Bonding performance and interfacial adaptation of modern bulk-fill restorative composites after aging in artificial saliva: an in vitro study.

OBJECTIVES: This study aimed at comparing the microtensile bond strength (MTBS) and interfacial adaptation of a modern self-curing and a light-curing restorative bulk-fill composite to a conventional composite applied with the layering technique. METHODS: Forty-eight occlusal cavities were divided in three main groups (16/group) based on tested materials: (i) STELA, bulk-fill self-curing restorative (STELA, SDI Ltd.); (ii) 3 M-BULK, bulk-fill composite (Filtek One Bulk-Fill, 3 M Oral Care); and (iii) 3 M-CTR, a conventional composite (Filtek Supreme XTE, 3 M Oral Care). These were used in combination with their adhesives in self-etch (SE) or etch-and-rinse (ER) mode. Specimens stored in artificial saliva (24 h or 12 months) were evaluated for MTBS and fractography. The interfacial analysis was performed through confocal microscopy. ANOVA and Fisher's LSD post hoc tests were performed with a level of significance of 5%. RESULTS: All the tested materials applied in ER mode presented (24 h) greater bond strength than in SE mode. Although all materials showed a significant drop in the bond strength after prolonged storage, STELA showed the highest bonding performance and interfaces with few gaps. 3 M-BULK had the lowest bond strength and an interface with several voids and gaps. CONCLUSIONS: All materials were affected by interface degradation and bonding reduction over prolonged aging. However, their use in combination with adhesives applied in ER mode may offer greater immediate bonding performance. CLINICAL RELEVANCE: The use of restorative light-curing bulk-fill composites may generate gaps at the bonding interface and voids. STELA may represent a suitable alternative to avoid such issues.

Multi-response optimisation analysis of material properties in dental restorative composites under the influence of thermal and thermomechanical stimuli - A 3D finite element study.

OBJECTIVES: Restored teeth undergo more damage than intact teeth. Therefore, the scientific investigation of their mechanical and physical behaviour under varying oral conditions is vital. The current study is to numerically investigate the stresses on a class-II mesio-occluso-distal (MOD) restored molar due to thermal and thermomechanical stimuli with varying input properties such as coefficient of thermal expansion and elastic properties. This is performed to optimise the dental restoration material, thereby reducing the stresses and failure of the restoration. METHODS: An upper molar was scanned using µ-CT for segmenting and modelling the enamel and dentine. A class-II MOD cavity was then prepared on the model, after which non-manifold meshing was generated. The coefficient of thermal expansion (CTE) and elastic modulus (E) properties of the restoration were varied from 20 × 10-6 °C-1 to 55 × 10-6 °C-1 and 5 GPa-20 GPa, respectively. After the material properties and boundary conditions were set for the finite element (FE) analysis, the thermal and thermomechanical loading analyses were performed to demonstrate the influence of input parameters on the stress. The maximum values of principal stresses on the restoration-enamel junction and the restoration were evaluated. The results were statistically processed using analysis of variance, response surface methodology (RSM) and optimisation analysis to estimate the most optimum inputs for minimising principal stresses. RESULTS: The study reveals that the location of principal stress occurs at the restoration-enamel junction (REJ) and the restoration changes based on the composite material value of E and CTE due to thermal and thermomechanical stimuli. The REJ showed higher principal stress than restoration during the application of both thermal and thermomechanical stimuli, making it more vulnerable to fracture and failure. Moreover, the study showed non-linear variations in the values and locations of principal stresses due to thermal and thermomechanical stimuli with the change in the property of the restoration composite used. Finally, this study derived an optimised restorative value for CTE and E due to the application of thermal and simultaneous thermal and mechanical stimuli. CONCLUSION: This study highlights the importance of choosing the suitable material properties of the restoration composite by dental clinicians to repair a large class MOD cavity. The findings from this study also suggest that the difference in the values of E and CTE in a dental restoration composite when compared with the enamel causes a lack of uniformity in mechanical and thermal properties, thereby forming stress concentrations at the interfaces. The study establishes two optimised CTE and E values for the MOD restoration composite as 25 × 10-6 °C-1 and 20 GPa and 37 × 10-6 °C-1 and 5 GPa, respectively.

