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1.
J Environ Manage ; 359: 121109, 2024 May.
Artigo em Inglês | MEDLINE | ID: mdl-38723500

RESUMO

The impact of climate change on water availability and quality has affected agricultural irrigation. The use of treated wastewater can alleviate water in agriculture. Nevertheless, it is imperative to ensure proper treatment of wastewater before reuse, in compliance with current regulations of this practice. In decentralized agricultural scenarios, the lack of adequate treatment facilities poses a challenge in providing treated wastewater for irrigation. Hence, there is a critical need to develop and implement innovative, feasible, and sustainable treatment solutions to secure the use of this alternative water source. This study proposes the integration of intensive treatment solutions and natural treatment systems, specifically, the combination of up-flow anaerobic sludge blanket reactor (UASB), anaerobic membrane bioreactor (AnMBR), constructed wetlands (CWs), and ultraviolet (UV) disinfection. For this purpose, a novel demo-scale plant was designed, constructed and implemented to test wastewater treatment and evaluate the capability of the proposed system to provide an effluent with a quality in compliance with the current European wastewater reuse regulatory framework. In addition, carbon-sequestration and energy analyses were conducted to assess the sustainability of the proposed treatment approach. This research confirmed that UASB rector can be employed for biogas production (2.5 L h-1) and energy recovery from organic matter degradation, but its effluent requires further treatment steps to be reused in agricultural irrigation. The AnMBR effluent complied with class A standards for E. coli, boasting a concentration of 0 CFU 100 mL-1, and nearly negligible TSS levels. However, further reduction of BOD5 (35 mg L-1) is required to reach water quality class A. CWs efficiently produced effluent with BOD5 below 10 mg L-1 and TSS close to 0 mg L-1, making it suitable for water reuse and meeting class A standards. Furthermore, CWs demonstrated significantly higher energy efficiency compared to intensive treatment systems. Nonetheless, the inclusion of a UV disinfection unit after CWs was required to attain water class B standards.


Assuntos
Reatores Biológicos , Esgotos , Eliminação de Resíduos Líquidos , Águas Residuárias , Áreas Alagadas , Anaerobiose , Eliminação de Resíduos Líquidos/métodos , Agricultura , Carbono
2.
J Environ Manage ; 355: 120214, 2024 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-38422843

RESUMO

Specific flood volume is an important criterion for evaluating the performance of sewer networks. Currently, mechanistic models - MCMs (e.g., SWMM) are usually used for its prediction, but they require the collection of detailed information about the characteristics of the catchment and sewer network, which can be difficult to obtain, and the process of model calibration is a complex task. This paper presents a methodology for developing simulators to predict specific flood volume using machine learning methods (DNN - Deep Neural Network, GAM - Generalized Additive Model). The results of Sobol index calculations using the GSA method were used to select the ML model as an alternative to the MCM model. It was shown that the DNN model can be used for flood prediction, for which high agreement was obtained between the results of GSA calculations for rainfall data, catchment and sewer network characteristics, and calibrated SWMM parameters describing land use and sewer retention. Regression relationships (polynomials and exponential functions) were determined between Sobol indices (retention depth of impervious area, correction factor of impervious area, Manning's roughness coefficient of sewers) and sewer network characteristics (unit density of sewers, retention factor - the downstream and upstream of retention ratio) obtaining R2 = 0. 55-0.78. The feasibility of predicting sewer network flooding and modernization with the DNN model using a limited range of input data compared to the SWMM was shown. The developed model can be applied to the management of urban catchments with limited access to data and at the stage of urban planning.


