1.
Inorg Chem
; 57(23): 14463-14466, 2018 Dec 03.
Artigo
em Inglês
| MEDLINE
| ID: mdl-30407799
RESUMO
c-Si6Cl12 functions as a Lewis acid strong enough to abstract chloride ions from 2 mol of triphenylchloromethane to form the salt [Tr+]2[Si6Cl142-]. This is the first example of a Lewis acid "hole" breaking a carbon-halogen bond.