Effect of silane coupling agent and concentration on fracture toughness and water sorption behaviour of fibre-reinforced dental composites.

OBJECTIVES: This paper presents the effect of silane treatment of S-2 Glass fibres on the fracture toughness and water sorption/solubility behaviour of fibre-reinforced flowable dental composites. The effect of epoxy- and methacrylate-based silane coupling agents (SCAs) on the mechanical strength and hydrolytic properties were investigated. The concentration of the selected SCAs on the mechanical and physical properties were investigated. The influence of molecular structure and concentration in the interfacial adhesion at the fibre-matrix interfaces was also studied. METHODS: Short S-2 Glass fibres of 250 µm in length and 5 µm in diameter were etched with acid to remove any impurities and roughen the surface. The acid-etched fibres were silane treated with 3MPS, 3GPS, and 8MOTS at different concentrations by weight (%). The silane-treated fibres were incorporated at 5 % into the dental resin mixture. Untreated fibres were added at 5 % to the dental resin mixture and served as the control group. The physical properties such as water sorption, solubility, and desorption along with mechanical properties such as fracture toughness and total fracture work of the fibre-reinforced dental composites grafted with the above-mentioned SCAs were evaluated. The surface morphology of the fractured surface was studied and analysed. RESULTS: The fracture toughness tests showed that the dental composites grafted with optimum weight per cent (wt. %) concentration of the SCA had a better stress intensity factor (KIC) when compared to the 2.0 wt. % and 3.0 wt. % concentration. The KIC value of dental composites grafted with untreated surface etched glass fibres was less than the KIC values of dental composites grafted with optimum concentrations of 3MPS, 3GPS, and 8MOTS by 81.6 %, 38.6 %, and 110.5 %, respectively. A similar trend was found while investigating the total work of fracture of the dental composites, between optimum concentration, 2.0 wt. % and 3.0 wt. % concentration of respective SCA. The increase in silane concentration also led to an increase in the water sorption/solubility characteristics. The absorption of water was most severe in the fibre-reinforced dental composites without silane treatment (32.9 µg/mm3). The ANOVA results showed that the fibre-reinforced dental composites grafted with 8MOTS at optimum concentration showed an increase in fracture toughness when compared to optimum concentrations of 3GPS and 3MPS by 51.9 % and 15.9 %, respectively. The enhanced mechanical and physical characteristics are due to the increased adhesion between the fibre and silane achieved from the optimum wt. % concentration of 8MOTS. Similarly, dental composites grafted with 8MOTS at optimum concentration showed a decrease in water sorption characteristics when compared to optimum concentrations of 3GPS and 3MPS by 18.2 % and 0.6 %, respectively. The decreased water sorption characteristics at the optimum concentration of 8MOTS could be due to the reduced availability of reactive hydroxyl groups and the hydrophobic characteristics of 8MOTS. SIGNIFICANCE: Silane coupling agents (SCAs) are important components of dental composites. The type and concentration of SCA have a significant effect on material properties. The current study focuses on understanding the effects of different SCAs and wt. % concentrations on the interfacial fracture behaviour and the influence of different SCAs on the water sorption and solubility behaviour of S-2 Glass fibre-reinforced flowable dental composites.

Design and tribological performance of short S-Glass fibre reinforced biocomposites on the influence of fibre length and concentration.

