Highly stretchable and sensitive strain sensors with ginkgo-like sandwich architectures.

The development of a strain sensor that can detect tensile strains exceeding 800% has been challenging. The non-conductive stretchable Eco-flex tape has been widely used in strain sensors due to its high elastic limit. In this work, an Eco-flex-based strain sensor that was conductive until occurrence of fracture was developed. The silver nanoparticles and carbon nanotubes constituted stretchable conductive paths in the Eco-flex matrix. The maximum tensile strain of this sensor was 867%, and the resistance change rate was higher than 104, while the strain resolution was 7.9%. Moreover, the sensor is characterized by segmented logarithmic linearity. This excellent performance was attributed to the ginkgo-like pattern, the patterned strain-coordinating architecture (PSCL), and specific nanocomposites with micro-cracks. The deformation of the architecture and the evolution of the microcracks were studied. In addition, the application of this strain sensor on a wing-shaped aircraft was proposed and its feasibility was demonstrated.

Wearable Circuits Sintered at Room Temperature Directly on the Skin Surface for Health Monitoring.

A soft body area sensor network presents a promising direction in wearable devices to integrate on-body sensors for physiological signal monitoring and flexible printed circuit boards (FPCBs) for signal conditioning/readout and wireless transmission. However, its realization currently relies on various sophisticated fabrication approaches such as lithography or direct printing on a carrier substrate before attaching to the body. Here, we report a universal fabrication scheme to enable printing and room-temperature sintering of the metal nanoparticle on paper/fabric for FPCBs and directly on the human skin for on-body sensors with a novel sintering aid layer. Consisting of polyvinyl alcohol (PVA) paste and nanoadditives in the water, the sintering aid layer reduces the sintering temperature. Together with the significantly decreased surface roughness, it allows for the integration of a submicron-thick conductive pattern with enhanced electromechanical performance. Various on-body sensors integrated with an FPCB to detect health conditions illustrate a system-level example.

Low-temperature sintering of silver nanoparticles on paper by surface modification.

Ultralow-temperature sintering plays a vital role in the development of flexible printed electronics, which improves flexibility and reduces energy consumption. This study investigates the ultralow-temperature sintering of large-sized silver nanoparticles (Ag NPs) by laser modification of the substrate surface. Ag NPs in conductive ink were sintered at only 60 °C. Designing the appropriate size of modified regions, the sintered Ag layer exhibits a sheet resistance of only 0.274 Ω and withstands 10 000 folding cycles. Energy-dispersive x-ray spectroscopy showed that TiO2 formed by laser ablation promotes the sintering of Ag NPs and joining with the substrate. A paper-based flexible integrated circuit board was also prepared.

Highly stretchable patternable conductive circuits and wearable strain sensors based on polydimethylsiloxane and silver nanoparticles.

Patterned circuits on highly stretchable conductive films are critical in the practical application of next-generation flexible and wearable devices. Currently, most patterned circuits do not exhibit highly stretchable properties, and a lithography process in vacuum is required. In this study, silver nanoparticles (AgNPs) and liquid polydimethylsiloxane (PDMS) are mixed together to form liquid conductive adhesives (CAs). Various stretchable patterned circuits are prepared using this CA to achieve all required functions. Six basic patterns, including rhombus, straight lines, serpentine, triangle, ellipses, and fold line, are studied for their stretchable and electrical properties. The film is found to maintain excellent conductivity after withstanding tensile strain of up to 320% and more than 10 000 stretching-releasing cycles of 0%-150%. More than 86% of visible lights can be penetrated through the film due to the transparent substrates. Functional and wearable devices are manufactured, and devices fabricated from rhombus-pattern circuits are found to exhibit stable electrical conductivity when subjected to very high tensile strains. According to the sensitivity of the straight-line patterned circuit to strain, a repeatable use sensitive strain sensor is studied. Also, two types of artificial electrical skin are demonstrated.