Biodegradable microplastics aging processes accelerated by returning straw in paddy soil.

Biodegradable microplastics (MPs) have been released into agricultural soils and inevitably undergo various aging processes. Straw return is a popular agricultural management strategy in many countries. However, the effect of straw return on the aging process of biodegradable MPs in flooded paddy soil, which is crucial for studying the characteristics, fate, and environmental implications of biodegradable MPs, remains unclear. Here, we constructed a 180-day microcosm incubation to elucidate the aging mechanism of polylactic acid (PLA)-MPs in straw-enriched paddy soil. This study elucidated that the prominent aging characteristic of PLA-MPs occurred in the straw-enriched paddy soil, accompanied by increased chrominance (76.64-182.3 %), hydrophilicity (2.92-22.07 %), roughness (33.12-58.01 %), and biofilm formation (42.12-100.3 %) for the PLA-MPs, especially with 2 % (w/w) straw return treatment (P < 0.05). A 2 % straw return treatment has significantly impacted ester CO group changes in PLA-MPs, altered the MPs-attached soil bacterial communities composition, strengthened bacterial network structure, and increased soil proteinase K activity. The findings of this work demonstrated that flooded, straw-enriched paddy soil accelerated PLA-MPs aging affected by soil-water chemistry, soil microbe, and soil enzymatic. This study helps to deepen our understanding of the aging process of PLA-MPs in straw return paddy soil. ENVIRONMENTAL IMPLICATION: Microplastics (MPs) are emerging contaminants in the global soil and terrestrial ecosystems. Biodegradable MPs are more likely to be formed and released into agricultural soils during aging. Straw return is a popular agricultural management strategy in many countries. Considering the wide use of plastic film, sewage sludge, plastic-coated fertilizer, and organic fertilizer in agricultural ecosystems, it is crucial to pay attention to the aging process of biodegradable MPs in straw-enriched paddy soil, which has not been adequately emphasized. This aspect has been overlooked in previous studies and threatens ecosystems. This study demonstrated that straw-enriched paddy soil accelerated polylactic acid (PLA)-MPs aging influenced by the dissolved organic matter, microorganisms, and enzyme activity associated with straw decomposition.

Sustainable design of photo-Fenton-like oxidation process in actual livestock wastewater through the highly dispersed FeCl3 anchoring on a g-C3N4 substrate.

Photocatalytic technology emerges as a promising solution for the sustainable treatment of contaminated wastewater. However, the practical implementation of designed photocatalysts often faces challenges due to the intricate 'high carbon footprint' process and limited outdoor laboratory investigations. Herein, a simple yet versatile impregnation approach is proposed to anchor highly dispersed FeCl3 on a g-C3N4 substrate (Fe-C3N4) with minimal energy consumption and post-processing. Fe-C3N4 enhances photocatalytic reactivity for antibiotic degradation via a synergistic photo-Fenton-like oxidation technique, efficiently removing antibiotic pollutants from actual livestock wastewater. The Fe-C3N4 catalyst exhibited consistent degradation performance over five cycles in laboratory conditions, maintaining a degradation efficiency exceeding 90 % for tetracycline hydrochloride (TCHCl). Furthermore, we engineered a straightforward Fe-C3N4Na2SiO3 reactor for treating livestock wastewater, achieving an 81.8 % removal of TCHCl in outdoor field tests conducted in the winter and summer in China. The Fe-C3N4 catalyst demonstrated high feasibility in treating antibiotic-contaminated livestock wastewater under year-round climatic conditions, leveraging synergistic effects. The stabilization of Fe-C3N4 for the degradation of antibiotic-containing wastewater under sunlight represents a significant advancement in the practical application of photocatalysts, marking a crucial milestone from experimental conception to implementation. Acute toxicity estimation suggested that intermediates/products generated exhibited lower toxicity compared to TCHCl, indicating their practical applicability. Density functional theory (DFT) analysis successfully predicted significant electron transfer between Fe-C3N4 and TCHCl, indicating efficient interfacial interactions on the TCHCl surface. To ensure the environmental sustainability of Fe-C3N4, a life cycle assessment (LCA) was conducted to compared this photocatalyst with other commonly used emerging photocatalysts. The results demonstrated that Fe-C3N4 exhibits a two orders of magnitude lower CO2 equivalent emission compared to the ZnO photocatalyst, indicating a cost-effective and efficient synergistic photo-Fenton-like catalytic approach. This low-cost photocatalyst, moving from the laboratory to real-world wastewater applications, provides a powerful and more sustainable solution for the efficient treatment of wastewater containing antibiotics from livestock farming.