Fibre-reinforced biocomposites usage has gained prominence over the past decade. Although higher fracture toughness was observed when fibres were added to biocomposites, material degradation could occur due to filler and fibre content intolerance in the biocomposite matrix. Optimisation of resin-fibre-filler ratios helps in increasing the tribological performance of high load-bearing applications. However, the tribological performance is less understood due to limited in-vitro studies on the effect of fibre microstructures. A comprehensive investigation of the reciprocating and rotary wear behaviour of different compositions was carried out by varying fibre (0%, 5%, 10% and 15%) to particulate filler (40%, 45%, 50%, and 55%) weight fractions. The investigation aimed to identify the optimal composition of fibre-reinforced biocomposites based on the in-vitro ball-on-disc reciprocating and rotary wear tests in the presence of modified Fusayama solution. The cross-sectional areas of wear tracks were analysed using laser microscopy and scanning electron microscopy techniques to assess the surface morphology and subsurface damage of the wear tracks on biocomposites and the antagonist. The numerical results were statistically analysed using two-way ANOVA followed by a posthoc Tukey's test (p = 0.05). The results showed a combination of adhesive, abrasive and fatigue wear for all the tested Groups. The friction coefficient had a longer transient period for the 5 wt% and 10 wt% Groups. Based on the surface roughness, coefficient of friction, SEMs, specific wear rate, and ease of manufacturing, the threshold limit for fibre loading was found to be 10 wt%. The rotary test had a considerably lower specific wear rate compared to the reciprocating test. Fibre weight fraction was found to be the influencing factor of the abrasive wear behaviour compared to fibre length for the tested Groups.

Influence of silane coupling agent on the mechanical performance of flowable fibre-reinforced dental composites.

OBJECTIVES: This experimental investigation explored the optimisation of silane treatment of surface-modified S-2 Glass fibres in restorative dental composites for improved mechanical performance. The influence of optimum amount of silane to improve the interfacial adhesion at the fibre-matrix interfaces and its effect on the mechanical properties of the restorative composites were explored. METHODS: S-2 Glass fibres of 5 µm diameter and 250 µm length were surface modified using the acid etching technique. The etched fibres were then treated with either 3-methacryloxypropyltrimethoxysilane (3-MPS), 3-Glycidoxipropyltrimethoxysilane (3-GPS) or 8-methacryloxyoctyltrimethoxysilane (8-MOTS) at varying molar % / wt% concentrations. Fibres that were not silanised with any silane coupling agents were used as the control sample. The silanol content of each mixed silane was observed using Fourier transform infrared (FT-IR) spectroscopy analysis. Fibres (5 wt%) with optimised molar% / wt% silane coupling concentration were added to UDMA/TEGDMA dental resin. Mechanical properties such as flexural strength, flexural modulus, and the breaking energy of the materials were evaluated using a comprehensive experimental programme. RESULTS: FTIR spectrum of glass fibre silanised with each silane coupling agent revealed many peaks from 3800 to 1400 cm-1, indicative of -CH3, -CH2, and CO bonding, suggesting the proper silanization of the fibre. The contact angle test revealed that optimum wt% concentration of 3-MPS, 3-GPS and 8-MOTS were 0.5%, 0.8% and 1.4% respectively. The flexural strength of the fibre-reinforced with optimum concentration of 3-MPS (DC-3-MPS_0.5%) increased by 7.0% compared to those of the 2 wt% concentration of 3-MPS fibre-reinforced composite (DC-3-MPS_2.0%). While the flexural strength of optimum concentration 8-MOTS grafted dental resin composites (DC-8-MOTS_1.4%) were 9.9% higher than that of 2 wt% concentration 8-MOTS grafted dental resin composite (DC-8-MOTS_2.0%) and the flexural strength of optimum concentration of 3-GPS (DC-3-GPS_0.8%) was 7.5% higher when compared to that of 2 wt% concentration 3-GPS grafted dental resin composites (DC-3-GPS_2.0%). A concurrent trend was found while investigating the fracture behaviour of the dental composite with optimum wt% concentration of each silane coupling agent against its corresponding higher wt% concentrations. The ANOVA results showed that the optimum fibre-reinforced dental composites grafted with 8-MOTS showed better mechanical behaviour when compared to 3-GPS and 3-MPS. SIGNIFICANCE: The interfacial adhesion between the fibre and the resin due to silane coupling agents has helped to improve the mechanical properties of the fibre-reinforced dental composite. This is the first experimental study to provide a thorough investigation into the significance of the optimal use of silane coupling agents to treat the S-2 Glass fibres and subsequently the influence on the mechanical performance of the fibre-reinforced flowable dental composites.

The influence of dental restoration depth, internal cavity angle, and material properties on biomechanical resistance of a treated molar tooth.

