1.
Chem Commun (Camb)
; 55(54): 7832-7835, 2019 Jul 02.
Artigo
em Inglês
| MEDLINE
| ID: mdl-31215550
RESUMO
The structure of a highly active pyridine-alkoxide iridium water oxidation catalyst (WOC) is examined by X-ray absorption spectroscopy (XAS). A detailed comparison with IrO2 points to a rigid molecular unit of low nuclearity, with the best analysis suggesting a novel tetrameric iridium-oxo cubane as the resting state.