Investigating mechanisms of state localization in highly ionized dense plasmas.

We present experimental observations of K_{ß} emission from highly charged Mg ions at solid density, driven by intense x rays from a free electron laser. The presence of K_{ß} emission indicates the n=3 atomic shell is relocalized for high charge states, providing an upper constraint on the depression of the ionization potential. We explore the process of state relocalization in dense plasmas from first principles using finite-temperature density functional theory alongside a wave-function localization metric, and find excellent agreement with experimental results.

Increase in seed tannin extractability and oxidation using a freeze-thaw treatment in cool-climate grown red (Vitis vinifera L.) cultivars.

Grape seed maturation involves the gradual oxidation of tannins, decreasing excessive bitterness and astringency in wine. In cool climates, this process is limited by the short growing season, affecting wine quality. A "freeze-thaw" treatment on seeds of red vinifera cultivars at veraison and harvest was used to evaluate the effect of oxidation and extractability on seed phenolic fractions. Freezing increased the extraction of total phenolics and o-diphenols quantified from fractionation (fraction 1, vacuolar tannins; fraction 2, hydrogen bonded tannins; fraction 3, covalently bonded tannins), especially at harvest. Despite this, colorimetry, microscopy, oxidation reactivity index (ORI), and correlations between the color index and fractions indicated that freezing disrupted vacuole integrity, enhancing oxidation in the seed coat. In conclusion, vacuolar tannins (which are the main seed phenolics extracted during fermentation) were highly correlated with seed color change, potentially providing information for winemaking in cool climate regions.

Two deep-mantle sources for Paleocene doming and volcanism in the North Atlantic.

The North Atlantic Igneous Province (NAIP) erupted in two major pulses that coincide with the continental breakup and the opening of the North Atlantic Ocean over a period from 62 to 54 Ma. The unknown mantle structure under the North Atlantic during the Paleocene represents a major missing link in deciphering the geodynamic causes of this event. To address this outstanding challenge, we use a back-and-forth iterative method for time-reversed global convection modeling over the Cenozoic Era which incorporates models of present-day tomography-based mantle heterogeneity. We find that the Paleocene mantle under the North Atlantic is characterized by two major low-density plumes in the lower mantle: one beneath Greenland and another beneath the Azores. These strong lower-mantle upwellings generate small-scale hot upwellings and cold downwellings in the upper mantle. The upwellings are dispersed sources of magmatism and topographic uplift that were active on the rifted margins of the North Atlantic during the formation of the NAIP. While most studies of the Paleocene evolution of the North Atlantic have focused on the proto-Icelandic plume, our Cenozoic reconstructions reveal the equally important dynamics of a hot, buoyant, mantle-wide upwelling below the Azores.

On the deep-mantle origin of the Deccan Traps.

The Deccan Traps in west-central India constitute one of Earth's largest continental flood basalt provinces, whose eruption played a role in the Cretaceous-Paleogene extinction event. The unknown mantle structure under the Indian Ocean at the start of the Cenozoic presents a challenge for connecting the event to a deep mantle origin. We used a back-and-forth iterative method for time-reversed convection modeling, which incorporates tomography-based, present-day mantle heterogeneity to reconstruct mantle structure at the start of the Cenozoic. We show a very low-density, deep-seated upwelling that ascends beneath the Réunion hot spot at the time of the Deccan eruptions. We found a second active upwelling below the Comores hot spot that likely contributed to the region of partial melt feeding the massive eruption.

Kinematics and dynamics of the East Pacific Rise linked to a stable, deep-mantle upwelling.

Earth's tectonic plates are generally considered to be driven largely by negative buoyancy associated with subduction of oceanic lithosphere. In this context, mid-ocean ridges (MORs) are passive plate boundaries whose divergence accommodates flow driven by subduction of oceanic slabs at trenches. We show that over the past 80 million years (My), the East Pacific Rise (EPR), Earth's dominant MOR, has been characterized by limited ridge-perpendicular migration and persistent, asymmetric ridge accretion that are anomalous relative to other MORs. We reconstruct the subduction-related buoyancy fluxes of plates on either side of the EPR. The general expectation is that greater slab pull should correlate with faster plate motion and faster spreading at the EPR. Moreover, asymmetry in slab pull on either side of the EPR should correlate with either ridge migration or enhanced plate velocity in the direction of greater slab pull. Based on our analysis, none of the expected correlations are evident. This implies that other forces significantly contribute to EPR behavior. We explain these observations using mantle flow calculations based on globally integrated buoyancy distributions that require core-mantle boundary heat flux of up to 20 TW. The time-dependent mantle flow predictions yield a long-lived deep-seated upwelling that has its highest radial velocity under the EPR and is inferred to control its observed kinematics. The mantle-wide upwelling beneath the EPR drives horizontal components of asthenospheric flows beneath the plates that are similarly asymmetric but faster than the overlying surface plates, thereby contributing to plate motions through viscous tractions in the Pacific region.

Dynamic topography change of the eastern United States since 3 million years ago.

Sedimentary rocks from Virginia through Florida record marine flooding during the mid-Pliocene. Several wave-cut scarps that at the time of deposition would have been horizontal are now draped over a warped surface with a maximum variation of 60 meters. We modeled dynamic topography by using mantle convection simulations that predict the amplitude and broad spatial distribution of this distortion. The results imply that dynamic topography and, to a lesser extent, glacial isostatic adjustment account for the current architecture of the coastal plain and proximal shelf. This confounds attempts to use regional stratigraphic relations as references for longer-term sea-level determinations. Inferences of Pliocene global sea-level heights or stability of Antarctic ice sheets therefore cannot be deciphered in the absence of an appropriate mantle dynamic reference frame.

Geodynamic and seismic constraints on the thermochemical structure and dynamics of convection in the deep mantle.

We revisit a recent study by Forte & Mitrovica in which global geophysical observables associated with mantle convection were inverted and the existence of a strong increase in viscosity near a depth of 2000 km was inferred. Employing mineral-physics data and theory we also showed that, although there are chemical anomalies in the lowermost mantle, they are unable to inhibit the dominant thermal buoyancy of the deep-mantle mega-plumes below Africa and the Pacific Ocean. New Monte Carlo simulations are employed to explore the impact of uncertainties in current mineral-physics constraints on inferences of deep-mantle thermochemical structure. To explore the impact of the high-viscosity peak at a depth of 2000 km on the evolution of lower-mantle structure, we carried out time-dependent convection simulations. The latter show that the stability and longevity of the dominant long-wavelength heterogeneity in the lowermost mantle are controlled by this viscosity peak.