OBJECTIVES: To assess the hypotheses that a restored tooth structure for a class II occlusal-distal (OD) cavity can be reinforced by optimizing the cavity geometry and choosing composites with adequate mechanical properties. METHODS: A human maxillary molar tooth was scanned, and segmented. The 2D profiles of dentin and enamel were drawn and imported to ABAQUS software. Eighteen restored tooth models with different cavity occlusal depths (OcDs) and internal cavity angles were developed. A semi-circular stone part was used to apply contact loads to the restored tooth model. After setting up the required interactions and boundary conditions, a written Python code was used to automatically assign a wide range of elastic moduli, from 2 GPa to 26 GPa, to the composite restorations, and assign constant material properties to the enamel and dentine. For simplicity, the behaviour of the mechanical material was postulated homogeneous and elastic, while the FE analyses were linearly carried out in this study. Also, the code enabled the FEA software to conduct the stress analyses, determine maximum principal stresses, and record the obtained results. RESULTS: The internal cavity angle formed between the mesial wall and the pulpal floor of the cavity significantly changed the peak maximum principal stress both in the enamel and restoration. The peak stress concentrations were observed mostly at the enamel-restoration interface, with an almost perpendicular orientation to this interface. Regarding the effect of occlusal cavity depth (OcD), the model with the shallowest cavity (OcD = 1.5 mm) represented greater resistance to applied loads than the model with deeper cavities (OcD = 2.0 mm and OcD 2.5 mm). The composite modulus (CM) in the range of 10-18 GPa reduced the maximum principal stress concentrations in the enamel. The lowest result for maximum principal stress was observed in the model with OcD = 1.5 mm, CM = 10 GPa and internal cavity angles = 100°, which was the strongest model against contact loads. SIGNIFICANCE: Class II OD cavities with optimal geometry have reduced induced stress levels, thus being able to be more mechanically robust against contact load transmitted by a stone. Cavity geometry designs with obtuse (more than 90°) internal cavity angles were significantly efficient in minimizing peak stress concentrations. The results indicated that for the model with obtuse internal cavity angles, choosing a composite with optimised properties can diminish stress, particularly at the tooth-restoration interface. Furthermore, the shallowest the cavity, the sturdier the restoration was, especially when the interface tooth-restoration laid on enamel and not on dentine.

Influence of thermal and thermomechanical stimuli on a molar tooth treated with resin-based restorative dental composites.

OBJECTIVES: In-vivo experimental techniques to understand the biomechanical behavior of a restored tooth, under varying oral conditions, is very limited because of the invasive nature of the study and complex tooth geometry structure. Therefore, 3D-Finite element analyses are used to understand the behavior of a restored tooth under varying oral conditions. In this study, the distribution of maximum principal stress (MaxPS) and the location of MaxPS on a restored tooth using six different commercially available dental resin composites under the influence of thermal and thermomechanical stimuli are performed. METHODS: An intact tooth was scanned using µ-CT and segmented to obtain separate geometric models of the tooth, including enamel and dentine. Then, a class II mesial-occlusal-distal (MOD) cavity was constructed for the tooth model. The restored tooth model was further meshed and imported to the commercial Finite Element (FE) software ANSYS. Thermal hot and cold stimuli at 50 °C and 2 °C, respectively, were applied on the occlusal and lingual surface of the tooth model with the tooth's ambient temperature set at 37 °C. A uniform loading of 400 N was applied on the occlusal surface of the tooth to imitate the masticatory forces during the cyclic thermal stimuli. RESULTS: The results of this study showed that the restorative materials with higher thermal conductivity showed a lower temperature gradient between the restoration and enamel, during the application of thermal stimuli, leading to a higher value of MaxPS on the restoration. Moreover, on applying thermal stimuli, the location of MaxPS at the restoration-enamel junction (REJ) changes based on the value of the coefficient of thermal expansion (CTE). The MaxPS distribution on the application of simultaneous thermal and mechanical stimuli was not only dependent on the elastic modulus of restorative materials but also their thermal properties such as the CTE and thermal conductivity. The weakest part of the restoration was at the REJ, as it experienced the peak stress level during the application of thermomechanical stimuli. SIGNIFICANCE: The findings from this study suggest that restorative materials with lower values of elastic modulus, lower coefficient of thermal expansion and higher values of thermal conductivity result in lower stresses on the restoration. The outcomes from this study also suggest that the thermal and mechanical properties of a restorative material can have a considerable effect on the selection of restorative materials by dental clinicians over conventional restorative materials.

