Reprocessable Networks from Vegetable Oils, Salts, and Food Acids: A Green Polymer Outreach Demonstration for Middle School Students.

Massive amounts of mismanaged plastic waste have led to growing concerns about their adverse impacts on the environment, ecosystem, and human health. Enabling efficient plastic recycling is a key component for developing a sustainable future, which requires cohesive efforts in technology innovations, public awareness, and workforce development. Particularly, outreach activities to inform the broader community about current efforts to fabricate sustainable polymeric materials can play a central role in inspiring future generations while also improving their knowledge, viewpoints, and behaviors to address plastic waste challenges. Herein, this account demonstrates an effort to educate middle school students about a key emerging concept in polymer science for sustainable material development: reprocessable polymer networks. Background information is provided to the students about the need to transition from petroleum-based chemical feedstocks to their bioderived counterparts. We note that the materials used in this demonstration lesson are all produced from common household foods, with which students routinely interact in various applications, making them not only safe but also compelling for the middle school classroom.

Accurate additive manufacturing of lightweight and elastic carbons using plastic precursors.

Despite groundbreaking advances in the additive manufacturing of polymers, metals, and ceramics, scaled and accurate production of structured carbons remains largely underdeveloped. This work reports a simple method to produce complex carbon materials with very low dimensional shrinkage from printed to carbonized state (less than 4%), using commercially available polypropylene precursors and a fused filament fabrication-based process. The control of macrostructural retention is enabled by the inclusion of fiber fillers regardless of the crosslinking degree of the polypropylene matrix, providing a significant advantage to directly control the density, porosity, and mechanical properties of 3D printed carbons. Using the same printed plastic precursors, different mechanical responses of derived carbons can be obtained, notably from stiff to highly compressible. This report harnesses the power of additive manufacturing for producing carbons with accurately controlled structure and properties, while enabling great opportunities for various applications.

Immobilization of Protease K with ZIF-8 for Enhanced Stability in Polylactic Acid Melt Processing and Catalytic Degradation.

Polylactic acid (PLA) is a biodegradable alternative to petroleum-based polymers for improving environmental sustainability of our society. However, the limited degradation rate and environmental conditions for PLA-based products remain significant challenges for their broader use in various applications. While Proteinase K (Pro K) from Tritirachium album has been demonstrated to efficiently degrade PLA, its autocatalytic degradation function in composite films is underexplored. Here, this work reports a strategy that encapsulates Pro K with zeolitic imidazole framework-8 (ZIF-8) in situ, combining a PLA matrix to prepare Pro K@ZIF-8/PLA films through solvent casting. The method is scalable and commercially viable, and the pH and thermal stability of the Pro K enzyme are significantly enhanced after immobilization. The enzyme can retain 61.8% of its initial activity after annealing at 160 °C for 10 min, allowing for its use in the melt processing of filler-containing PLA films. As a result, Pro K@ZIF-8/PLA films in buffer solutions exhibit stable degradation rates, which can be extended to PLA decomposition in acidic environments. Moreover, the enzyme in Pro K@ZIF-8/PLA films prepared by thermoforming remains active sufficiently to degrade PLA with a weight loss of up to 15% in 2 weeks. These results further indicate that our strategy can be broadly applicable for melt processing and controlled degradation of PLA materials with immobilized enzymes, allowing for its transformative impact for promoting environmental sustainability.