Assuntos
Inundações , Modelos Teóricos , Algoritmos , Redes Neurais de Computação , Planejamento de Cidades , Chuva , Cidades , Movimentos da Água
3.
Water Res ; 238: 120030, 2023 Jun 30.
Artigo em Inglês | MEDLINE | ID: mdl-37150063

RESUMO

Polyethylene (PE) pipes have been widely used in drinking water distribution systems across the world. In many cases, chlorine dioxide (ClO2) is used to maintain a residual disinfectant concentration in potable water. Practical experiences have shown that the lifetime of PE pipes is significantly reduced due to exposure to drinking water with ClO2. Recently, many companies have proposed new PE pipes with a modified formulation, which are more resistant to chlorine dioxide. However, a standardized test method for evaluating the long-term performances of PE pipes is still missing. This literature review was performed to provide a description of chlorine dioxide uses and degradation mechanisms of polyethylene pipes in real water distribution systems. Current accelerated aging methods to evaluate long-term performances of PE pipes exposed to ClO2 are described and discussed along with the common technics used to characterize the specimens. Accelerate aging methods can be distinguished in immersion aging tests and pressurized pipe loop tests. Wide ranges of operational conditions (chlorine dioxide concentration, water pressure, water temperature, etc.) are applied, resulting in a great variety of results. It was concluded that pressurized looping tests applying semi-realistic operational conditions could better replicate the aging mechanisms occurring in service. Despite this, the acceleration and the evaluation of the long-term performance are still difficult to determine precisely. Further experimentation is needed to correlate chemical-mechanical characterization parameters of PE pipes with their lifetime in service.


Assuntos
Compostos Clorados , Desinfetantes , Água Potável , Purificação da Água , Polietileno , Abastecimento de Água , Óxidos , Cloro , Purificação da Água/métodos , Desinfecção
4.
PLoS One ; 17(11): e0276312, 2022.
Artigo em Inglês | MEDLINE | ID: mdl-36327282

RESUMO

An original method for analyzing the influence of the meteorological, as well as physical-geographical conditions on the flooding of stormwater in small urban catchment areas is proposed. A logistical regression model is employed for the identification of the flooding events. The elaborated model enables to simulate the stormwater flooding in a single rainfall event, on the basis of the rainfall depth, duration, imperviousness of the catchment and its spatial distribution within the analyzed area, as well as the density of the stormwater network. The rainfall events are predicted considering the regional convective rainfall model for 32 rain gauges located in Poland, based on 44 years of rainfall data. In the study, empirical models are obtained to calculate the rainfall duration conditioning the flooding of stormwater in a small urban catchment area depending on the characteristics of the examined urban basins. The empirical models enabling to control the urbanization process of catchment areas, accounting for the local rainfall and meteorological characteristics are provided. The paper proposes a methodology for the identification of the areas especially sensitive to stormwater flooding in small urban catchment areas depending to the country scale. By employing the presented methodology, the regions with most sensitive urban catchments are identified. On this basis, a ranking of towns and cities is determined from the most sensitive to flooding in small urban catchment areas to the regions where the risk of flooding is lower. Using the method developed in the paper, maximum impervious catchment area are determined for the selected regions of the country, the exceedance of which determines the occurrence of stormwater flooding.


Assuntos
Inundações , Movimentos da Água , Chuva , Cidades , Urbanização , Modelos Teóricos
5.
Environ Technol ; : 1-14, 2022 Jul 18.
Artigo em Inglês | MEDLINE | ID: mdl-35794016

RESUMO

One of the most recent innovations to promote a circular economy during wastewater treatment is the production of biopolymers. It has recently been demonstrated that it is possible to integrate the production of biopolymers in the form of polyhydroxyalkanoates (PHA) with nitrogen removal via nitrite during the treatment of sludge reject water. In the present study, simulation of a new process for bioresource recovery was conducted by an appropriate modification of the Activated Sludge Model 3. The process consists of the integrated nitrogen removal via nitrite from sludge reject water and the selection of PHA-storing biomass by inducing a feast and famine regime under aerobic and anoxic conditions. According to the results, it is anticipated that simulation data matched very satisfactorily with the experimental data and confirmed the main experimental observation, showing that during the famine period the PHA depletion was almost complete due to the availability of nitrite as the electron acceptor. Simulation results indicate that the selection of the volumetric organic loading rate and of the relative duration of the aerobic feast/anoxic famine duration is critical in order to allow for the effective denitritation of the internally stored PHA during the famine phase.

