Trajectories of technogenic tritium in the Rhône River (France).

Tritium is a radioisotope of hydrogen with a half-life of 12.32 years and was used for its luminescent properties by the watchmaking industry from 1962 to the 2008. Tritiated luminescent salts were integrated in the paints applied on the index and dial of watches and clocks. French and Swiss watchmaking workshops used more than 28 000 TBq of tritium over this period of time and produced almost 350 million watches. Despite the end of tritiated salts use in watchmaking workshops in 1992 in France and 2008 in Switzerland, high level of organically bound tritium (OBT) are still observed in sediments of the Rhône River downstream the Lake Geneva. Contamination of the Rhône River by tritiated hot particles since 1962 up to nowadays remains poorly documented. In order to assess the long term behavior and fate of technogenic tritium in this river and its trajectories in the river system, two sediment cores were collected at the upstream (UC) and downstream (DC) part of the Rhône River in France and OBT contents were determined. For both sedimentary cores, maximum OBT contents were registered over the 1980s when tritium was intensively used by watchmaking industries. These residual OBT contents are 1 000 to 10 000 fold higher than current natural background levels in riverine sediments. The OBT contents progressively decreased since 1989 with close effective half-life in upstream and downstream area (5 ± 2 years). The OBT contents were lower in DC than in UC due to the dilution by uncontaminated sediments delivered by tributaries not affected by the watchmaking industries. Trajectories analysis indicates that the resiliency of the Rhône River system in regards to this contamination would be reached in 14-70 years and in 14-28 years respectively for the upstream and downstream part of the river.

An invitation to contribute to a strategic research agenda in radioecology.

With intentions of integrating a portion of their respective research efforts into a trans-national programme that will enhance radioecology, eight European organisations recently formed the European Radioecology ALLIANCE (www.er-alliance.org). The ALLIANCE is an Association open to other organisations throughout the world with similar interests in promoting radioecology. The ALLIANCE members recognised that their shared radioecological research could be enhanced by efficiently pooling resources among its partner organizations and prioritising group efforts along common themes of mutual interest. A major step in this prioritisation process was to develop a Strategic Research Agenda (SRA). An EC-funded Network of Excellence in Radioecology, called STAR (Strategy for Allied Radioecology), was formed, in part, to develop the SRA. This document is the first published draft of the SRA. The SRA outlines a suggested prioritisation of research topics in radioecology, with the goal of improving research efficiency and more rapidly advancing the science. It responds to the question: "What topics, if critically addressed over the next 20 years, would significantly advance radioecology?" The three Scientific Challenges presented within the SRA, with their 15 associated research lines, are a strategic vision of what radioecology can achieve in the future. Meeting these challenges will require a directed effort and collaboration with many organisations the world over. Addressing these challenges is important to the advancement of radioecology and in providing scientific knowledge to decision makers. Although the development of the draft SRA has largely been a European effort, the hope is that it will initiate an open dialogue within the international radioecology community and its stakeholders. This is an abbreviated document with the intention of introducing the SRA and inviting contributions from interested stakeholders. Critique and input for improving the SRA are welcomed via a link on the STAR website (www.star-radioecology.org).

Radiological consequences of the extreme flooding on the lower course of the Rhone valley (December 2003, south east France).

In early December 2003 unusual weather conditions led to major flooding of the lower Rhone valley. When it floods, the Rhone carries large masses of solid matter in suspension, which potentially includes associated artificial (anthropogenic) radioactive contaminants from soil drainage in the catchment area and from re-uptake of sedimentary matter that has been contaminated with low-level radioactive liquid effluents from almost twenty nuclear facilities situated along the Rhone valley. A sampling campaign was carried out to investigate the level and spread of both sediment mass and associated radioactive contamination across the flooded areas. An attempt was made to assess the radiological consequences of such an extreme event on contamination of the food chain. Our results show that almost 700,000 tons of sediment was transported onto the floodplain, of which 80% were coarse and fine sands. These materials transferred 6660 MBq of 137Cs, 93 MBq of (239+240)Pu, 13 MBq of 238Pu and 204 MBq of 60Co over a surface area of 60 km2. More than 90% of deposited sediments are concentrated in a 10 km2 area of agricultural soils, and we estimated that 18% were plowed into the soil. Nevertheless, the level of activity measured in the vegetable crops and milk was not significantly different from the level measured in similar samples from regions that were not affected by the December 2003 floods.

Distribution of organic carbon, selected stable elements and artificial radionuclides among dissolved, colloidal and particulate phases in the Rhône River (France): preliminary results.

The behaviour of radionuclides discharged from nuclear facilities in the Rhône River depends on their distribution among the dissolved, colloidal and particulate phases. A large water sample was fractionated using sequential ultrafiltration. Size distributions of organic carbon, Fe, Al, Si, Ca, Mg, Cu, Zn, 137Cs, 60Co and 106Ru were obtained. Our results show that organic colloids account for 11% of the total organic carbon content. Approximately 20% of the dissolved (< 450 nm) Fe and Al are in colloidal classes. 137Cs is not significantly transferred by the colloidal phase while 25% of 60Co or 106Ru is associated with organic and inorganic colloids.

Ultrafiltration of large volumes for the determination of colloidally bound artificial radionuclides in natural waters.

A methodology based on large volume ultrafiltration (> 1000 l) is developed in order to characterize the artificial radionuclides associated with the colloidal populations in natural waters. "Inorganic elements" and organic carbon sinks or sources due to sorption or post desorption within the ultrafiltration assembly/membranes of the Sartorius system are underlined and discussed from methodological step experiments as well as recoveries obtained for artificial radionuclides such as 106Ru, 125Sb, 137Cs and 239+240Pu fractionating natural waters from the Rhône River (France), its estuary and the Mediterranean Sea (Gulf of Lions).