The effect of dental restoration geometry and material properties on biomechanical behaviour of a treated molar tooth: A 3D finite element analysis.

OBJECTIVES: To test the hypothesis that restoration of class II mesio-occlusal-distal (MOD) cavities can be strengthened through judicious choice of restoration geometry and material properties. METHODS: An intact extracted human maxillary molar tooth was digitized, segmented, reconstructed, and four 3D restored tooth models were developed with four different restoration geometries: one straight, one single-curved, and two double-curved. Stress analysis was conducted for representative loading using finite element analysis, and maximum principal stresses were determined at the dentine-enamel and restoration-enamel junctions. A range of restorative material elastic moduli (5-80 GPa) and Poisson's ratios (0.25-0.35) were studied. Vertical loads of 400 N were applied on occlusal points, while the roots of the molar teeth, below the crevices, were supported in all directions. All the materials were modelled as homogeneous, isotropic, and elastic. RESULTS: The maximum principal stresses at the restoration-enamel junctions were strongly dependent on the MOD restoration geometries. Peak stresses occurred along the palatal surface of the restoration rather than the opposite buccal surface. Double-curved restorations showed the lowest peak stress at restoration-enamel junctions. Choice of the mechanical properties of restorative material in the range of 5-35 GPa further reduced stress concentrations on the enamel. SIGNIFICANCE: Class II MOD restorations may be stronger if designed with double-curved marginal geometries that can reduce stress concentrations. Designs with convex and concave geometries were particularly effective because they reduced stress concentrations dramatically. Results suggest that relatively minor changes to the geometry of a restoration can have a substantial effect on stress at the restoration-enamel junction and motivate future experimental analysis.

Evaluation of depth-wise post-gel polymerisation shrinkage behaviour of flowable dental composites.

Short fibre reinforced flowable dental composites are gaining acceptance over particulate filled composites due to their competence to impart improved physio-mechanical properties and capability to prevent crack propagation. However, limited research exists to assess their overall post-gel shrinkage behaviour, which is an important factor to determine marginal seal around restoration and hence its longevity. In this paper, depth-wise post-gel shrinkage strain and the resulting factors such as degree of conversion and rheological behaviour of flowable fibre reinforced composite (FRC) containing 5% weight fraction of 5 µm diameter, 350 µm length S-Glass fibres in UDMA/TEGDMA mixture along with 50% strontium filler particles were investigated. Post-gel shrinkage strain was measured using an array of optical fibre Bragg grating sensors (FBGs) of diameter 250 µm and length 1 mm each embedded at three different depths (depth 0 mm, depth 2.5 mm and depth 5 mm from curing light tip) within the flowable dental composite samples. The rheological behaviour during the polymerisation process was carried out using dynamic oscillatory tests. To evaluate the conversion of CC during polymerisation, degree of conversion tests were conducted by using FTIR spectroscopy. The results obtained for FRC samples were further compared with that of particulate filled composite (PFC) samples, with 55% strontium filler particles only within the same resin system. The relationship between post-gel shrinkage strain at different depths, rheological behaviour and degree of conversion was also explored. The experimental results from the sensor embedded materials suggested that the post-gel shrinkage strain was higher at the top surface (depth 0 mm) and was 50% more than at the bottom surface (depth of 5 mm) for dental FRC as well as PFC samples. Further, similar flow behaviour and not significant different (p<0.05) degree of conversion (DC), post-gel shrinkage strain for dental PFC and FRC composites was observed, establishing a convincing positive relationship between all the key factors and further implying that replacement of fibres with fillers did not affect the overall post-gel polymerisation shrinkage behaviour in dental composites. This investigation has also demonstrated that fibre optic sensors-based shrinkage measurements can be an ideal technique to evaluate post-gel shrinkage performance of dental resins with PFCs or FRCs.

