1.
Chemistry
; 30(33): e202401235, 2024 Jun 12.
Artigo
em Inglês
| MEDLINE
| ID: mdl-38593362
RESUMO
Trialkyl phosphines PMe3 and PEt3 catalyze the 1,2-cis-diboration of 1,3-butadiynes to give 1,2-diboryl enynes. The products were utilized to synthesize 1,1,2,4-tetraaryl enynes using a Suzuki-Miyaura protocol and can readily undergo proto-deborylation.