Bismuth tungstate Bi2WO6: a review on structural, photophysical and photocatalytic properties.

This review paper provides a comprehensive overview of the recent trends in bismuth tungstate (Bi2WO6) research, covering its structural, electrical, photoluminescent, and photocatalytic properties. The structural characteristics of bismuth tungstate are explored in detail, including its different allotropic crystal structures with respect to its isotypic materials. The electrical properties of bismuth tungstate, such as its conductivity and electron mobility, are also discussed, along with its photoluminescent properties. The photocatalytic activity of bismuth tungstate is a particular focus, with recent advances in doping and co-doping strategies with metals, rare earth and other elements summarized. The limitations and challenges of using bismuth tungstate as a photocatalyst are also examined, such as its low quantum efficiency and susceptibility to photodegradation. Finally, recommendations for future research directions are provided, including the need for further studies on the underlying mechanisms of photocatalytic activity, the development of more efficient and stable bismuth tungstate-based photocatalysts, and the exploration of new applications in fields such as water treatment and energy conversion.

Low-temperature synthesis, characterization and photocatalytic properties of lanthanum vanadate LaVO4.

In this study, we have successfully prepared tetragonal lanthanum vanadate LaVO4 nanoparticles by a facile co-precipitation method at room temperature. The obtained materials were characterized using different structural and micro-structural techniques such as the characterization by X-ray diffraction (XRD), UV-Vis diffuse reflectance spectrum (DRS), transmission electron microscopy (TEM), and Raman spectrometry. The obtained structure is crystallized in single tetragonal phase with pin-like nanostructure. A main optical transition with bandgap energy of 3.26 eV is evidenced, and the average lifetime of charges carriers was found to be 1 ns Furthermore, the photoluminescence occurs in the visible light range. The photocatalytic activity was evaluated by the photocatalytic degradation of methylene blue (MB) with initial concentration of 10 mg L-1. The result indicates that LaVO4 particles showed a best photocatalytic activity of 98.2% degradation for methylene blue solution after irradiation of 90 min under visible light. Furthermore, the photocatalytic mechanism and reusability were studied.

ZIF-8 metal organic framework materials as a superb platform for the removal and photocatalytic degradation of organic pollutants: a review.

Metal organic frameworks (MOFs) are attracting significant attention for applications including adsorption, chemical sensing, gas separation, photocatalysis, electrocatalysis and catalysis. In particular, zeolitic imidazolate framework 8 (ZIF-8), which is composed of zinc ions and imidazolate ligands, have been applied in different areas of catalysis due to its outstanding structural and textural properties. It possesses a highly porous structure and chemical and thermal stability under varying reaction conditions. When used alone in the reaction medium, the ZIF-8 particles tend to agglomerate, which inhibits their removal efficiency and selectivity. This results in their mediocre reusability and separation from aqueous conditions. Thus, to overcome these drawbacks, several well-designed ZIF-8 structures have emerged by forming composites and heterostructures and doping. This review focuses on the recent advances on the use of ZIF-8 structures (doping, composites, heterostructures, etc.) in the removal and photodegradation of persistent organic pollutants. We focus on the adsorption and photocatalysis of three main organic pollutants (methylene blue, rhodamine B, and malachite green). Finally, the key challenges, prospects and future directions are outlined to give insights into game-changing breakthroughs in this area.

ZIF-8 metal organic framework composites as hydrogen evolution reaction photocatalyst: A review of the current state.

In the past decade, extensive research has been devoted to synthesis of ZIF-8 materials for catalytic applications. As physico-chemical properties are synthesis-dependent, this review explores different synthesis strategies based the solvent and solvent-free synthesis of zeolitic imidazole framework. Accordingly, the effect of several parameters on the ZIF-8 synthesis were discussed including solvent, deprotonating agents, precursors ratio is delivered. Additionally, the advantages and disadvantages of each synthesis have been discussed and assessed. ZIF-8 textural and structural properties justify its wide use as a stable high surface area MOF in aqueous catalytic reactions. This review includes the applicatios of ZIF-8 materials in photocatalytic hydrogen evolution reaction (HER). The efficiency of the reviewed materials was fairly assessed. Finally, Limitations, drawbacks and future challenges were fully debated to ensure the industrial viability of the ZIFs.

[Severe macrophage activation syndrome following visceral leishmaniasis in a child]. / Syndrome d'activation macrophagique sévère secondaire à une leishmaniose viscérale infantile.

Visceral leishmaniasis (VL) is a parasitic disease that is a public health problem in Morocco and is one of the frequent infectious causes of macrophage activation syndrome (MAS). The combination of clinical and laboratory criteria, even very unspecific, make it possible to diagnose MAS, but a definitive diagnosis requires cytological examination. Rapid treatment is essential. The outcome was favorable.