Knowledge graph and development hotspots of biochar as an emerging aquatic antibiotic remediator: A scientometric exploration based on VOSviewer and CiteSpace.

As an emerging material in the field of environmental remediation, biochar produced by carbonisation of organic solid waste has been widely used in the remediation of antibiotic wastewater due to its environmental friendliness and excellent adsorption properties. This study analyses the current literature in the field in a comprehensive and scientific manner using CiteSpace and VOSviewer technologies. Between 2011 and 2023, a total of 1162 papers were published in this domain, spanning three distinct stages: applied methods, mechanism investigation, and enhanced improvement. The results of keyword clustering indicate that the remediation of antibiotics complexed with multiple pollutants by biochar is the main research topic, followed by the remediation of antibiotics by biochar in combination with other technologies. Furthermore, drawing from current research hotspots in antibiotic remediation using biochar, this study identified the pivotal mechanisms involved: (1) The primary mechanisms by which raw biochar remediates antibiotics include π-π electron donor-acceptor interactions, hydrophobic interactions, electrostatic interactions, hydrogen-bonding, and pore filling. (2) Steam activation, acid/base, metal salt/metal oxide, and clay mineral modification can improve the physical/chemical properties of biochar, enhancing its adsorptive removal of antibiotics. (3) Biochar activated persulfate and degraded antibiotics via free radical pathways (SO4-•, •OH and O2-•) as well as non-free radical pathways (1O2 and electron transfer). In addition, the challenge and prospect of biochar engineering applications for antibiotic remediation lies in improving the main mechanism of antibiotic remediation by biochar. The prospective utilization of biochar in enhancing the remediation of antibiotic-related pollutants holds tremendous value for the future.

Unraveling the photochemical behavior of dissolved organic matter derived from hydrothermal carbonization process water: Insights from molecular transformation and photoactive species.

Hydrothermal carbonization process water (HTPW) has been utilized as a substitute for chemical fertilizers in agricultural applications. However, the input of HTPW into paddy water, particularly the significant proportion of dissolved organic matter (DOM) in HTPW (DOM-HTPW), directly engages in photochemical transformations, a phenomenon often overlooked. This study observed a consistent decrease in humification (SUVA280, 7.7-53.9%) and aromaticity (SUVA254, 6.1-40.0%) of DOM-HTPW after irradiation. The primary active photobleaching components of DOM-HTPW varied depending on the feedstock, such as protein for chicken manure DOM-HTPW and lignin for rice straw DOM-HTPW. The photochemical activity of DOM-HTPW was augmented by its lower molecular weight and higher hydrophilic composition, particularly evident in chicken manure DOM-HTPW, which exhibited higher generation rates for 1O2 (35.1-37.1%), 3DOM* (32.8-43.9%), and O2•- (28.6-48.8%) as measured by molecular probes. DOM-HTPW effectively facilitated the phototransformation of tetracycline, with the contribution of O2•- being more significant than 3DOM* and 1O2. These findings shed new light on the understanding the photochemical processes of DOM-HTPW as exogenous DOM and the interconnected fate of contaminants in aquatic environments.

Biochar and hydrochar application influence soil ammonia volatilization and the dissolved organic matter in salt-affected soils.

Biochar, which including pyrochar (PBC) and hydrochar (HBC), has been tested as a soil enhancer to improve saline soils. However, the effects of PBC and HBC application on ammonia (NH3) volatilization and dissolved organic matter (DOM) in saline paddy soils are poorly understood. In this research, marsh moss-derived PBC and HBC biochar types were applied to paddy saline soils at 0.5 % (w/w) and 1.5 % (w/w) rates to assess their impact on soil NH3 volatilization and DOM using a soil column experiment. The results revealed that soil NH3 volatilization significantly increased by 56.1 % in the treatment with 1.5 % (w/w) HBC compared to the control without PBC or HBC. Conversely, PBC and the lower application rate of HBC led to decrease in NH3 volatilization ranging from 2.4 % to 12.1 %. Floodwater EC is a dominant factor in NH3 emission. Furthermore, the fluorescence intensities of the four fractions (all humic substances) were found to be significantly higher in the 1.5 % (w/w) HBC treatment applied compared to the other treatments, as indicated by parallel factor analysis modeling. This study highlights the potential for soil NH3 losses and DOM leaching in saline paddy soils due to the high application rate of HBC. These findings offer valuable insights into the effects of PBC and HBC on rice paddy saline soil ecosystems.