6.
Water Res ; 207: 117831, 2021 Dec 01.
Artigo em Inglês | MEDLINE | ID: mdl-34798451

RESUMO

In this paper, a new regional methodological approach for determining direct and indirect emissions from wastewater treatment plants (WWTPs) is proposed. Additionally, an entire territorial wastewater treatment service located in the northern Italy and serving 411,484 PE was assessed. The most accurate emission factor identification is presented using appropriate on-site measurements, monitoring different aerated operational units and sampling several streams in 12 relevant WWTPs of different treatment capacities, ranging from 3000 to 73,000 PE. Dissolved greenhouse gas (GHG) concentrations from 0.2 to 24 mgN2O/L, 0.1 to 1 mgCH4/L and 1.8 to 52 mgCO2/L in effluent flows were detected. Specific carbon footprints resulted in the emissions of 0.04-0.20 tonCO2eq/PE/y, varying as per the size of the plants. The most impactful categories were identified for indirect emissions, associated with dissolved GHGs discharged in the surface water body and due to energy consumption, which accounted for 13-70% and 10-40%, respectively. The overall territorial carbon footprint of the wastewater treatment service was also quantified to provide evidence-based decision support system (DSS) and prepare systemic mitigation strategies.


Assuntos
Gases de Efeito Estufa , Purificação da Água , Pegada de Carbono , Efeito Estufa , Gases de Efeito Estufa/análise , Itália
7.
J Environ Manage ; 300: 113681, 2021 Dec 15.
Artigo em Inglês | MEDLINE | ID: mdl-34521009

RESUMO

In the framework of minimum liquid discharge (MLD) or zero liquid discharge (ZLD), sustainable brine management can be achieved via appropriate hybrid treatment technologies that provide water reuse, resource recovery, energy recovery and even freshwater production. This paper reviews the state of the art brine treatment technologies targeting MLD/ZLD and resource recovery and highlights their advantages and limitations. The right combination of treatment processes can add a high value to the brine management and shift the focus from removal to recovery and reuse point and help to adopt a more circular economy approach. ZLD technologies targets 100% water recovery using both membrane- and thermal-based technologies, while they are often hindered by high cost and intensive energy requirement. Meanwhile, the recovery of salts and other resources can partially compensate the operation cost of ZLD processes. MLD is a promising option that achieves up to 95% water recovery by using mainly membrane-based technologies. At this point, feasibility assessment is important to assess the environmental and economic sound of technologies. In the second part, we provide a techno-economic assessment of the most common technologies to provide possible benefits on a desalination plant. In the latter sections, innovative brine treatment schemes are discussed aiming MLD/ZLD, while resource recovery from brine and possible valorization routes of the recovered materials are highlighted to help to reduce the overall costs of the plants and to reach the targets of circular economy.


Assuntos
Sais , Purificação da Água , Tecnologia , Água
8.
Environ Pollut ; 286: 117535, 2021 Oct 01.
Artigo em Inglês | MEDLINE | ID: mdl-34119863

