Electrical Double-Layer Capacitors Based on a Ternary Ionic Liquid Electrolyte Operating at Low Temperature with Realistic Gravimetric and Volumetric Energy Outputs.

We report on electrical double-layer capacitors (EDLCs) performing effectively at low temperature (down to -40 °C), owing to the tuned characteristics of both the ionic liquid (IL) electrolyte and carbonaceous electrodes. The transport properties of the electrolyte have been enhanced by adding a low-viscosity IL with the tetracyanoborate anion, [EMIm][TCB], to a mixture of [EMIm][FSI] with [EMIm][BF4 ], which was already successfully applied for this application. The formulated ternary electrolyte, [EMIm][FSI]0.6 [BF4 ]0.1 [TCB]0.3 , remained in the liquid state until it reached the glass transition at -99 °C and displayed a relatively low viscosity and high conductivity (η=23.6 mP s and σ=14.2 mS cm-1 at 20 °C, respectively). The electrodes were made of a hierarchical SiO2 -templated carbon with well-defined and uniform mesopores of ∼9 nm facilitating ion transport to the interconnected micropores accounted for the charge storage, whereas the high density of the electrodes promoted high volumetric energy outputs of the cells.

Latitudinal consistency of biomass size spectra - benthic resilience despite environmental, taxonomic and functional trait variability.

Global warming is expected to cause reductions in organism body size, a fundamental biological unit important in determining biological processes. Possible effects of increasing temperature on biomass size spectra in coastal benthic communities were investigated. We hypothesized higher proportions of smaller size classes in warmer conditions. Soft bottom infauna samples were collected in six Norwegian and Svalbard fjords, spanning wide latitudinal (60-81°N) and bottom water temperature gradients (from -2 to 8 °C). Investigated fjords differed in terms of environmental settings (e.g., pigments or organic carbon in sediments). The slopes of normalised biomass size spectra (NBSS) did not differ among the fjords, while the benthic biomass and NBSS intercepts varied and were related to chlorophyll a and δ13C in sediments. The size spectra based on both abundance and biomass remained consistent, regardless of the strong variability in macrofauna taxonomic and functional trait composition. Variable relationships between temperature and body size were noted for particular taxa. Our results indicate that while benthic biomass depends on the nutritional quality of organic matter, its partitioning among size classes is consistent and independent of environmental and biological variability. The observed size structure remains a persistent feature of studied communities and may be resilient to major climatic changes.

Thiocyanates as attractive redox-active electrolytes for high-energy and environmentally-friendly electrochemical capacitors.

This manuscript reports on the novel insight into the development of high voltage carbon/carbon electrochemical capacitors operating in aqueous solutions of alkali metals and ammonium thiocyanates (KSCN, NaSCN, LiSCN, and NH4SCN). The effect of salt concentration, electrode porosity and current collectors on the capacitance value, system stability, and power performance has been investigated. Therefore, thiocyanate-based electrolytes were recognized as cheap and highly conductive electrolytic solutions (up to 401 mS cm-1 for NH4SCN at RT) allowing a cell voltage of 1.6 V in a symmetric carbon/carbon system to be achieved. At the same time, they display an attractive redox activity, enhancing the energy of the device with a good performance during cycling.