Hydrochar and Its Dissolved Organic Matter Aged in a 30-Month Rice-Wheat Rotation System: Do Primary Aging Factors Alter at Different Stages?

Hydrochar, recognized as a green and sustainable soil amendment, has garnered significant attention. However, information on the aging process in soil and the temporal variability of hydrochar remains limited. This study delves deeper into the interaction between hydrochar and soil, focusing on primary factors influencing hydrochar aging during a 30-month rice-wheat rotation system. The results showed that the initial aging of hydrochar (0-16 months) is accompanied by the development of specific surface area and leaching of hydrochar-derived dissolved organic matter (HDOM), resulting in a smaller particle size and reduced carbon content. The initial aging also features a mineral shield, while the later aging (16 to 30 months) involves surface oxidation. These processes collectively alter the surface charge, hydrophilicity, and composition of aged hydrochar. Furthermore, this study reveals a dynamic interaction between the HDOM and DOM derived from soil, plants, and microbes at different aging stages. Initially, there is a preference for decomposing labile carbon, whereas later stages involve the formation of components with higher aromaticity and molecular weight. These insights are crucial for understanding the soil aging effects on hydrochar and HDOM as well as evaluating the interfacial behavior of hydrochar as a sustainable soil amendment.

Microplastics alter soil structure and microbial community composition.

Microplastics (MPs), including conventional hard-to-biodegrade petroleum-based and faster biodegradable plant-based ones, impact soil structure and microbiota in turn affecting the biodiversity and functions of terrestrial ecosystems. Herein, we investigated the effects of conventional and biodegradable MPs on aggregate distribution and microbial community composition in microhabitats at the aggregate scale. Two MP types (polyethylene (PE) and polylactic acid (PLA) with increasing size (50, 150, and 300 µm)) were mixed with a silty loam soil (0-20 cm) at a ratio of 0.5 % (w/w) in a rice-wheat rotation system in a greenhouse under 25 °C for one year. The effects on aggregation, bacterial communities and their co-occurrence networks were investigated as a function of MP aggregate size. Conventional and biodegradable MPs generally had similar effects on soil aggregation and bacterial communities. They increased the proportion of microaggregates from 17 % to 32 %, while reducing the macroaggregates from 84 % to 68 %. The aggregate stability decreased from 1.4 mm to 1.0-1.1 mm independently of MP size due to the decline in the binding agents gluing soil particles (e.g., microbial byproducts and proteinaceous substances). MP type and amount strongly affected the bacterial community structure, accounting for 54 % of the variance. Due to less bioavailable organics, bacterial community composition within microaggregates was more sensitive to MPs addition compared to macroaggregates. Co-occurrence network analysis revealed that MPs exacerbated competition among bacteria and increased the complexity of bacterial networks. Such effects were stronger for PE than PLA MPs due to the higher persistence of PE in soils. Proteobacteria, Bacteroidetes, Chloroflexi, Actinobacteria, and Gemmatimonadetes were the keystone taxa in macroaggregates, while Actinobacteria and Chloroflexi were the keystone taxa in microaggregates. Proteobacteria, Actinobacteria, and Chloroflexi were the most sensitive bacteria to MPs addition. Overall, both conventional and biodegradable MPs reduced the portion of large and stable aggregates, altering bacterial community structures and keystone taxa, and consequently, the functions.

Manure derived hydrochar reduced phosphorus loss risk via an alteration of phosphorus fractions and diversified microbial community in rice paddy soil.