Dimensional stability of short fibre reinforced flowable dental composites.

Fibre-reinforced dental composites are proven to have superior mechanical properties in comparison with micro/nano/hybrid filled composites. However, the addition of small quantities of short glass fibres could affect the dimensional stability of the restoration both during initial stages as well as through the life of the restoration. This in-vitro study aims at evaluating the physical properties of short S-Glass reinforced flowable dental composites. Two S-Glass short fibre-particulate reinforced (5 wt% of aspect ratios 50 and 70) and one particulate only reinforced flowable dental composites were prepared with UDMA-TEGDMA based dental monomer systems. Samples were photopolymersied for 60 s and stored in distilled water at 37 °C for 24 h before testing. Depth of cure (through-thickness microhardness), volumetric shrinkage (Archimedes technique), polymerisation stress (cantilever based tensometer), curing exotherm (thermocouple), water sorption and solubility (ISO 4049) and thermal expansion coefficient (dilatometer) were determined. The test results were statistically analysed using one-way ANOVA (p < 0.05). Depth of cure increased by 41%, volumetric shrinkage increased by 8.3%, shrinkage stress increased by 37.6%, exotherm increased by 20.2%, and thermal expansion reduced by 6.4% while water sorption and solubility had a negligible effect with the inclusion of short glass fibres. The study demonstrates that within the same organic resin system and quantity, a small replacement of fillers with short fibres could significantly affect the dimensional stability of the composite system. In conjunction with mechanical properties, this study could help clinicians to gain confidence in fibre reinforced dental composite restorative system.

Post-gel polymerisation shrinkage profiling of polymer biomaterials using a chirped fibre Bragg grating.

A strain profile measurement technique using a chirped fibre Bragg grating (CFBG) sensor by implementing an integration of differences (IOD) method is reported in this paper. Using the IOD method the spatial distribution of strain along the length of the CFBG is extracted from its power reflectance spectra. As a proof of concept demonstration, the developed technique is applied to measure the polymerisation shrinkage strain profile of a photo-cured polymer dental composite which exhibits a non-uniform strain distribution attributed to the curing lamp characteristics. The result from the CFBG technique is compared with that of an FBG array embedded in the dental composite and is correlated with the degree of conversion of the material which also depends on the curing lamp intensity distribution. This technology will have significant impact and applications in a range of medical, materials and engineering areas where strain or temperature gradient profile measurement is required in smaller scales.

Evaluation of rheological behaviour of flowable dental composites reinforced with low aspect ratio micro-sized glass fibres.

OBJECTIVE: Experimental investigation is carried out to determine the flowability and stickiness of the developed composite material for dental restoration containing low aspect ratio (AR ≤ 100) surface treated micro-sized glass fibres. METHODS: Specimens are manufactured by mixing low AR (50/70/100) micro-sized glass fibres with two different weight fractions (5%/10%) into UDMA/TEGDMA based resin. Particulate filler composite (PFC) containing 55% glass fillers is used as the control group. Dynamic oscillatory strain sweep tests are conducted to analyse the linear viscoelastic behaviour. Solid-to fluidic transition behaviour of dental composites is also calculated in terms of flow and yield stresses. Furthermore, the oscillatory frequency sweep tests are conducted at three different strains (0.5%, 5% and 50%) resembling the positioning of unset paste onto restorations for different real-life clinical situations. Additionally, stickiness of dental composites with handling instrument (steel) and dentine covered with bonding agent is also evaluated. RESULTS: The results suggested the all the FRC groups exhibited non-Newtonian, shear-thinning behaviour. It is further established that inclusion of 5% of 50/70AR fibres into dental composites does not affect the flowability. Simultaneously, stickiness with dentine covered with bonding agent is more for these two compositions as compared to that of handling instrument (steel). SIGNIFICANCE: This study suggest that visco-elastic properties of dental composites are greatly affected by the type of filler (spherical shaped particulate fillers or rod-shaped fibres) as well as fibre weight fraction/fibre AR. This phenomenon can be attributed to the varying interactions between micro-sized fibres of different AR/weight fraction, particulate fillers and monomers.

