Influence of Graphene Oxide on Mechanical Properties and Durability of Cement Mortar.

The effect of graphene oxide (GO) on the mechanical strengths and durability of cement composites was researched by preparing GO-modified cement mortars. Thermogravimetric analysis (TGA) and nuclear magnetic resonance (29Si MAS-NMR) were performed on the cement paste to evaluate the influence of GO on the hydration process and chain structure of calcium-silicate-hydrate (C-S-H) gels. TGA revealed that the high GO dosage increased the content of C-S-H by 5.46% compared with the control at 28 days. Similarly, 29Si-NMR improved the hydration degree and main chain length (MCL) in GO-modified samples at 28 days. The GO led to increases of 2.54% and 7.01% in the hydration degree and MCL, respectively, compared with the control at 28 days. These findings underscore the multifaceted role of GO in improving the mechanical properties and durability of cement composites. Mechanical strength tests, such as compressive and flexural tests, were conducted on cement mortars. The optimal dosage of GO increased the compressive strength by 9.02% after 28 days. Furthermore, the flexural strength of cement mortars with the combination of GO and superplasticizer (SP) after 28 days increased by 21.86%, compared with reference mortar. The impact of GO proved to be more pronounced and beneficial in the durability tests, suggesting that GO can enhance the microstructure through hydration products to create a dense and interconnected microstructure.

Numerical Simulation of PFRC Fracture Subjected to High Temperature by Means of a Trilinear Softening Diagram.

Fibre-reinforced concrete (FRC) has been used for decades in certain applications in the construction industry, such as tunnel linings and precast elements, but has experienced important progress in recent times, boosted by the inclusion of guidelines for its use in some national and international standards. Traditional steel fibres have been studied in depth and their performance is well-known, although in recent years new materials have been proposed as possible alternatives. Polyolefin macro-fibres, for instance, have been proven to enhance the mechanical properties of concrete and the parameters that define their behaviour (fibre length, fibre proportion or casting method, for instance) have been identified. These fibres overcome certain traditional problems related to steel fibres, such as corrosion or their interaction with magnetic fields, which can limit the use of steel in some applications. The behaviour of polyolefin fibre-reinforced concrete (PFRC) has been numerically reproduced with success through an embedded cohesive crack formulation that uses a trilinear softening diagram to describe the fracture behaviour of the material. Furthermore, concrete behaves well under high temperatures or fire events, especially when it is compared with other construction materials, but the behaviour of PFRC must be analysed if the use of these fibres is to be extended. To this end, the degradation of PFRC fracture properties has been recently experimentally analysed under a temperature range between 20 °C and 200 °C. As temperature increases, polyolefin fibres modify their mechanical properties and their shape, which reduce their performance as reinforcements of concrete. In this work, those experimental results, which include results of low (3 kg/m3) and high (10 kg/m3) proportion PFRC specimens, are used as reference to study the fracture behaviour of PFRC exposed to high temperatures from a numerical point of view. The experimental load-deflection diagrams are reproduced by modifying the trilinear diagram used in the cohesive model, which helps to understand how the trilinear diagram parameters are affected by high temperature exposure. Finally, some expressions are proposed to adapt the initial trilinear diagram (obtained with specimens not exposed to high temperature) in order to numerically reproduce the fracture behaviour of PFRC affected by high temperature exposure.

Co-producing uncomfortable, transdisciplinary, actionable knowledges against the corporate food regime through critical science approaches.

