Enhanced ultrasonic degradation of methylene blue using a catalyst-free dual-frequency treatment.

Methylene blue is one of the most common pollutants found in wastewater, primarily due to its widespread use in the dye industry. Consequently, it is imperative to explore environmentally friendly and efficient methods for degrading this pollutant into non-toxic byproducts. While ultrasonic degradation methods in combination with additives or catalysts have proven effective, such additives or catalysts may inadvertently contribute to secondary pollution. Moreover, the preparation of these catalysts imposes an additional burden in terms of effort and cost. To address these issues, this paper introduces a catalyst-free dual-frequency ultrasound degradation approach for methylene blue. The sonochemical quality of the cavitation bubbles is improved using this technique because the bulk solution is populated with two types of bubbles, whose mean sizes are determined by the dual ultrasound frequencies. The findings demonstrate that, under identical acoustic power density conditions, dual-frequency ultrasound consistently outperforms single-frequency modes across all investigated parameters. Furthermore, the larger the difference between the dual frequencies used, the more effective the degradation of methylene blue. Finally, after just 20 min of sonication, a degradation efficiency of 91% was achieved with dual frequencies of 20 and 80 kHz at an acoustic power density of 209.63 ± 6.94 W/L. Consequently, this technique offers an environmentally friendly, catalyst-free, and highly effective method for degrading methylene blue.

Assessing Challenges of 2D-Molybdenum Ditelluride for Efficient Hydrogen Generation in a Full-Scale Proton Exchange Membrane (PEM) Water Electrolyzer.

Proton exchange membrane (PEM) water electrolyzers are critical enablers for sustainable green hydrogen production due to their high efficiency. However, nonplatinum catalysts are rarely evaluated under actual electrolyzer operating conditions, limiting knowledge of their feasibility for H2 production at scale. In this work, metallic 1T'-MoTe2 films were synthesized on carbon cloth supports via chemical vapor deposition and tested as cathodes in PEM electrolysis. Initial three-electrode tests revealed that at 100 mA cm-2, the overpotential of 1T'-MoTe2 approached that of leading 1T'-MoS2 systems, confirming its promise as a hydrogen evolution catalyst. However, when tested in a full-scale PEM electrolyzer, 1T'-MoTe2 delivered only 150 mA cm-2 at 2 V, far below expectations. Postelectrolysis analysis revealed an unexpected passivating tellurium layer, likely inhibiting catalytic sites. While initially promising, the unanticipated passivation caused 1T'-MoTe2 to underperform in practice. This highlights the critical need to evaluate emerging electrolyzer catalysts in PEM electrolyzers, revealing limitations of the idealized three-electrode configuration. Moving forward, validation of model systems in actual electrolyzers will be key to identifying robust nonplatinum catalysts for sustainable green hydrogen production.