Mid-infrared hyperspectral sensor based on MEMS Fabry-Pérot interferometer for stand-off sensing applications.

We report a novel hyperspectral sensor employing a Fabry-Pérot interferometer based on micro-electro-mechnical system and a custom mid-infrared supercontinuum laser. The Fabry-Pérot interferometer allows on-axis filtering, of spectral components of supercontinuum light backscattered from a target, with a spectral resolution of about 25 nm. We demonstrated hyperspectral identification of black polypropylene (PP) and polyethylene (PE500) using the 3-3.5 [Formula: see text]m region of the supercontinuum spectrum and a corresponding measurement rate of 62.5 spectra / s. The resulted spectra show excellent agreement with the reference based on an FTIR spectrometer. Furthermore, we showed that the coloring of the plastics has no effect on their identification at this wavelength range.

On-Line Monitoring of Radiocarbon Emissions in a Nuclear Facility with Cavity Ring-Down Spectroscopy.

There are currently no suitable methods for sensitive automated in situ monitoring of gaseous radiocarbon, one of the main sources of radioactive gas emissions from nuclear power plants. Here, we present a transportable instrument for in situ airborne radiocarbon detection based on mid-infrared cavity ring-down spectroscopy and report its performance in a 1-week field measurement at the Loviisa nuclear power plant. Radiocarbon is detected by measuring an absorption line of the 14CO2 molecule. The time resolution of the measurements is 45 min, significantly less than the few days' resolution of the currently used technique, while maintaining a comparable sensitivity. The method can also assess the prevalence of radiocarbon in different molecular species in the airborne emissions. The optical in situ monitoring presented is a completely new method for monitoring emissions from nuclear facilities.

Radiocarbon dioxide detection using cantilever-enhanced photoacoustic spectroscopy.

In this Letter, we report on the sub-parts-per-billion-level radiocarbon dioxide detection using cantilever-enhanced photoacoustic spectroscopy. The 14C/C ratio of samples is measured by targeting a 14CO2 absorption line with minimal interference from other CO2 isotopes. Using a quantum cascade laser as a light source allows for a compact experimental setup. In addition, measurements of sample gases with 14CO2 concentrations as low as 100 parts-per-trillion (ppt) are presented. The Allan deviation demonstrates a noise equivalent concentration of 30 ppt at an averaging time of 9 min. The achieved sensitivity validates this method as a suitable alternative to more complex optical detection methods for radiocarbon dioxide detection used so far, and it can be envisioned for future in situ radiocarbon detection.

Optical interruption of a quantum cascade laser for cavity ring-down spectroscopy.

We demonstrate optical unlocking of a cavity resonance in a mid-infrared (MIR) quantum cascade laser (QCL) cavity ring-down spectrometer using a low-power multimode near-infrared (NIR) laser diode. A NIR laser with a center wavelength of 1310 nm is injected into a QCL whose amplitude and frequency are modulated as a result. The shift in frequency leads to a rapid interruption of the cavity resonance. The optical method is compared to cavity interruption with a current step by measuring ring-down times in a high-finesse optical cavity, coupled with a QCL with a center wavelength of 4.5 µm. The results indicate the comparable performance of the all-optical method with the more conventional current modulation, but with significantly reduced bandwidth requirements for the QCL driver, opening the way to other potential applications in MIR laser spectroscopy.

Laser Spectroscopy for Monitoring of Radiocarbon in Atmospheric Samples.

In-situ monitoring of radiocarbon emissions is challenging due to the lack of a suitable method for sensitive online detection of this isotope. Here we report on a complete system for automatized continuous on-site monitoring of radiocarbon gaseous emissions from nuclear facilities. By combining radiocarbon detection using mid-infrared cavity ring-down spectroscopy and an advanced sampling system, an elevated amount of radiocarbon in an atmospheric-like gas matrix was detected. Radiocarbon was detected in the form of 14CO2 after extraction of the carbon dioxide from the air sample. The system is also able to discriminate between radiocarbon in organic or inorganic molecular form by converting 14CH4 into 14CO2. This work lays the groundwork for further use of this technology in nuclear facilities for online on-site monitoring of radioactive gaseous emissions as well as future work on in-situ monitoring of atmospheric radiocarbon.

Broadband photoacoustic spectroscopy of CH414 with a high-power mid-infrared optical frequency comb.

We report a photoacoustic spectroscopy setup with a high-power mid-infrared frequency comb as the light source. The setup is used in broadband spectroscopy of radiocarbon methane. Owing to the high sensitivity of a cantilever-enhanced photoacoustic cell and the high-power light source, we can reach a detection limit below 100 ppb in a broadband measurement with a sample volume of only a few milliliters. The first infrared spectrum of CH414 is reported and given a preliminary assignment. The results lay a foundation for the development of optical detection systems for radiocarbon methane.