The current corporate food regime generates some of the most challenging ecological, social, and ethical problems for humanity in its quest for sustainability and ecological justice. Different scientific disciplines have analyzed these problems in-depth, but usually from their comfort zone, i.e., without engagement with other disciplines and epistemologies. The predominance of disciplinary visions seriously limits, however, understanding the complexities of the corporate food regime, including the impacts it generates. Further, most research concerned with this food regime confronts epistemological, methodological, and political limitations to engage with the type of solutions that could lead to transitions to just sustainabilities. Here we review and integrate the findings from scientific literature focused on the ecological, social, or ethical impacts of the corporate food regime, with an emphasis on impacts that operate on a global scale. In addition, we analyze the need for critical science approaches to trigger generative processes for the co-production of uncomfortable, transdisciplinary, actionable knowledges that are fit for designing just and sustainable food regimes. Much of the evidence presented in our analysis is in tension with the interests of the corporate food regime, which fosters decision-making processes based on selective ignorance of the impacts caused by this regime. Our work provides arguments that justify the need to promote transitions to just sustainabilities in agricultural systems from multiple domains (e.g., research and development, public policies, grassroots innovations). We posit that strategies to co-design and build such transitions can emerge from the co-production of uncomfortable, transdisciplinary, actionable knowledges through critical science approaches.

Grassroots innovation for the pluriverse: evidence from Zapatismo and autonomous Zapatista education.

The social and environmental failure of successive Western development models imposed on the global South has led local communities to pursue alternatives to development. Such alternatives seek radical societal transformations that require the production of new knowledge, practices, technologies, and institutions that are effective to achieve more just and sustainable societies. We may think of such a production as innovation driven by social movements, organizations, collectives, indigenous peoples, and local communities. Innovation that is driven by such grassroots groups has been theorized in the academic literature as "grassroots innovation". However, research on alternatives to development has rarely examined innovation using grassroots innovation as an analytical framework. Here, we assess how grassroots innovation may contribute to building alternatives to development using Zapatismo in Chiapas (Mexico) as a case study. We focus on grassroots innovation in autonomous Zapatista education because this alternative to formal education plays a vital role in knowledge generation and the production of new social practices within Zapatista communities, which underpin the radical societal transformation being built by Zapatismo. We reviewed the academic literature on grassroots innovation as well as gray literature and audiovisual media on Zapatismo and autonomous Zapatista education. We also conducted ethnographic fieldwork in a Zapatista community and its school. We found innovative educational, pedagogical, and teaching-learning practices based on the (re)production of knowledge and learning, which are not limited to the classroom but linked to all the activities of Zapatistas. Our findings suggest that innovation self-realized by Zapatistas plays a key role on the everyday construction of Zapatismo. Therefore, we argue that a specific theoretical framework of grassroots innovation for the pluriverse, based on empirical work carried out in different alternatives to development, is an urgent task that will contribute to a better understanding of how such alternatives grassroots groups imagine, design, and build, particularly across the global South.

Effect of Sulfate Ions on Galvanized Post-Tensioned Steel Corrosion in Alkaline Solutions and the Interaction with Other Ions.

Zinc protection of galvanized steel is initially dissolved in alkaline solutions. However, a passive layer is formed over time which protects the steel from corrosion. The behavior of galvanized steel exposed to strong alkaline solutions (pH values of 12.7) with a fixed concentration of sulfate ions of 0.04 M is studied here. Electrochemical measurement techniques such as corrosion potential, linear polarization resistance and electrochemical impedance spectroscopy are used. Synergistic effects of sulfate ions are also studied together with other anions such as chloride Cl− or bicarbonate ion HCO3− and with other cations such as calcium Ca2+, ammonium NH4+ and magnesium Mg2+. The presence of sulfate ions can also depassivate the steel, leading to a corrosion current density of 0.3 µA/cm2 at the end of the test. The presence of other ions in the solution increases this effect. The increase in corrosion current density caused by cations and anions corresponds to the following orders (greater to lesser influence): NH4+ > Ca2+ > Mg2+ and HCO3− > Cl− > SO42−.

Suitability of Constitutive Models of the Structural Concrete Codes When Applied to Polyolefin Fibre Reinforced Concrete.