Phosphorus (P) loss caused by the irrational use of manure organic fertilizer has become a worldwide environmental problem, which has caused a potential threat to water safety and intensified agricultural non-point source pollution. Hydrothermal carbonization is method with a low-energy consumption and high efficiency to deal with environmental problems. Application of pig manure-derived hydrochar (PMH) to soil exhibited potential of sustainable development compared with the pristine pig manure (PM). However, the effects of PMH on the distribution of P among the fractions/forms and the interaction between microorganisms and P forms and its relevance to the potential loss of P in paddy fields has not been clarified. Therefore, in this study, a soil column experiment was conducted using the untreated soil (control), and the PM, PMH1 (PMH derived at 180 °C), and PMH2 (PMH derived at 260 °C) treated soils (at the dose of 0.05 %) and rice was cultivated to investigate the effects of PM and PMH on the P fractions, mobilization, ad potential loss via the induced changes on soil microbial community after a complete growing season of rice. The trend of P utilization was evaluated by P speciation via continuous extraction and 31P NMR. The addition of PMH reduced the proportion of residual P in soil by 23.8-26.3 %, and increased the proportion of HCl-P and orthophosphate by 116.2-158.6 % and 6.1-6.8 % compared to PM. The abundance of gcd gene developed after the application of PMH2, which enhanced the mobile forms of soil P utilization via secreting gluconic acid. The network diagram analysis concluded that the changes in various P forms were mainly related to Proteobacteria, Bacteroides, Firmicutes and Acidobacteria. The results illustrated that PMH mitigate the potential risk of P loss more than PM by altering P fractions and affecting soil microbial community.

One-step synthesis of phytic acid-assisted hydrochar boost selective sorption and in situ passivation of lanthanum.

The rare earth metal element lanthanum (La) possesses carcinogenic, genotoxic, and accumulative properties, necessitating urgent development of an efficient and cost-effective method to remove La. However, current sorbents still encounter challenges such as poor selectivity, low sorption capacity, and high production costs. This study therefore proposes a promising solution: the creation of phytic acid-assisted sludge hydrochars (P-SHCs) to eliminate La from water and soil environments. This method harnesses phytic acid's exceptional binding ability and the economical hydrothermal carbonization process. P-SHCs exhibit robust sorption affinity, fast sorption kinetics, and excellent sorption selectivity for La when compared with pristine hydrochars (SHCs). This advantage arises from the remarkable binding ability of phosphate functional groups (polyphosphates) on P-SHCs, forming P-O-La complexes. Moreover, P-SHCs demonstrate sustained sorption efficiency across at least five cycles, with a slight decrease attributed to the loss of phosphorus species and mass during recycling. Furthermore, P-SHCs demonstrated superior economic feasibility, with a higher estimated cost-benefit ratio than that of other sorbents. Our study further validates the exceptional passivation capability of P-SHCs, showcasing relative stabilization efficiency ranging from 37.6 % to 79.6 % for La contamination. Additionally, acting as soil passivation agents, P-SHCs foster the enrichment of specific soil microorganisms such as Actinobacteria and Proteobacteria, capable of solubilizing phosphorus and resisting heavy metals. These findings present novel ideas and technical support for employing P-SHCs in combatting environmental pollution stemming from rare earth metals.

Multi-analyte fluorescence sensing based on a post-synthetically functionalized two-dimensional Zn-MOF nanosheets featuring excited-state proton transfer process.

Covalent post-synthetic modification of metal-organic frameworks (MOFs) represents an underexplored but promising avenue for allowing the addition of specific fluorescent recognition elements to produce the novel MOF-based sensory materials with multiple-analyte detection capability. Here, an excited-state proton transfer (ESPT) active sensor 2D-Zn-NS-P was designed and constructed by covalent post-synthetic incorporation of the excited-state tautomeric 2-hydroxypyridine moiety into the ultrasonically exfoliated amino-tagged 2D Zn-MOF nanosheets (2D-Zn-NS). The water-mediated ESPT process facilitates the highly accessible active sites incorporated on the surface of 2D-Zn-NS-P to specifically respond to the presence of water in common organic solvents via fluorescence turn-on behavior, and accurate quantification of trace amount of water in acetonitrile, acetone and ethanol was established using the as-synthesized nanosheet sensor with the detection sensitivity (<0.01% v/v) superior to the conventional Karl Fischer titration. Upon exposure to Fe3+ or Cr2O72-, the intense blue emission of the aqueous colloidal dispersion of 2D-Zn-NS-P was selectively quenched even in the coexistence of common inorganic interferents. The prohibition of the water-mediated ESPT process and local emission, induced by the coordination of ESPT fluorophore with Fe3+ or by Cr2O72- competitively absorbs the excitation energy, was proposed to responsible for the fluorescence turn-off sensing of the respective analytes. The present study offers the attractive prospect to develop the ESPT-based fluorescent MOF nanosheets by covalent post-synthetic modification strategy as multi-functional sensors for detection of target analytes.