Influence of Surface Treatment on the Interfacial and Mechanical Properties of Short S-Glass Fiber-Reinforced Dental Composites.

The influence of interfacial shear strength (IFSS) between processed short S-glass fibers (250 and 350 µm in length, 5 µm in diameter) and the dental resin (a mixture of urethane dimethacrylate and triethylene glycol dimethacrylate monomers) on the mechanical properties has been studied experimentally. The surface profile of short S-glass fibers was modified using a selective atomic level metal etching process and simple silanization process to enhance the interfacial properties. The S-glass fibers were etched in acid solutions to increase the surface roughness and selectively remove Al3+ and Mg2+ ions, which promoted the mechanical and chemical interfacial bonding reactions. The single glass fiber tensile and microdroplet pull-out tests were performed to investigate the effects of interfacial properties on the flexural strength of the resultant composites. The surface modified S-glass fibers showed an increase of 11-40% in IFSS compared to untreated glass fibers. Composites reinforced with 350 µm length glass fibers (AR-70), which were treated in piranha solution for 4 h, showed the highest improvement in overall mechanical properties, flexural strength (34.2%), modulus (9.7%), and breaking energy (51.9%), compared to the untreated fiber-reinforced composites. The modified Lewis-Nielsen equation was developed using the effective fiber length factor to accurately predict the modulus of the short fiber-reinforced composites and validated with experimental results.

Selective Atomic-Level Etching on Short S-Glass Fibres to Control Interfacial Properties for Restorative Dental Composites.

Interfacial bonding between fibre and matrix is most critical to obtain enhanced mechanical properties of the resulting composites. Here we present a new surface tailoring method of selective wet etching and organosilicon monomers (3-(Trimethoxysilyl) propyl methacrylate, TMSPMA) deposition process on the short S-Glass fibre as a reinforcing material, resulting in increased mechanical retention and strong chemical bonding between glass fibres and polymer resin (a mixture of triethylene glycol dimethacrylate (TEGDMA) and urethane dimethacrylate (UDMA) monomers). The effect of surface modification on fibre matrix interfacial strength was investigated through microdroplet tests. An S-Glass fibre treated with piranha solution (a mixture of H2O2 and H2SO4) for 24 hours followed by TMSPMA surface silanization shows highest increase up to 39.6% in interfacial shear strength (IFSS), and critical fibre length could be reduced from 916.0 µm to 432.5 µm. We find the optimal surface treatment condition in that the flexural strength of dental composites reinforced by the S-Glass fibres enhanced up to 22.3% compared to the composites without fibre surface treatments. The significant elevation in strength is attributed to changes in the surface roughness of glass fibres at atomic scale, specifically by providing the multiplied spots of the chemical bridge and nano-mechanical interlocking. The findings offer a new strategy for advanced tailoring of short S-Glass fibres to maximise the mechanical properties of biomedical and dental composites.

Polymerisation Shrinkage Profiling of Dental Composites using Optical Fibre Sensing and their Correlation with Degree of Conversion and Curing Rate.

Traditional polymerisation shrinkage (PS) measurement systems measure average PS of dental composites, but the true local PS varies along the length and breadth of the composite. The PS depends on the curing light intensity distribution, resultant degree of conversion (DOC) and the curing rate. In this paper, optical fibre Bragg grating (FBG) sensing based technology is used to measure the linear post-gel PS at multiple locations within dental composite specimens, and is correlated with DOC and curing rate. A commercial dental composite is used, and its post-gel PS and DOC are mapped using embedded fibre Bragg grating sensors at different curing conditions. The distance between the curing lamp and the composite specimen is varied which resulted in different intensity distribution across the specimen. The effect of curing light intensity distribution on PS, curing rate and DOC are investigated for demonstrating a relationship among them. It is demonstrated that FBG sensing method is an effective method to accurately profiling post-gel PS across the specimen.