Accuracy of maxillary full-arch digital impressions of tooth and implant models made by two intraoral scanners.

OBJECTIVES: Limited studies are available on the accuracy of intraoral scanners (IOSs) for full-arch implant and tooth models. This study aimed to assess the accuracy of maxillary full-arch digital impressions of tooth and implant models made by two IOSs. MATERIALS AND METHODS: This in vitro, experimental study was conducted on two maxillary dentiform models: one with six prepared natural teeth and the other with six implants at the site of canine, first premolar, and first molar teeth, bilaterally. A highly accurate industrial scanner was used for actual measurements on the models that served as the reference scan. TS (Trios3) and CO (CEREC Omnicam) IOSs were then used to scan each model 10 times according to the manufacturer's instructions. All scans were saved in STL format. The GOM Inspect software was used according to the best-fit algorithm to compare the accuracy of measurements in the groups with the reference scan. The trueness and precision were calculated. Statistical analyses were carried out using SPSS by one-way analysis of variance and t-test (α = .05). RESULTS: TS showed a significantly higher trueness than CO for both tooth and implant models (p < .05). TS also revealed significantly higher precision than CO for the tooth model; however, the difference in precision for the implant model was not significant between the two IOSs (p > .05). CONCLUSIONS: TS showed higher accuracy than CO in both tooth and implant models.

Hybrid silica aerogel nanocomposite adsorbents designed for Cd(II) removal from aqueous solution.

Hybrid silica aerogel (HSA) nanoparticles were synthesized by sol-gel method and drying at ambient pressure. Also, two magnetic nanocomposites of HSA with Fe3 O4 nanoparticles and chitosan (CS) were prepared including HSA-Fe3 O4 and HSA-Fe3 O4 -CS. The morphology, structure, and magnetic properties of the HSA as well as its nanocomposites were analyzed by SEM, XRD, TGA, VSM, and ATR-FTIR techniques. The saturation magnetization (Ms ) values for the Fe3 O4 NPs, HSA-Fe3 O4, and HSA-Fe3 O4 -CS nanocomposite film were 69.93, 19.04, and 5.77 emu/g, respectively. Furthermore, the abilities of the HSA, HSA-Fe3 O4 , CS, and HSA-Fe3 O4 -CS adsorbents were assessed for removal of cadmium(II) heavy metal ions (100 ppm) from aqueous solution. All adsorbents removed/adsorbed the maximum Cd(II) ions in 120 min when adsorbent dosage = 20 mg and pH = 8. Moreover, the highest adsorption capacities were 58.5, 69.4, 65.8, and 71.9 mg/g for the HSA, CS, HSA-Fe3 O4, and HSA-Fe3 O4 -CS, respectively. Kinetic studies using all adsorbents verified that Cd(II) adsorption obeyed the second-order model illustrating the analyte chemisorption was happened on the adsorbent surfaces. All adsorption data were well consistent with the Langmuir isotherms. The reusability experiment confirmed that all of adsorbents could preserve >95% of their initial adsorption capacities even after five series of adsorption/desorption tests. PRACTITIONER POINTS: Hybrid silica aerogel (HSA), HSA-Fe3 O4, and HSA-Fe3 O4 -CS adsorbents were produced. Nanocomposites were characterized by XRD, TGA, SEM, VSM, and ATR-FTIR analysis. Adsorption of cadmium(II) ions by adsorbents was examined in aqueous solution. The highest adsorption capacity was obtained for the HSA-Fe3 O4 -CS (71.9 mg/g). Cd(II) adsorption followed second-order kinetics and Langmuir isotherm model.