaluate their benefits in terms of the pump absorption and laser efficiency. We observed an interesting decrease of the laser threshold for upconversion pumping when adding a small fraction of the direct pump revealing a seeding effect for the excited-state absorption from the metastable 3F4 level. A recycling process of this manifold by excited-state absorption in the 3F4 → 3F2,3 loop was also observed. The pump absorption seeding is a viable route for the development of low-threshold upconversion pumped thulium lasers.

LED-pumped Cr:LiSAF laser system operating at 100†Hz based on a multipass amplifier.

The LED-pumping technology is used for the first time, to the best of our knowledge, to develop a complete master oscillator power amplifier (MOPA) system including a multipass amplifier. A pumping head using an original slab architecture is developed integrating a Cr:LiSAF slab pumped by 2112 blue LEDs via a Ce:YAG luminescent concentrator. The slab configuration enables the reaching of a large number of passes-up to 22-together with access to efficient cooling, allowing for a repetition rate scale up. For 22 passes, the amplifier delivers pulses with energy up to 2.4 mJ at 10-Hz repetition rate with a gain of 4.36 at 825 nm. A complete study of the MOPA is described, concluding in nearly constant performances versus the repetition rate, up to 100 Hz.

Light recycling in LED-pumped Ce:YAG luminescent concentrators.

We report the development of a high-brightness, high-power Ce:YAG luminescent concentrator pumped by 2240 blue LEDs in quasi-continuous wave operation (10 µs, 10  Hz). Using light confinement and recycling in the three space dimensions, the parallelepiped (1mm×14×mm×200mm) Ce:YAG emits a power of 145 W from a square output surface (1 × 1mm2) corresponding to a brightness of 4.6 kW/cm2/sr. This broadband yellow source has a unique combination of luminous flux (7.6 104 lm) and brightness (2.4 104 cd/mm2) and overcomes many other visible incoherent sources by one order of magnitude. This paper also proposes a deep understanding of the performance drop compared to a linear behavior when the pump power increases. Despite excited state absorption was unexpected for this low doped Ce:YAG pumped at a low irradiance level, we demonstrated that it affects the performance by tripling the losses in the concentrator. This effect is particularly important for small output surfaces corresponding to strong light recycling in the concentrator and to average travel distances inside the medium reaching meters.

LED-pumped femtosecond Cr:LiSAF regenerative amplifier system.

We report on the first, to the best of our knowledge, LED-pumped femtosecond regenerative amplifier. It is based on a Cr:LiSAF crystal pumped by 2240 blue LEDs via a Ce:YAG luminescent concentrator. The amplifier was seeded by pulses from a Ti:sapphire oscillator at 835 nm temporally stretched from 90 fs to 100 ps. At the output of the regenerative amplifier, we obtain 1 mJ pulse energy at a 10 Hz repetition rate, given by the frequency of the LED-pumping module. After compression, we obtain 100 fs pulses with a spectral bandwidth of 10 nm at 835 nm.

Generation of optically synchronized pump-signal beams for ultrafast OPCPA via the optical Kerr effect.

In recent years, multi-petawatt laser installations have achieved unprecedented peak powers, opening new horizons to laser-matter interaction studies. Ultra-broadband and extreme temporal contrast pulse requirements make optical parametric chirped pulse amplification (OPCPA) in the few-picosecond regime the key technology in these systems. To guarantee high fidelity output, however, OPCPA requires excellent synchronization between pump and signal pulses. Here, we propose a new highly versatile architecture for the generation of optically synchronized pump-signal pairs based on the Kerr shutter effect. We obtained >550µJ pump pulses of 12 ps duration at 532 nm optically synchronized with a typical ultrashort CPA source at 800 nm. As a proof-of-principle demonstration, our system was also used for amplification of ∼20µJ ultra-broadband pulses based on an OPCPA setup.

3D luminescent concentrators.

A solution to develop high-brightness incoherent sources consists in luminescent concentration. Indeed, the absorption/emission process in a high index medium allows us to circumvent the brightness conservation law by the confinement of the light in 1 or 2 dimensions. In practice, Ce-doped luminescent concentrators pumped with InGaN LED exceed LED's brightness by one order of magnitude. This work shows how light confinement in 3 dimensions increases the brightness by an additional order of magnitude. Thanks to an analytical approach validated by experimental results, this concept gives new degrees of freedom for the design of luminescent concentrators and paves the way to a generation of incoherent sources among the brightest ever designed.

Comparison of multi-pass and regenerative strategies for energetic high-gain amplifiers based on Yb:CaF2.

Yb-doped materials, due to their high saturation fluence and consequently their low gain, represent a challenging choice for high-energy amplifiers. In this Letter, we study two original amplifier designs adapted to a large number of passes capable of operating in the 100 mJ energy range at repetition rates up to 100 Hz using Yb:CaF2 crystals as active media. Amplification geometries based on double-head active-mirror configurations are presented. We confront two alternative strategies suitable for amplification of large beams: regenerative and geometrical multi-pass amplifiers. This Letter consists of finding the pivot point, allowing us to discriminate the specific interest of each strategy. We present compensation methods of the thermal lens adapted to each amplifier configuration with and without cavity, and we demonstrate that despite similar laser heads and pumping conditions, the thermal lens impacts differently the optimal performance for multi-pass or regenerative strategy. We perform amplification up to 66 mJ pulses at 10 Hz with the regenerative amplifier and 52 mJ at 100 Hz with the multi-pass amplifier.