Bibliometric analysis of biochar-based organic fertilizers in the past 15 years: Focus on ammonia volatilization and greenhouse gas emissions during composting.

Biochar-based organic fertilizer is a new type of ecological fertilizer formulated with organic fertilizers using biochar as the primary conditioning agent, which has received wide attention and application in recent years. This study conducted a comprehensive bibliometric analysis of the main hot spots and research trends in the field of biochar-based organic fertilizer research by collecting indicators (publication year, number, prominent authors, and research institutions) in the Web of Science database. The results showed that the research in biochar-based organic fertilizer has been in a rapid development stage since 2015, with exponential growth in publications number; the main institution with the highest publications number was Northwest Agriculture & Forestry University; the researchers with the highest number of publications was Mukesh Kumar Awasthi; the most publications country is China by Dec 30, 2022. The hot spots of biochar-based organic fertilizer research have been nitrogen utilization, greenhouse gas emission, composting product quality and soil fertility. Biochar reduces ammonia volatilization and greenhouse gas emissions from compost mainly through adsorption. The results showed that adding 10% biochar was an effective measure to achieve co-emission reduction of ammonia and greenhouse gases in composting process. In addition, biochar modification or combination with other additives should be the focus of future research to mitigate ammonia and greenhouse gas emissions from composting processes.

Different crystalline manganese dioxide and biochar co-conditioning aerobic composting: Reduced ammonia volatilization and improved organic fertilizer quality.

Aerobic composting is a sustainable and effective waste disposal method. However, it can generate massive amounts of ammonia (NH3) via volatilization. Effectively reducing NH3 volatilization is vital for advancing aerobic composting and protecting the ecological environment. Herein, two crystal types of MnO2 (α-MnO2 and δ-MnO2) are combined with biochar (hydrochar (WHC) and pyrochar (WPC), respectively) and used as conditioners for the aerobic composting of chicken manure. Results reveal that α-MnO2 (34.6%) can more effectively reduce NH3 accumulation than δ-MnO2 (27.1%). Moreover, the combination of WHC and MnO2 better reduces NH3 volatilization (48.5-58.9%) than the combination of WPC and MnO2 (15.8-40.1%). The highest NH3 volatilization reduction effect (58.9%) is achieved using the combination of WHC and δ-MnO2. Because the added WHC and δ-MnO2 promote the humification of the compost, the humic acid to fulvic acid ratio (HA/FA ratio) dramatically increases. The combination of WHC and δ-MnO2 doubled the HA/FA ratio and resulted in a net economic benefit of 130.0 RMB/t. Therefore, WHC and δ-MnO2 co-conditioning can promote compost decomposition, improving the quality of organic fertilizers and substantially reducing NH3 volatilization.

Surface acidic sites strengthened core-shell HC@MnO2 for enhanced gaseous ammonia adsorption.

As a common gaseous pollutant in atmospheric environment, ammonia (NH3) not only contributes to the formation of haze, but also disturb the nitrogen balance in ecosystem through atmospheric nitrogen deposition. Therefore, the control of NH3 emission has important environmental significance. Adsorption is the most commonly used technology for NH3 purification in practice, and efficient adsorbents are the key to adsorption method. Herein, a core-shell structured HC@MnO2 adsorbent was constructed by in-situ growth of layered δ-MnO2 on hydrochar (HC) surface, and its surface acidic sites were further strengthened. The enhancement of surface acidic sites significantly improved the adsorption performance of HC@MnO2 for NH3, reaching 34.49 mg NH3/g, which was superior to commercial carbon-based materials (whose adsorption capacity was 8.47 times that of Coal-based activated carbon, 14.25 times that of Coconut shell activated carbon, and 12.77 times that of Bamboo charcoal). Moreover, the operating parameters and adsorption kinetics were detailly investigated. The adsorption of HC@MnO2 on NH3 was in accordance with pseudo-second-order adsorption kinetics model. Large surface area of core-shell structure and abundant surface acidic sites of δ-MnO2 are the decisive reasons for the excellent adsorption performance of HC@MnO2. Importantly, the enhancement of surface stronger Brønsted acidic sites is the key to improve NH3 adsorption performance of HC@MnO2. Finally, the thermal regeneration and recycling performance of HC@MnO2-H were also investigated. This study provides a suggestive for further research on low-cost composite materials with excellent NH3 adsorption performance.