The use of fibres as structural reinforcement in concrete is included in standards, providing guidelines to reproduce their behaviour, which have been proven adequate when steel fibres are used. Nevertheless, in recent years new materials, such as polyolefin fibres, have undergone significant development as concrete reinforcement. This work gives insight on how suitable the constitutive models proposed by the Model Code 2010 (MC2010) are in the case of such polymer fibres. A set of numerical models has been carried out to reproduce the material behaviour proposed by the MC2010 and the approach based on the softening function proposed by the authors. The results show remarkable differences between the experimental results and the numerical simulations when the constitutive models described in the MC2010 are employed for different polyolefin fibre reinforced concrete mixes, while the material behaviour can be reproduced with greater accuracy if the softening function proposed by the authors is employed when this type of macro-polymer fibres is used. Moreover, the relatively complex behaviour of polyolefin fibre reinforced concrete may be reproduced by using such constitutive model.

Matrix Optimization of Ultra High Performance Concrete for Improving Strength and Durability.

This paper seeks to optimize the mechanical and durability properties of ultra-high performance concrete (UHPC). To meet this objective, concrete specimens were manufactured by using 1100 kg/m3 of binder, water/binder ratio 0.20, silica sand and last generation of superplasticizer. Silica fume, metakaolin and two types of nano silica were used for improving the performances of the concrete. Additional mixtures included 13 mm long OL steel fibers. Compressive strength, electrical resistivity, mercury intrusion porosimetry tests, and differential and thermogravimetric thermal analysis were carried out. The binary combination of nano silica and metakaolin, and the ternary combination of nano silica with metakaolin and silica fume, led to the best performances of the UHPC, both mechanical and durable performances.

Assessment of the Post-Cracking Fatigue Behavior of Steel and Polyolefin Fiber-Reinforced Concrete.

Some types of fiber-reinforced concrete (FRC) such as steel fiber-reinforced concrete (SFRC) or polyolefin fiber-reinforced concrete (PFRC) are suitable for structural uses but there is still scarce knowledge regarding their flexural fatigue behavior. This study aimed to provide some insight into the matter by carrying out flexural fatigue tests in pre-cracked notched specimens that previously reached the Service Limit State (SLS) or the Ultimate Limit State (ULS). The fatigue cycles applied between 30% and 70% of the pre-crack load at 5 Hz until the collapse of the material or until 1,000,000 cycles were reached. The results showed that the fatigue life of PFRC both at SLS or ULS was remarkably higher than the correspondent of SFRC. The fracture surface analysis carried out found a linear relation between the fibers present in the fracture surface and the number of cycles that both SFRC and PFRC could bear.

Influence of Natural Weather Conditions in the Long-Term Fracture Energy of Glass Fibre Reinforced Cement (GRC) Modified with Chemical Additions.

The use of glass fibre-reinforced cement (GRC) in structural elements has been limited due to the reduction in the mechanical properties of the material with aging. Chemical additions have been used to modify the cement mortar formulation in order to minimise such loss, but no conclusive results have been obtained yet. Moreover, the application of accelerated aging methods in such modified GRC formulations still poses several uncertainties. An experimental campaign seeking to assess the reduction in the fracture energy of two GRCs manufactured with modified matrixes after five years of exposure to natural environment was performed. Furthermore, a comparison with results from the literature that used accelerated aging methods was performed. The results show that the use of the chemical additives might be capable of maintaining to a notable extent the mechanical properties of GRC after five years of natural aging. Regarding the accelerated aging method by means of immersion in hot water tanks, it seemed that the equivalences applied in previous research accurately match the degradation of the material after natural exposure to weather. Additionally, a digital image correlation analysis showed that aged GRCs seemed to distribute damage in a smaller area than young GRCs.

Fracture and Size Effect of PFRC Specimens Simulated by Using a Trilinear Softening Diagram: A Predictive Approach.