RESUMO

The water intake of a drinking water treatment plant (DWTP) in Central Italy was monitored over six bloom seasons for cyanotoxin severity, which supplies drinking water from an oligo-mesotrophic lake with microcystin levels up to 10.3 µg/L. The historical data showed that the water temperature did not show extreme/large seasonal variation and it was not correlated either with cyanobacterial growth or microcystin concentration. Among all parameters, the cyanobacteria growth was negatively correlated with humidity and manganese and positively correlated with atmospheric temperature. No significant correlation was found between microcystin concentration and the climatic parameters. Polymer(chitosan)-enhanced microfiltration (PEMF) and ultrafiltration (PEUF) were further tested as an alternative microcystin removal approach from dense cyanobacteria-rich flows. The dominant cyanobacteria in the water intake, Planktothrix rubescens, was isolated and enriched to simulate cyanobacterial blooms in the lake. The PEMF and PEUF were separately applied to enriched P. rubescens culture (PC) (microcystin = 1.236 µg/L) as well as to the sand filter backwash water (SFBW) of the DWTP where microcystin concentration was higher than 12 µg/L. The overall microcystin removal rates from the final effluent of PC (always <0.15 µg/L) were between 90.1-94.7% and 89.5-95.4% using 4 and 20 mg chitosan/L, respectively. Meanwhile, after the PEMF and PEUF of SFBW, the final effluent contained only 0.099 and 0.057 µg microcystin/L with an overall removal >99%. The presented results are the first from the application of chitosan to remove P. rubescens as well as the implementation of PEMF and PEUF on SFBW to remove cyanobacterial cells and associated toxins.


Assuntos
Cianobactérias , Água Potável , Monitoramento Ambiental , Itália , Microcistinas/análise , Polímeros , Ultrafiltração
9.
ACS Sustain Chem Eng ; 9(28): 9455-9464, 2021 Jul 19.
Artigo em Inglês | MEDLINE | ID: mdl-35059238

RESUMO

Polyhydroxyalkanoates (PHAs) are versatile biodegradable polymers produced by bacteria and are suitable for many downstream applications. They can be produced inexpensively from mixed microbial cultures under feast and famine conditions in the presence of biobased volatile fatty acids (VFAs). Here, we investigated the effect of changing the sludge retention time (SRT) and the addition of fermented cellulosic primary sludge (CPS) as a carbon source on the selection of PHA-storing biomass when applying the feast and famine strategy under aerobic and anoxic conditions, respectively. Increasing the SRT from 5 to 7-10 days enhanced PHA yields under feast conditions from 0.18 gCODPHA/gCODVFA (period 1) to 0.40 gCODPHA/gCODVFA (period 2). The use of fermented CPS as a carbon source (period 3) increased PHA yields to 0.62 gCODPHA/gCODVFA despite the presence of biodegradable non-VFA fractions. Microbial characterization by denaturing gradient gel electrophoresis and fluorescence in situ hybridization revealed high microbial speciation during the three experimental periods. In period 3, the dominant genera were Thauera, Paracoccus, and Azoarcus, which accounted for ∼95% of the total microbial biomass.

10.
Environ Res ; 196: 110367, 2021 05.
Artigo em Inglês | MEDLINE | ID: mdl-33131711

RESUMO

The first phase of this study aimed to evaluate the environmental impact of combined sewer overflow (CSO) events originated from 35 spillways on the Rio Vallescura catchment (Central Italy) and to understand their contribution to the deterioration of the coastal bathing water quality. A specific analytical campaign was carried out in the sewer system and a dynamic rainfall-runoff simulation model was developed and integrated with a water quality model and further validated. The simulations led to identify the most critical spills in terms of flow rate and selected pollutant loads (i.e. suspended solids, biochemical oxygen demand, chemical oxygen demand, total Kjeldahl nitrogen, Escherichia coli). Specifically, the E. coli release in the water body due to CSO events represented almost 100% of the different pollutant sources considered. In the second phase, the applicability of various disinfection methods was investigated on the CSOs introduced into the catchment. On site physical (UV) and lab-scale chemical (peracetic acid (PAA), performic acid (PFA), ozone) disinfectant agents were tested on microbial indicators including E. coli and intestinal enterococci. PFA and ozone were more effective on the removal of both bacteria (above 3.5 log units) even at low concentration and with short contact time; whereas, PAA showed a moderate removal efficiency (around 2.5 log units) only for E. coli. The highest removal efficiency was achieved in the on-site UV unit and none of the indicator bacteria was detected in the final effluent after the sand filtration and UV treatment. Finally, potential scenarios were developed in comparison to the baseline scenario for the management and treatment of CSOs where a mitigation of E. coli loads from 28% to 73% was achieved on the receiving water body, and a comparative cost assessment of the disinfection methods was provided for in situ treatment of the most critical spillway.