Improvement in the temporal contrast in the tens of ps range of the multi-PW Apollon laser front-end.

We demonstrate the impact of the optics roughness in Öffner stretchers used in chirped pulse amplification laser chains and how it is possible to improve the temporal contrast ratio in the temporal range of 10-100 ps by adequately choosing the optical quality of the key components. Experimental demonstration has been realized in the front-end source of the multi-petawatt (PW) laser facility Apollon, resulting in an enhancement of the contrast ratio by two to three orders of magnitude.

Tunable UV source based on an LED-pumped cavity-dumped Cr:LiSAF laser.

We developed a light-emitting diode (LED)-pumped Cr:LiSAF laser operating in Q-switched and cavity-dumped regimes. The laser produces 1.1 mJ pulses with a pulse duration of 8.5 ns at a repetition rate of 10 Hz on a broad spectrum centered at 840 nm with a full width at half maximum of 23 nm. After frequency tripling in two cascaded LBO crystals, we obtained 7 ns pulses with an energy of 13 µJ at 280 nm and with a spectral width of 0.5 nm, limited by the spectral acceptance of the phase matching process. By rotating both LBO crystals, UV emission is tuned from 276 nm to 284 nm taking advantage of the broad infrared spectrum of the Cr:LiSAF laser.

LED-pumped passively Q-switched Cr:LiSAF laser.

We report, to the best of our knowledge, the first light-emitting diode (LED)-pumped Cr:LiSAF laser, in both quasi-continuous-wave (QCW) and passively Q-switched operation. This Letter is based on the recent development of LED-pumped luminescent concentrators (LCs). Combining the capacity of high-density integration of blue LEDs with the excellent properties of Ce:YAG LCs, this new pump source can deliver high irradiance (7.3 kW/cm2) in the visible to pump Cr:LiSAF. The Cr:LiSAF laser demonstrates an energy of 8.4 mJ at 850 nm in QCW (250 µs pulses at 10 Hz). A small signal gain per roundtrip of 1.44 at 850 nm and a wavelength tunability between 810 and 960 nm have been performed. A passively Q-switched oscillator is also presented using a Cr:YAG saturable absorber. A peak power of 3.1 kW is obtained with a pulse energy of 130 µJ and duration of 41.6 ns.

Dual-color deep-tissue three-photon microscopy with a multiband infrared laser.

Multiphoton microscopy combined with genetically encoded fluorescent indicators is a central tool in biology. Three-photon (3P) microscopy with excitation in the short-wavelength infrared (SWIR) water transparency bands at 1.3 and 1.7 µm opens up new opportunities for deep-tissue imaging. However, novel strategies are needed to enable in-depth multicolor fluorescence imaging and fully develop such an imaging approach. Here, we report on a novel multiband SWIR source that simultaneously emits ultrashort pulses at 1.3 and 1.7 µm that has characteristics optimized for 3P microscopy: sub-70 fs duration, 1.25 MHz repetition rate, and µJ-range pulse energy. In turn, we achieve simultaneous 3P excitation of green fluorescent protein (GFP) and red fluorescent proteins (mRFP, mCherry, tdTomato) along with third-harmonic generation. We demonstrate in-depth dual-color 3P imaging in a fixed mouse brain, chick embryo spinal cord, and live adult zebrafish brain, with an improved signal-to-background ratio compared to multicolor two-photon imaging. This development opens the way towards multiparametric imaging deep within scattering tissues.

LED-pumped alexandrite laser oscillator and amplifier.

Taking advantage of light-emitting-diode (LED) performance breakthrough driven by the lighting market, we report, to the best of our knowledge, the first LED-pumped chromium-doped crystal laser oscillator and amplifier based on alexandrite crystals (Cr3+:BeAl2O4). We developed a Ce:YAG concentrator as the pumped source, illuminated by blue LEDs that can be easily power scaled. With 2200 LEDs (450 nm), the Ce:YAG concentrator can deliver to the gain medium up to 268 mJ at 10 Hz at 550 nm with a irradiance of 8.5 kW/cm2. We demonstrate, in oscillator configuration, an LED-pumped alexandrite laser delivering an energy of 2.9 mJ at 748 nm in free running operation. In the cavity, we measured a double-pass small signal gain of 1.28, which is in good agreement with numerical simulations. As an amplifier, the system demonstrated to boost a CW Ti:sapphire laser by a factor of 4 at 750 nm in eight passes with a large tuning range from 710 nm to 800 nm.

Supercontinuum-seeded few-cycle mid-infrared OPCPA system.

We propose and demonstrate an OPCPA architecture emitting few-cycle pulses at 3070 nm and 1550 nm based on a high-energy femtosecond ytterbium-doped fiber amplifier pump. The short pump pulse duration allows direct seeding by a supercontinuum in the 1.4 - 1.7 µm signal range, generated in bulk YAG. It also allows a simplified dispersion management along the system and broad optical gain bandwidth. The dual output system delivers 20 µJ, 49 fs signal pulses at 1550 nm and 10 µJ, 72 fs idler pulses at 3070 nm. Power scaling limitations due to beam distortion in the last MgO:PPLN-based OPCPA stage are discussed and investigated.