The size effect on plain concrete specimens is well known and can be correctly captured when performing numerical simulations by using a well characterised softening function. Nevertheless, in the case of polyolefin-fibre-reinforced concrete (PFRC), this is not directly applicable, since using only diagram cannot capture the material behaviour on elements with different sizes due to dependence of the orientation factor of the fibres with the size of the specimen. In previous works, the use of a trilinear softening diagram proved to be very convenient for reproducing fracture of polyolefin-fibre-reinforced concrete elements, but only if it is previously adapted for each specimen size. In this work, a predictive methodology is used to reproduce fracture of polyolefin-fibre-reinforced concrete specimens of different sizes under three-point bending. Fracture is reproduced by means of a well-known embedded cohesive model, with a trilinear softening function that is defined specifically for each specimen size. The fundamental points of these softening functions are defined a priori by using empirical expressions proposed in past works, based on an extensive experimental background. Therefore, the numerical results are obtained in a predictive manner and then compared with a previous experimental campaign in which PFRC notched specimens of different sizes were tested with a three-point bending test setup, showing that this approach properly captures the size effect, although some values of the fundamental points in the trilinear diagram could be defined more accurately.

Achieving Ultra-High Performance Concrete by Using Packing Models in Combination with Nanoadditives.

This paper describes the packing models that are fundamental for the design of ultra-high-performance concrete (UHPC) and their evolution. They are divided into two large groups: continuous and discrete models. The latter are those that provide the best method for achieving an adequate simulation of the packing of the particles up to nanometric size. This includes the interaction among the particles by means of loosening and wall coefficients, allowing a simulation of the virtual and real compactness of such particles. In addition, a relationship between virtual and real compactness is obtained through the compaction index, which may simulate the energy of compaction so that the particles are placed in the mold. The use of last-generation additives allows such models to be implemented with water-cement (w/c) ratios close to 0.18. However, the premise of maximum packing as a basic pillar for the production of UHPC should not be the only one. The cement hydration process affected by nanoadditives and the ensuing effectiveness of the properties in both fresh and hardened states according to the respective percentages in the mixture should also be studied. The characterization tests of the aggregates and additions (dry and wet compactness, granulometry, density and absorption) have been carried out in order to implement them numerically in the polydisperse packing model to obtain the compactness of the mixture. Establishing fixed percentages of nanoadditives in the calculation of the mixture's compactness. The adequate ratio and proportion of these additions can lead to better results even at lower levels of compactness. The compressive strength values obtained at seven days are directly proportional to the calculated compactness. However, at the age of 28 days, better results were obtained in mixes with lower cement contents, fewer additions and lower compactness. Thus, mixes with lower cement contents and additions (silica fume and limestone filler) with a compactness of φ = 0.775 reached 80.1 MPa of strength at 7 days, which is lower than mixes with higher cement contents and number of additions (SF, limestone filler and nanosilica), which achieved a compactness of φ = 0.789 and 93.7 MPa for compressive strength. However, at 28 days the result was reversed with compressive strengths of 124.6 and 121.7 MPa, respectively.

Influence of High Temperature on the Fracture Properties of Polyolefin Fibre Reinforced Concrete.

Concrete has become the most common construction material, showing, among other advantages, good behaviour when subjected to high temperatures. Nevertheless, concrete is usually reinforced with elements of other materials such as steel in the form of rebars or fibres. Thus, the behaviour under high temperatures of these other materials can be critical for structural elements. In addition, concrete spalling occurs when concrete is subjected to high temperature due to internal pressures. Micro polypropylene fibres (PP) have shown to be effective for reducing such spalling, although this type of fibres barely improves any of the mechanical properties of the element. Hence, a combination of PP with steel rebars or fibres can be effective for the structural design of elements exposed to high temperatures. New polyolefin fibres (PF) have become an alternative to steel fibres. PF meet the requirements of the standards to consider the contributions of the fibres in the structural design. However, there is a lack of evidence about the behaviour of PF and elements made of polyolefin fibre reinforced concrete (PFRC) subjected to high temperatures. Given that these polymer fibres would be melt above 250 °C, the behaviour in the intermediate temperatures was assessed in this study. Uni-axial tests on individual fibres and three-point bending tests of PFRC specimens were performed. The results have shown that the residual load-bearing capacity of the material is gradually lost up to 200 °C, though the PFRC showed structural performance up to 185 °C.