Assuntos
Desinfetantes , Desinfecção , Escherichia coli , Itália , Esgotos , Qualidade da Água
11.
Chemosphere ; 262: 128415, 2021 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-33182128

RESUMO

The occurrence, fate and removal of microplastics (MPs) in a wastewater treatment plant (WWTP) in Central Italy were investigated together with their potential adverse effects on anaerobic processes. In the influent of the WWTP, 3.6 MPs.L-1 were detected that mostly comprised polyester fibers and particles in the shape of films, ranging 0.1-0.5 mm and made of polyethylene and polypropylene (PP). The full-scale conventional activated sludge scheme removed 86% of MPs, with the main reduction in the primary and secondary settling. MPs particles bigger than 1 mm were not detected in the final effluent and some loss of polymers types were observed. In comparison, the pilot-scale upflow granular anaerobic sludge blanket (UASB) + anaerobic membrane bioreactor (AnMBR) configuration achieved 94% MPs removal with the abatement of 87% of fibers and 100% of particles. The results highlighted an accumulation phenomenon of MPs in the sludge and suggested the need to further investigate the effects of MPs on anaerobic processes. Accordingly, PP-MPs at concentrations from 5 PP-MPs.gTS-1 to 50 PP-MPs.gTS-1 were spiked in the pilot-scale UASB reactor that was fed with real municipal wastewater, where up to 58% decrease in methanogenic activity was observed at the exposure of 50 PP-MPs.gTS-1. To the best of our knowledge, the presented results are the first to report of PP-MPs inhibition on anaerobic processes.


Assuntos
Eliminação de Resíduos Líquidos/métodos , Anaerobiose , Reatores Biológicos , Itália , Microplásticos , Plásticos , Polietileno , Esgotos , Águas Residuárias
13.
Sensors (Basel) ; 20(7)2020 Mar 30.
Artigo em Inglês | MEDLINE | ID: mdl-32235669

RESUMO

The paper presented the methodology for the construction of a soft sensor used for activated sludge bulking identification. Devising such solutions fits within the current trends and development of a smart system and infrastructure within smart cities. In order to optimize the selection of the data-mining method depending on the data collected within a wastewater treatment plant (WWTP), a number of methods were considered, including: artificial neural networks, support vector machines, random forests, boosted trees, and logistic regression. The analysis conducted sought the combinations of independent variables for which the devised soft sensor is characterized with high accuracy and at a relatively low cost of determination. With the measurement results pertaining to the quantity and quality of wastewater as well as the temperature in the activated sludge chambers, a good fit can be achieved with the boosted trees method. In order to simplify the selection of an optimal method for the identification of activated sludge bulking depending on the model requirements and the data collected within the WWTP, an original system of weight estimation was proposed, enabling a reduction in the number of independent variables in a model-quantity and quality of wastewater, operational parameters, and the cost of conducting measurements.

