Preparation of sulfur self-doped coal-based adsorbent and its adsorption performance for Cu2.

The limited application of high-sulfur coal (HSC) and the increasing severity of copper pollution in solution are two pressing issues. To alleviate such issues, a sulfur self-doped coal-based adsorbent (HSC@ZnCl2) was obtained by pyrolysis (850 °C, 60 min holding time) of HSC and ZnCl2 with a mass ratio of 1:0.5. The results adsorption experiment revealed that the endothermic and spontaneous adsorption process was consistent with the Sips isothermal model (R2 = 0.992) and pseudo-second-order kinetic (R2 = 0.994), and that the adsorption process with a maximum adsorption capacity of 11.97 mg/g. Meanwhile, the adsorption of Cu2+ onto HSC@ZnCl2 was a result of the synergistic effects of various interactions, such as the complexation by oxygen-containing functional groups, electrostatic attraction and surface precipitation by ZnS on the adsorbent surface, and the process also included redox reaction. The findings of this work indicate that the preparation of sulfur self-doped coal-based adsorbent prepared from high-sulfur coal is a promising method for its large-scale utilization.

Cultivation and Nutritional Evaluation of Agaricus bisporus with Tea Residue as Culture Medium.

Different constituents of the cultivation substrate have significant effect on the yield and quality of edible mushrooms. The residue after the extraction of instant tea has exhibited to be biologically significant, and could be used as a substrate for cultivation. This study aimed to investigate the feasibility of tea extraction residue (TER) on button mushroom (Agaricus bisporus) cultivation, as an ingredient in the substrate, and assess the growth status, nutritional values, and sensory characteristics of fruiting body. The results showed that the strains could grow well on the cultivated substrate with 20% addition of TER. The total amount of hydrolyzed amino acids in the fruiting bodies of three TER-based groups (TER accounted for 10%, 20%, and 37.5%, respectively) was higher than that of the control group, and the total amount of essential amino acids was increased by 33.33%, 22.47%, and 9.92% compared with the control group, respectively. In addition, the results of gas chromatography-mass spectrometry (GC-MS) revealed that the addition of TER to the cultivation of substrate significantly enhanced the content of typical mushroom-flavor compounds in button mushroom, such as 1-octen-3-ol, 3-octanol, and 1-octen-3-one. It can be concluded that TER may be an ideal choice for the substrate in commercial cultivation of button mushroom.

Will China's R&D investment improve green innovation performance? An empirical study.

In 2020, China's R&D investment reached 2442.6 billion RMB, and it ranks second in the world, but the performance of green innovation has not proportionately improved. The question of how to promote the improvement of green innovation performance is particularly important in order to mitigate future environmental problems and issues due to rapid development of China's economy. While past research has examined the relationship between R&D investment and green innovation, they have not explicitly considered the effect of regional technological innovation level on this relationship. Hence, we fill this gap by exploring the relationship between R&D investment and green innovation performance using data from various regions in China from 2015 to 2019, under the effect of a threshold variable, namely, technological innovation. We explore the impact of economic development level, environmental regulation level, foreign direct investment, and science and technology in fiscal expenditures on green innovation performance. The empirical results show that when the regional technological innovation level is used as the threshold variable, the R&D investment has a significant double-threshold effect with the lagging three-phase green innovation performance. When the technological innovation level is low (< 0.1082), R&D investment has a negative impact on green innovation performance. Moreover, when the technological innovation level is high (>0.5837), the impact of regional R&D investment on green innovation performance is sub-optimal. Consequently, the range of [0.1082 to 0.5837] is the best range for the positive impact of R&D investment on green innovation performance. Furthermore, among China's 30 provinces and cities, 24% (mostly areas located in the southwest and northeast of China) have the technological innovation level in the optimal range. Our results help explain the current status of China's R&D investment and green innovation development, and provide a theoretical basis for the formulation of government innovation investment policies.