Manure-derived hydrochar superior to manure: Reducing non-point pollution risk by altering nitrogen and phosphorus fugacity in the soil-water system.

Hydrothermal carbonization (HTC) technology is an emerging technology for the disposal of manure-based wet wastes. However, the effects of manure-derived hydrochar inputs to agricultural soils on nitrogen (N) and phosphorus (P) morphology and conversion in soil-water systems remain largely unexplored. In this study, pig and cattle manure (PM and CM), and their derived hydrochar (PCs and CCs) were applied to agricultural soils, with changes in nutrient morphology and enzyme activities related to N and P transformation in the soil-water systems observed through flooded incubation experiments. The results showed that floodwater ammonia N concentrations were reduced by 12.9-29.6% for PCs relative to PM, and 21.6-36.9% for CCs relative to CM, respectively. Moreover, floodwater total P concentrations of PCs and CCs were reduced by 11.7-20.7% relative to PM and CM. Soil enzyme activities closely related to N and P transformations in the soil-water system responded differently to manure and manure-derived hydrochar application. Compared to manure, the application of manure-derived hydrochar inhibited soil urease and acid phosphatase activity by up to 59.4% and 20.3%, respectively, whereas it had significant promotion effects on soil nitrate reductase (∼69.7%) and soil nitrite reductase (∼64.0%). The products of manure after HTC treatments have the characteristics of organic fertilizers, and the fertilization effects of PCs are more prominent than CCs, which are subject to further verification in field trials. Our findings improve the current understanding of manure-derived organic matter affecting N and P conversions in soil-water systems and the risk for non-point source pollution.

Hydrothermal carbonization aqueous phase promotes nutrient retention and humic substance formation during aerobic composting of chicken manure.

The aqueous phase (AP) of hydrothermal carbonization is rich in humic substances (HSs), which could influence the poultry manure composting process and the product quality. Here, raw AP and its modified product (MAP) with different nitrogen (N) contents were added into chicken manure composting at low (5%) or high (10%) rate. Results showed that all APs addition decreased the temperature and pH but AP-10% increased total N, HSs, and humic acid (HA) of compost by 12%, 18% and 27%, respectively. MAP applications increased the total phosphorus by 8-9% and MAP-10% enhanced the total potussium content by 20%. Additionally, both AP and MAP additions increased the contents of three major components of dissolved organic matter by 20-64%. In conclusion, both AP and MAP can generally improve the chicken manure compost quality, which provides a new idea for the recycling of APs derived from agro-forestry wastes during hydrothermal carbonization.

Nitrated hydrochar reduce the Cd accumulation in rice and shift the microbial community in Cd contaminated soil.

Rice grown on Cd-contaminated soil may accumulate Cd in grain, which is extremely harmful to human health. Several managements are developed to reduce the Cd load in rice, while in-situ immobilization by soil amendments has been attractive for its feasibility. Waste-derived hydrochar (HC) has been shown effective at immobilizing Cd in soil. However, potential plant negative effects and huge application amount are crucial to resolving in extensive application of HC. Nitric acid ageing may be an effective method to deal with these problems. In this paper, HC and nitrated hydrochar (NHC) were added to the Cd-contaminated soil at rates of 1% and 2% in a rice-soil column experiment. Results showed that NHC markedly promoted root biomass of rice by 58.70-72.78%, whereas HC had effects of 35.86-47.57%. Notably, NHC at 1% reduced the accumulation of Cd in rice grain, root and straw by 28.04%, 15.08% and 11.07%, respectively. A consistent decrease of 36.30% in soil EXC-Cd concentration was caused by NHC-1%. Following soil microbial community was shifted greatly under HC and NHC applications. The relative abundance of Acidobacteria was decreased by 62.57% in NHC-2% and by 56.89% in HC-1%. Nevertheless, Proteobacteria and Firmicutes were promoted by NHC addition. In contrast to HC, co-occurrence network of dominated bacteria was more complex and centralized generated by NHC. Key bacteria in that metabolic network of NHC such as Anaerolineae and Archangiaceae played key roles in Cd immobilization. These observations verified that NHC was more efficient to decrease Cd accumulation in rice and could alleviate the negative roles to plant by microbial changings in community composition and network. It could provide an enrichment of paddy soil microbial responds to the interaction of NHC with Cd and lay a foundation for the remediation of Cd-contaminated soil by NHC.