14.
Water Res ; 174: 115633, 2020 May 01.
Artigo em Inglês | MEDLINE | ID: mdl-32109752

RESUMO

This study combined at pilot scale the recovery of cellulosic primary sludge from the sieving of municipal wastewater followed by the production of bio-based VFAs through acidogenic fermentation. The sieving of municipal wastewater was accomplished by a rotating belt filter which allowed the removal of around 50% of suspended solids when operated at solids loading rates higher than 30-35 kgTSS/m2 h. The solids recovered by sieving contained around 40% of cellulose, which is a suitable raw material for the production of bio-based VFAs. Initially, fermentation batch tests of cellulosic primary sludge were carried out adjusting the initial pH of the sludge at values of 8, 9, 10 and 11, in order to evaluate the best production yields of bio-based VFAs and their composition. The highest VFAs yield achieved was 521 mgCODVFA/gVS occurring when pH was adjusted at 9, while propionic acid reached 51% of the total VFAs. Then, the optimal conditions were applied at long term in a sequencing batch fermentation reactor where the highest potential productivity of bio-based VFAs (2.57 kg COD/m3 d) was obtained by adjusting the pH feeding at 9 and operating with an hydraulic retention time of 6 days under mesophilic conditions. The cost-benefit analyses for the implementation of cellulosic primary sludge recovery was carried out consideringthe anaerobic digestion as reference scenario. The economical assessment showed that the production of bio-based VFAs from cellulosic primary sludge as carbon source and/or as chemical precursors give higher net benefits instead of the only biogas production.


Assuntos
Reatores Biológicos , Águas Residuárias , Ácidos Graxos Voláteis , Fermentação , Esgotos
15.
Waste Manag ; 100: 208-218, 2019 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-31546181

RESUMO

The recovery of cellulose in toilet paper from municipal wastewater is one of the most innovative actions in the circular economy context. In fact, fibres could address possible new uses in the building sector as reinforcing components in binder-based materials. In this paper, rotating belt filters were tested to enhance the recovery of sludge rich in cellulose fibres for possible valorisation in construction applications. Recovered cellulosic material reached value up to 26.6 gm-3 with maximum solids removal of 74%. Content of cellulose, hemicellulose and lignin was found averagely equal to 87% of the total composition. Predictive equation of cellulosic material was further obtained. The addition of recovered cellulose fibres in mortars bring benefits in terms of lightness, microstructure and moisture buffering value (0.17 g/m2%UR). Concerning mechanical properties, flexural strength was improved with the addition of 20% of recovered cellulose fibres. In addition, a simplified economic assessment was reported for two possible pre-mixed blends with 5% and 20% of recovered fibres content.


Assuntos
Celulose , Esgotos , Materiais de Construção , Lignina , Águas Residuárias
16.
Sci Total Environ ; 634: 127-140, 2018 Sep 01.
Artigo em Inglês | MEDLINE | ID: mdl-29627535

RESUMO

The aim of this study was to compare the environmental performance and sustainability of different management options for livestock waste in Cyprus. The two most common practices in the country, i.e. the use of anaerobic lagoons and conventional biogas plants, were compared with the innovative scheme developed in the LiveWaste project (LIFE12 ENV/CY/000544), which aims not only to produce bioenergy, but also to treat the digestate for nutrient recovery and water reuse. The Life Cycle Assessment (LCA) methodology was combined with the Analytic Hierarchy Process (AHP) to compare the performance of these alternatives. Four relevant indicators were selected for each dimension of sustainability (environmental, social and economic). The results of the evaluations showed that anaerobic lagoons are not an appropriate option for the sustainable management of livestock waste due to environmental (e.g. climate change, acidification and eutrophication) and social impacts (e.g. noise exposure, visual impact and risk perception for human health). The most important strengths and weaknesses of anaerobic treatment with and without digestate treatment were identified. Compared to conventional anaerobic digestion where digestate is directly applied as an organic fertiliser, the technology proposed in the project entails higher technological complexity due to nitrogen removal and phosphorus recovery. The rise in chemical and electricity requirements increased the impacts on some indicators, such as climate change and operational cost (emissions of greenhouse gases and operation costs were around 50% higher), while reduced impacts in others due to proper nutrient management, as acidification and eutrophication impacts (which were 10 and almost two times lower, respectively). For the specific Cypriot conditions, where the overapplication of nutrients leads to pollution of water bodies, the innovative treatment scheme with higher technological development presents an interesting approach. Nevertheless, the treatment of the digestate should be analysed taking into account the specific characteristics of each scenario.