Numerical Simulation of the Fracture Behavior of High-Performance Fiber-Reinforced Concrete by Using a Cohesive Crack-Based Inverse Analysis.

Fiber-reinforced concrete (FRC) has become an alternative for structural applications due its outstanding mechanical properties. The appearance of new types of fibres and the fibre cocktails that can be configured by mixing them has created FRC that clearly exceeds the minimum mechanical properties required in the standards. Consequently, in order to take full advantage of the contribution of the fibres in construction projects, it is of interest to have constitutive models that simulate the behaviour of the materials. This study aimed to simulate the fracture behaviour of five types of FRC, three with steel fibres, one with a combination of two types of steel fibers, and one with a combination of polyolefin fibres and two types of steel fibres, by means of an inverse analysis based on the cohesive crack approach. The results of the numerical simulations defined the softening functions of each FRC formulation and have pointed out the synergies that are created through use of fibre cocktails. The information supplied can be of help to engineers in designing structures with high-performance FRC.

Author Correction: Valorization of Colombian fique (Furcraea bedinghausii) for production of cellulose nanofibers and its application in hydrogels.

An amendment to this paper has been published and can be accessed via a link at the top of the paper.

Effect of Extrusion Screw Speed and Plasticizer Proportions on the Rheological, Thermal, Mechanical, Morphological and Superficial Properties of PLA.

One of the critical processing parameters-the speed of the extrusion process for plasticized poly (lactic acid) (PLA)-was investigated in the presence of acetyl tributyl citrate (ATBC) as plasticizer. The mixtures were obtained by varying the content of plasticizer (ATBC, 10-30% by weight), using a twin screw extruder as a processing medium for which a temperature profile with peak was established that ended at 160 °C, two mixing zones and different screw rotation speeds (60 and 150 rpm). To evaluate the thermo-mechanical properties of the blend and hydrophilicity, the miscibility of the plasticizing and PLA matrix, Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC), oscillatory rheological analysis, Dynamic Mechanical Analysis (DMA), mechanical analysis, as well as the contact angle were tested. The results derived from the oscillatory rheological analysis had a viscous behavior in the PLA samples with the presence of ATBC; the lower process speed promotes the transitions from viscous to elastic as well as higher values of loss modulus, storage modulus and complex viscosity, which means less loss of molecular weight and lower residual energy in the transition from the viscous state to the elastic state. The mechanical and thermal performance was optimized considering a greater capacity in the energy absorption and integration of the components.

Valorization of Colombian fique (Furcraea bedinghausii) for production of cellulose nanofibers and its application in hydrogels.

Cellulose nanofibers were obtained from the Colombian fique (Furcraea bedinghausii) and Acrylic hydrogels (H) and reinforced acrylic hydrogels with fique nanofibres (HRFN) were synthesized, using the solution polymerization method. The extraction was carried out using a combined extraction method (chemical procedures and ultrasound radiation). The raw material (NAT-F), bleached fibers (B-F), hydrolyzed fibers and fibers treated with ultrasound (US-F) were characterized by infrared spectroscopy (FTIR) and thermal stability analysis; also, in order to have a comparison criterion, a commercial microcrystalline cellulose sample (CC) was analyzed, which demonstrated the extraction of fique cellulose. The surface morphology of the NAT-F and the B-F was determined by scanning electron microscopy and the average particle size of the nanofibers was made through transmission electron microscopy. In H y HRFN the strain percent and compression resistance (Rc) were measured. The fique nanofibers showed diameter and length averages of 25.2 ± 6.2 nm and 483.8 ± 283.2 nm respectively. Maximum degradation temperature was 317 °C. HRFN presented higher compression resistance (16.39 ± 4.30 kPa) and this resistance was 2.5 greater than the resistance of H (6.49 ± 2.48 kPa). The results indicate that fique lignocellulosic matrix has potential application for obtaining polymeric type composite materials.