Tofu by-product soy whey substitutes urea: Reduced ammonia volatilization, enhanced soil fertility and improved fruit quality in cherry tomato production.

Soy whey is an abundant, nutrient-rich and safe wastewater produced in tofu processing, so it is necessary to valorize it instead of discarding it as sewage. Whether soy whey can be used as a fertilizer substitute for agricultural production is unclear. In this study, the effects of soy whey serving as a nitrogen source to substitute urea on soil NH3 volatilization, dissolved organic matter (DOM) components and cherry tomato qualities were investigated by soil column experiment. Results showed that the soil NH4+-N concentrations and pH values of the 50% soy whey fertilizer combined with 50% urea (50%-SW) and 100% soy whey fertilizer (100%-SW) treatments were lower than those of 100% urea treatment (CKU). Compared with CKU, 50%-SW and 100%-SW treatments increased the abundance of ammonia oxidizing bacteria (AOB) by 6.52-100.89%, protease activity by 66.22-83.78%, the contents of total organic carbon (TOC) by 16.97-35.64%, humification index (HIX) of soil DOM by 13.57-17.99%, and average weight per fruit of cherry tomato by 13.46-18.56%, respectively. Moreover, soy whey as liquid organic fertilizer reduced the soil NH3 volatilization by 18.65-25.27% and the fertilization cost by 25.94-51.87% compared with CKU. This study provides a promising option with economic and environmental benefits for soy whey utilization and cherry tomato production, which contributes to the win-win effectiveness of sustainable production for both the soy products industry and agriculture.

Structural characteristics of dissolved black carbon and its interactions with organic and inorganic contaminants: A critical review.

Biochar (BC) is a sustainable and renewable carbonaceous material, and its soluble component, dissolved black carbon (DBC), is the key to understanding BC's geological and environmental processes. Although the relationship between the changes in DBC structure and its properties, functions, and associated environmental risks has been explored, a gap remains in our understanding of DBC's fate and behavior in the natural environment. Thus, in this review, we have highlighted the molecular and chemical compositions and the structural evolution of DBC during pyrolysis, the influence of DBC's physicochemical properties on its fate and transport, DBC's interaction with soil and its contaminants, and DBC stability in soil and water environments along with potential risks. Based on our in-depth assessment of DBC and its biogeochemical roles, we believe that future studies should focus on the following: (1) using advanced techniques to understand the chemical and molecular structure of DBC deeply and concisely and, thus, determine its fundamental role in the natural environment; (2) investigating the multi-functional properties of DBC and its interaction mechanisms; and (3) evaluating the environmental behaviors of and risks associated with DBC after BC application. In future, it is necessary to gain a deeper insight into the fate and transport of DBC with contaminants and study its associated risks under BC application in the environment.

Natural N-Doped Carbon Quantum Dots Derived from Straw and Adhered onto TiO2 Nanospheres for Enhancing the Removal of Antibiotics and Resistance Genes.

Antibiotics and antibiotic resistance genes (ARGs) are emerging environmental contaminants. TiO2 photocatalytic degradation has been proved an important removal technique, but its photocatalytic ability needs be improved. In our work, natural N-doped carbon quantum dots (N-SCQDs) were extracted from hydrothermal carbonization waste liquid of straw and were attached onto TiO2 nanospheres for remediating antibiotics [sulfadiazine (SA)] and ARGs (sul1, sul2, and intl1). The maximum SA reduction rates were close to 100%, and the ARG reduction rates were 52.91-83.52%/lg10 (sul1), 32.10-68.23%/lg10 (sul2), and 46.29-76.55%/lg10 (inlt1). The temperature of the straw derivatives would influence their photoelectric properties. N-SCQDs@TiO2 expands the application range of a novel potential high-efficiency degradation catalyst and offers a new way of hydrothermal carbonization waste liquid of agricultural waste.