Assuntos
Criação de Animais Domésticos/métodos , Conservação dos Recursos Naturais/métodos , Esterco/análise , Gerenciamento de Resíduos/métodos , Animais , Chipre , Gado
17.
Water Res ; 136: 112-119, 2018 06 01.
Artigo em Inglês | MEDLINE | ID: mdl-29500972

RESUMO

Cellulose from used toilet paper is a major untapped resource embedded in municipal wastewater which recovery and valorization to valuable products can be optimized. Cellulosic primary sludge (CPS) can be separated by upstream dynamic sieving and anaerobically digested to recover methane as much as 4.02 m3/capita·year. On the other hand, optimal acidogenic fermenting conditions of CPS allows the production of targeted short-chain fatty acids (SCFAs) as much as 2.92 kg COD/capita·year. Here propionate content can be more than 30% and can optimize the enhanced biological phosphorus removal (EBPR) processes or the higher valuable co-polymer of polyhydroxyalkanoates (PHAs). In this work, first a full set of batch assays were used at three different temperatures (37, 55 and 70 °C) and three different initial pH (8, 9 and 10) to identify the best conditions for optimizing both the total SCFAs and propionate content from CPS fermentation. Then, the optimal conditions were applied in long term to a Sequencing Batch Fermentation Reactor where the highest propionate production (100-120 mg COD/g TVSfed·d) was obtained at 37 °C and adjusting the feeding pH at 8. This was attributed to the higher hydrolysis efficiency of the cellulosic materials (up to 44%), which increased the selective growth of Propionibacterium acidopropionici in the fermentation broth up to 34%. At the same time, around 88% of the phosphorus released during the acidogenic fermentation was recovered as much as 0.15 kg of struvite per capita·year. Finally, the potential market value was preliminary estimated for the recovered materials that can triple over the conventional scenario of biogas recovery in existing municipal wastewater treatment plants.


Assuntos
Celulose/metabolismo , Ácidos Graxos Voláteis/metabolismo , Metano/metabolismo , Fósforo/metabolismo , Esgotos/química , Anaerobiose , Biodegradação Ambiental , Reatores Biológicos/microbiologia , Ácidos Graxos Voláteis/isolamento & purificação , Fermentação , Hidrólise , Metano/isolamento & purificação , Fósforo/isolamento & purificação , Propionibacterium/metabolismo , Águas Residuárias/química
18.
Water Res ; 125: 478-489, 2017 11 15.
Artigo em Inglês | MEDLINE | ID: mdl-28910743

RESUMO

The environmental and economic benefits and burdens of including the first Short Cut Enhanced Nutrient Abatement (SCENA) into a real municipal wastewater treatment plant were evaluated using life cycle assessment (LCA) and life cycle cost (LCC). The implications of accomplishing nitrogen (N) removal and phosphorus (P) recovery via nitrite in the side stream were assessed taking into account the actual effluent quality improvement, the changes in the electricity and chemical consumption, N2O, CO2 and CH4 emissions and the effects of land application of biosolids, among others. In addition, a case-specific estimation of the P availability when sludge is applied to land, therefore replacing conventional fertilizer, was performed. Furthermore, to account for the variability in input parameters, and to address the related uncertainties, Monte Carlo simulation was applied. The analysis revealed that SCENA in the side stream is an economic and environmentally friendly solution compared to the traditional plant layout with no side-stream treatment, thanks to the reduction of energy and chemical use for the removal of N and P, respectively. The uncertainty analysis proved the validity of the LCA results for global warming potential and impact categories related to the consumption of fossil-based electricity and chemicals, while robust conclusions could not be drawn on freshwater eutrophication and toxicity-related impact categories. Furthermore, three optimization scenarios were also evaluated proving that the performance of the WWTP can be further improved by, for instance, substituting gravitational for mechanical thickening of the sludge or changing the operational strategy to the chemically enhanced primary treatment, although this second alternative will increase the operational cost by 5%. Finally, the outcomes show that shifting P removal from chemical precipitation in the main line to biologically enhanced uptake in the side stream is key to reducing chemicals use, thus the operational cost, and increasing the environmental benefit of synthetic fertilizers replacement.