Periselectivity in the aza-Diels-Alder Cycloaddition between α-Oxoketenes and N-(5-Pyrazolyl)imines: A Combined Experimental and Theoretical Study.

The thermal 6π aza-Diels-Alder cycloadditions between α-oxoketenes, in situ derived from a thermally induced Wolff rearrangement of 2-diazo-1,3-diketones, and N-(5-pyrazolyl)imines as prototypical electron-rich 2-azadienes lead to two distinct sets of products, essentially as a function of the nature of the α-oxoketenes involved. For instance, cyclic five-membered α-oxoketenes lead preferentially to spiro hydropyridin-4-ones, which involves the α-oxoketenes as the 2π partners at their C═C double bond and the N-(5-pyrazolyl)imines as the 4π partners at their 2-azadiene moiety. In contrast, other cyclic and acyclic α-oxoketenes lead preferentially to 1,3-oxazin-4-ones, which now involves the α-oxoketenes as the 4π partners at their 1-oxadiene moiety and the N-(5-pyrazolyl)imines as the 2π partners at their C═N double bond. A computational modeling study using DFT methods allowed rationalizing this change of periselectivity: the formation of spiro hydropyridin-4-ones is under thermodynamic control while the formation of 1,3-oxazin-4-ones is kinetically controlled, and slightly thermodynamically disfavored in the five-membered ring series. The competing cyclodimerization of the α-oxoketenes is also studied in detail.

Analysis of the Versatility of Multi-Linear Softening Functions Applied in the Simulation of Fracture Behaviour of Fibre-Reinforced Cementitious Materials.

Fibre-reinforced cementitious materials (FRC) have become an attractive alternative for structural applications. Among such FRC, steel- and polyolefin fibre-reinforced concrete and glass fibre-reinforced concrete are the most used ones. However, in order to exploit the properties of such materials, structural designers need constitutive relations that accurately reproduce FRC fracture behaviour. This contribution analyses the suitability of multilinear softening functions combined with a cohesive crack approach for reproducing the fracture behaviour of the FRC mentioned earlier. The performed implementation accurately simulated fracture behaviour, while being versatile, robust, and efficient from a numerical point-of-view.

Influence of Pore Networking and Electric Current Density on the Crack Pattern in Reinforced Concrete Test Due to Pressure Rust Layer at Early Ages of an Accelerated Corrosion Test.

Research on early stages of corrosion of steel bars caused by chloride penetration is relevant in improving the durability of reinforced concrete structures. Similarly, the formation and development of cracks induced in the surrounding concrete is also of great importance. This paper uses integration of the analytical models examined in the published literature, combined with experimental research in corrosion induced at the concrete/steel interface, in estimating the time-to-crack initiation of reinforced concrete subjected to corrosion. This work studies the influence of the porous network and electric current density on the cracking process at early ages. The experimental program was performed by using an accelerated corrosion test. Two types of concrete were performed: A conventional concrete (CC) and a concrete with silica fume (SFC). A current density of 50 µA/cm2 and 100 µA/cm2 was applied to specimens of both concretes. Examination performed by scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) provided both qualitative and quantitative information on the penetration of the rust layer in the surrounding concrete porous network. Strain gauges were used to measure corrosion-induced deformations between steel and concrete matrices, as well as the formation of corrosion-induced cracks. A good correlation between the rate of penetration of the rust products in the surrounding pores and the delay of the cracking pressure in concrete was observed from the experimental results. This phenomenon is incorporated into the analytical model by using a reduction factor, which mainly depends on the pore size of the concrete. The crack width obtained exhibited a significant dependency on electric current density at the beginning of the test, depending mainly on the pore size of the concrete later.