Oil-Water Separation using Synthetic Trees.

Existing oil-water filtration techniques require gravity or a pump as the driving force for separation. Here, we demonstrate transpiration-powered oil-water filtration using a synthetic tree, which operates pumplessly and against gravity. From top to bottom, our synthetic tree was composed of: a nanoporous "leaf" to generate suction via evaporation, a vertical array of glass tubes serving as the tree's xylem conduits, and filters attached to the tube inlets to act as the oil-excluding roots. When placing the tree in an oil emulsion bath, filtrate samples were measured to be 97-98% pure water using gravimetry and refractometry. The spontaneous oil-water separation offered by synthetic trees could be useful for applications such as oil spill cleanup, wastewater purification, and oil extraction.

Transpiration-powered desalination water bottle.

Inspired by mangrove trees, we present a theoretical design and analysis of a portable desalinating water bottle powered by transpiration. The bottle includes an annular fin for absorbing solar heat, which is used to boost the evaporation rate of water from the interior synthetic leaf. This synthetic leaf comprises a nanoporous film deposited atop a supporting micromesh. Water evaporating from the leaf generates a highly negative Laplace pressure, which pulls the overlying source water across an upstream reverse osmosis membrane. Evaporated water is re-condensed in the bottom of the bottle for collection. The benefit of our hybrid approach to desalination is that reverse osmosis is spontaneously enabled by transpiration, while the thermal evaporation process is enhanced by heat localization and made more durable by pre-filtering the salt. We estimate that a 9.4 cm diameter bottle, with a 10 cm wide annular fin, could harvest about a liter of fresh water per day from ocean water.