Assuntos
Nitrogênio/isolamento & purificação , Fósforo/isolamento & purificação , Esgotos/análise , Eliminação de Resíduos Líquidos/métodos , Águas Residuárias/análise , Eutrofização , Fertilizantes , Aquecimento Global , Reciclagem , Eliminação de Resíduos Líquidos/economia
19.
Water Res ; 109: 173-185, 2017 Feb 01.
Artigo em Inglês | MEDLINE | ID: mdl-27883922

RESUMO

A technical and environmental evaluation of an innovative scheme for the co-treatment of domestic wastewater and domestic organic waste (DOW) was undertaken by coupling an upflow anaerobic sludge blanket (UASB), a sequencing batch reactor (SBR) and a fermentation reactor. Alternative treatment configurations were evaluated with different waste collection practices as well as various schemes for nitrogen and phosphorus removal. All treatment systems fulfilled the required quality of the treated effluent in terms of chemical oxygen demand (COD) and total suspended solids (TSS) concentrations. However, only the configurations performing the short-cut nitrification/denitrification with biological phosphorus removal met the specifications for water reuse. The environmental assessment included the analysis of impacts on climate change (CC), freshwater eutrophication (FE) and marine eutrophication (ME). A functional unit (FU) of 2000 people receiving treatment services was considered. The most relevant sources of environmental impacts were associated to the concentration of dissolved methane in the UASB effluent that is emitted to the atmosphere in the SBR process (accounting for 41% of impacts in CC), electricity consumption, mainly for aeration in the SBR (representing 14% of the impacts produced in CC), and the discharge of the treated effluent in receiving waters (contributing 98% and 57% of impacts in FE and ME, respectively). The scheme of separate waste collection together with biological nitrogen removal and phosphorus uptake via nitrite was identified as the best configuration, with good treated effluent quality and environmental impacts lower than those of the other examined configurations.


Assuntos
Eliminação de Resíduos Líquidos , Águas Residuárias , Reatores Biológicos , Mudança Climática , Nitrogênio , Esgotos
20.
J Environ Manage ; 203(Pt 2): 732-740, 2017 Dec 01.
Artigo em Inglês | MEDLINE | ID: mdl-28011015

RESUMO

This study assesses from an environmental perspective two different configurations for the combined treatment of wastewater and domestic organic waste (DOW) in a small and decentralised community having a population of 2000. The applied schemes consist of an upflow anaerobic blanket (UASB) as core treatment process. Scheme A integrates membranes with the anaerobic treatment; while in Scheme B biological removal of nutrients in a sequencing batch reactor (SBR) is applied as a post treatment to UASB effluent. In energy-related categories, the main contributor is electricity consumption (producing 18-50% of the impacts); whereas in terms of eutrophication-related categories, the discharge of the treated effluent arises as a major hotspot (with 57-99% of the impacts). Scheme B consumes 25% more electricity and produces 40% extra sludge than Scheme A, resulting in worse environmental results for those energy categories. However, the environmental impact due to the discharge of the treated effluent is 75% lower in eutrophication categories due to the removal of nutrients. In addition, the quality of the final effluent in Scheme B would allow its use for irrigation (9.6 mg N/L and 2 mg P/L) if proper tertiary treatment and disinfection are provided, expanding its potential adoption at a wider scale. Direct emissions due to the dissolved methane in the UASB effluent have a significant environmental impact in climate change (23-26%). Additionally, the study shows the environmental feasibility of the use of food waste disposers for DOW collection in different integration rates.


Assuntos
Mudança Climática , Eliminação de Resíduos Líquidos , Águas Residuárias , Anaerobiose , Reatores Biológicos , Esgotos
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